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Atomic Models Democritus to Rutherford 10/6/2007 Atomic Model s 2 Democritus (460—370 BC) • Greek Philosopher • Atomism • Nothing exists but atoms and empty space; everything else is opinion. • Atom comes from atomos meaning uncuttable. 10/6/2007 Atomic Model s 3 10/6/2007 Atomic Model s 4 1 Democritus Atomic Theory 1. All matter consists of INVISIBLE PARTICLES…..called atoms 2. Atoms are 3. 4. 5. 6. • Solids are made of small, pointy atoms. • Liquids are made of large, round atoms. INDESTRUCTIBLE & UNCHANGEABLE A VOID (empty space) exists between atoms Atoms are SOLID Atoms are HOMOGENEOUS……(no internal structure) Atoms DIFFER in size, shape, mass, position, • Oils are made of very fine, small atoms that can easily slip past each other. • Sweet things are made of smooth atoms, bitter things of sharp atoms arrangement….. 10/6/2007 Atomic Model s 5 10/6/2007 John Dalton (1766--1844) Atomic Model s 6 Dalton‛s Atomic Model 1. • A New System of All matter consists of TINY PARTICLES Chemical Philosophy • Developed the 1st useful 2. Atoms are INDESTRUCTIBLE & UNCHANGEABLE Atomic Theory • Good at experiments • 1st to associate atoms with stoichiometry 3. Elements are characterized by ATOMIC MASS 4. When elements react, their atoms combine in WHOLE NUMBER RATIOS 10/6/2007 Atomic Model s 7 10/6/2007 Atomic Model s 8 2 Dalton‛s Laws J. J. Thomson ( 1856--1940) • Law of Constant Composition (aka Law of Definite Proportions) Discovered electrons in 1891 for a given compound, the composition is always the same: H2O CO2 Cathode ray tubes CH4 Plum Pudding Atomic Model • Law of Multiple Proportions different compounds may be formed from the same elements in different, but fixed, ratios: H2O & H2O2 10/6/2007 CO2 & CO CH4 & C2H6 Atomic Model s 9 10/6/2007 Atomic Model s 10 11 10/6/2007 Atomic Model s 12 A Cathode Ray Tube 10/6/2007 Atomic Model s 3 Rutherford (1871--1937) Discovered the nucleus in 1911 Gold Foil Experiment Planetary Atomic Model 10/6/2007 Atomic Model s 13 10/6/2007 Atomic Model s 14 10/6/2007 Atomic Model s 15 10/6/2007 Atomic Model s 16 4 Rutherford‛s explanation for both large- and small-angle scattering, was the nucleus 10/6/2007 Atomic Model s 17 10/6/2007 Atomic Model s 18 Empty space!! If an atom were the size of a baseball stadium, The nucleus would be the size of a PEA 10/6/2007 Atomic Model s 19 10/6/2007 Atomic Model s 20 5 Structure of the Nucleus A Model of Helium 2 protons 2 neutrons 2 electrons 10/6/2007 Atomic Model s 21 10/6/2007 Atomic Model s 22 10/6/2007 Atomic Model s 24 Elements Chart Element Symbol Atomic # Atomic Mass Mass # # Protons # Electrons # Neutrons H 1 1.008 1 1 1 0 He 2 4.003 4 2 2 2 O 8 N 7 C 6 F 9 P 15 Sn 50 C-14 6 10/6/2007 Atomic Model s 23 6 Isotopes Same Atomic Number, Different Atomic Mass Same # of Protons, Different # of Neutrons 1 proton, 0 neutrons Hydrogen Deuterium Tritium (heavy hydrogen) (heavier hydrogen) 1 proton, 1 neutron 1 proton, 2 neutrons Carbon-12 6 protons, 6 neutrons Carbon-13 6 protons, 6 neutrons 10/6/2007 Atomic Model s 25 Alkali Metals Boron Family Alkaline Earth Metals Transition Metals Carbon Family 10/6/2007 Nitrogen Family Oxygen Family Halogens Noble Gases Atomic Model s 26 Source of Images and Text gas liquid http://antoine.frostburg.edu/chem/senese/101/atoms/dalton.shtml http://dbhs.wvusd.k12.ca.us/Rutherford-Model.html 10/6/2007 Atomic Model s 27 10/6/2007 Atomic Model s 28 7