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2017_22: The effect of climate change on arsenic in drinking water in Bangladesh Supervisors: Dr Dominik Weiss ([email protected]), Professor Ramon Villar (Chemistry); Chris Johnston (Bio-Nano-Consulting), Dr Pascal Salaun (University of Liverpool) Department: Earth Science & Engineering In this PhD project, we aim to investigate the effect of increasing groundwater salinity due to climate change on the release of arsenic from aquifers and on the removal efficiency of arsenic in water treatment facilities in Bangladesh. A study of the International Union for the Conservation of Nature (IUCN) published in 2015 highlighted the climate change vulnerability of drinking water supply infrastructure in coastal areas of Bangladesh. The impacts of climate change on water supplies directly affect suitable development of the country and puts at rest poverty reduction. Water supply will be crucially affected by climate change in many ways in Bangladesh. A key threat is from sea level rise and the subsequent salinity intrusion. This process could increase expenses for water treatment mechanisms. This in turn will affect access to safe drinking water options. This changed physical environment will affect public health issues and coast lively hood. The study by the IUCN predicts that the salinity front in Bangladesh will move towards inland from the south of Bangladesh. Based on model prediction, the population exposed to high salinity is expected to increase to 13.6 million in 2050. Pond sand filter have been proposed as one of the major low cost technology to address the problem of increasing saline water following climate change. The increase in salinity will profoundly affect the surface chemistry of aquifers and the efficiency of sorbents used in water treatment to remove toxic elements such as arsenic. The release of arsenic contained in sediments hosting drinking water reservoirs is a well-documented threat to human health in Bangladesh affecting millions of people. The increase in salinity likely leads to an increased release of arsenic from sediments due to ion exchange processes and/or increased dissolution of mineral oxides. The increase in salinity will also effect the efficiency of arsenic removal plants because of increased competitive adsorption. This process will be a particular threat to the pond sand filter (PSF) , which are increasingly used as low cost technology to improve water quality. PSFs are based on sand which is well known to adsorb arsenic much less effective than iron oxides and other mineral oxides. For more information on how to apply visit us at www.imperial.ac.uk/changingplanet Science and Solutions for a Changing Planet To address these question, we will conducted field and laboratory experiment to assess the chemistry of arsenic in saline solutions and in particular at the mineral water surface interactions. We will study the interface process macroscopically using batch and column experiments and microscopically using spectroscopy techniques including X-ray, UV/Vis, XPS and FTIR. This data will be used to develop surface complexation and reactive transport models which will ultimately allow us to develop a predictive assessment of the effects of increased salination on arsenic release in aquifers and on adsorption in pond sand filters. For more information on how to apply visit us at www.imperial.ac.uk/changingplanet