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هذه األسئله إهداء من عبدهللا الحضري [email protected] ORGANIC CHEMISTRY – PHARMACY Choose the best answer: CH 3 CH3CHCH-CH 3 CH 3 1- is: a) 3-bromo-2-chloro butane b) 2,3-dimethyl butane c) 2-bromo-3-chloro pentane 2- is: a) Pentane b) butane c) propane 3-Alkenes are soluble in a) water b) non polar solvent c) polar solvent 4- The simplest alkane is: a) ethylene b) acetylene c) methane CH 3 5- CH 3-CH-CH 2-CH=CH 2 is: 1 a) 1-bromo-5-methyl-3-hexyne b) 7-bromo-2-methyl-3-hexyne c) 4-methyl -l-pentene Cl 6a) chloro cyclo hexane b) 1,2-dimethyl cyclo hexane c) 1,1-dimethyl cyclo hexane CH3 OH 7- H2SO4 CH3 + 1. °C,THF 2. H2O + H 2O + CH3 OH 3. 8- Phenol has molecular formula: a) C6H8 b) C6H5OH c) C7H6 Br 9- Br a) m-dichloro benzene b) p-dibromo benzene c) o-dichloro benzene 2 10 -Oxidation of HO CH3 MnO4 1. H2O COOH 2. MnO 4 3. 11-The sulfonamide antibacterial effect is a) bacteriostatic b) bactericidal c) both 12-which is the highest boiling point a)CH3Cl b)C2H6 c)CH4 CH 3CH=CH 2 Cl2 13- a) CH3CCl2 - CHCl2 b) CH3CHCl-CH2Cl c) CH3-C=CCl4 14- ROH+HXRX+H2O The reaction work best when (tertiary, secondary, primary) alcohols. 3 HO 15- OH : a) resorcinol b) catechol c) hydroquinone R H-C-OH 16- H This is a: a) 1o alcohol b) 2o alcohol c) 3o alcohol 17- (diethylether, phenol, glycerol) is a humectant . 18- Oxidation of secondary alcohols give (alcohols, aldehydes, ketones) 19- Et2O is called: a) diethylether b) phenol c) ethene 20- Nucleophiles have a) positive charge b) negative charge c) neutral charge 21- CH3-O-CH3 is (asymetrical ether ,an unsymmetrical ether ,asymmetrical cyclic ether ) 22-CH3SH is (cyclohexanethiol, methanethiol, cresol) 4 23O OH O RC O C R Cl 1. 2. Cl 3. 24H CH 3-CH 2NCH 2-CH 3 (ethylmethyl propylamine , diethylamine , methyl propylamine) CH3 25- CH3-N-CH3 is (primary-secondary-tertiary) amine 26O C H is (benzaldehyde, acetaldehyde, formaldehyde) 27- O R-C-OH is (RCO2H, RCOOH, both) 5 28- Propene has molecular formula (C3H6, C4H10, C5H10) 29-CH3OH is called a) acetylene b) methanol c) ethane 30NH 2 NO 2 Sn/HCl Br a. NaOH Br NO 2 b. c. Br Put true or false 1. Atoms are composed of a positively charge neutrons. F 2. Mass number is the number of protons plus electrons. F 6 3. Side to side overlap gives σ bonds. 4. Alcohols are miscible with water . 5. The most electro negative element is nitrogen. 6.The electronegativity decrease horizontally from left to right. F T F F 7.Summation of all individual bond polarity is the atomic number. F 8.In structural isomerism there will be cis and trans. F 9.Tertiary amin can form hydrogen bond. F 10.Morphine and codeine are biologically active nitrogen compounds. Complete: 1. The unit of dipole moment is ----debey---------. 2. –agent orange-------------is a 50:50 mixture of esters of 2,4-D and 2,4,5-T. 7 T Br 3. CH3-CH2-CH2-Br CH3-CH-CH3 is--position----------isomerism . 4. CH3COOH+NaOH CH3COONa +H2O ---O 5. R –C+[O] R-COOH ------ H + Cl 2 6C6H5Cl +HCL --- 7- CH3-CH2-CH2-CH3 is called-------butane--------- 8- CH3-CH2-O-CH2-CH3 is called ---diethyl ether-9- C6H7N Is called -----aniline------ 10- O HC-H is called-----formaldehyde----------- Write the general formula of: 1. Alkanes 2. Alkenes 3. Alkynes 4. ester CnH2n+2 CnH2n CnH2n-2 RCOOR 8 RCOH 5. Aldehyde هذه األسئله إهداء من عبدهللا الحضري [email protected] 9