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Unit 3. The Chemistry of Life Topic 1. Basic Chemistry Composition of Matter Matter - Everything in universe is composed of matter o Matter is anything that occupies space or has mass Mass – quantity of matter an object has Weight – pull of gravity on an object Elements o Pure substances that cannot be broken down chemically into simpler kinds of matter o More than 100 elements (92 naturally occurring) o 90% of the mass of an organism is composed of 4 elements (oxygen, carbon, hydrogen and nitrogen) o Each element unique chemical symbol Consists of 1-2 letters First letter is always capitalized Atoms o The simplest particle of an element that retains all the properties of that element o Properties of atoms determine the structure and properties of the matter they compose o Our understanding of the structure of atoms based on scientific models, not observation o The Nucleus Central core Consists of positive charged protons and neutral neutrons Positively charged Contains most of the mass of the atom The Protons All atoms of a given element have the same number of protons Number of protons called the atomic number Number of protons balanced by an equal number of negatively charged electrons The Neutrons The number varies slightly among atoms of the same element Different number of neutrons produces isotopes of the same element Atomic Mass Protons & neutrons are found in the nucleus of an atom Protons and neutrons each have a mass of 1 amu (atomic mass unit) The atomic mass of an atom is found by adding the number of protons & neutrons in an atom o The Electrons Negatively charged high energy particles with little or no mass Travel at very high speeds at various distances (energy levels) from the nucleus Electrons in the same energy level are approximately the same distance from the nucleus Outer energy levels have more energy than inner levels Each level holds only a certain number of electrons Electrons in the same energy level are approximately the same distance from the nucleus Outer energy levels have more energy than inner levels Each level holds only a certain number of electrons o Energy Levels Atoms have 7 energy levels The levels are K (closest to the nucleus), L, M, N, O, P, Q (furthest from the nucleus) The K level can only hold 2 electrons Levels L – Q can hold 8 electrons (octet rule) Periodic Table o Elements are arranged by their atomic number on the Periodic Table o The horizontal rows are called Periods & tell the number of energy levels o Vertical groups are called Families & tell the outermost number of electrons Elements and Isotopes o A chemical element is a pure substance that consists entirely of one type of atom. o The number of protons in an atom of an element is the element's atomic number. o Atoms of the same element that differ in the number of neutrons they contain are known as isotopes. o Because they have the same number of electrons, all isotopes of an element have the same chemical properties. o Radioactive Isotopes Some isotopes are radioactive, meaning that their nuclei are unstable and break down at a constant rate over time Radioactive isotopes can be used to determine the ages of rocks and fossils to treat cancer. to kill bacteria that cause food to spoil as labels or “tracers” to follow the movement of substances within an organism Compounds o Most elements do not exist by themselves o Readily combine with other elements in a predictable fashion o A compound is a pure substance made up of atoms of two or more elements o The proportion of atoms are always fixed o Chemical formula shows the kind and proportion of atoms of each element that occurs in a particular compound o The physical and chemical properties of a compound differ from the physical and chemical properties of the individual elements that compose it Molecules o Molecules are the simplest part of a substance that retains all of the properties of the substance and exists in a free state o Some molecules are large and complex Chemical Formulas o Subscript after a symbol tell the number of atoms of each element o H20 has 2 atoms of hydrogen & 1 atom of oxygen o Coefficients before a formula tell the number of molecules o 3O2 represents 3 molecules of oxygen or (3x2) or 6 atoms of oxygen Chemical Bonds o The tendency of elements to combine and form compounds depends on the number and arrangement of electrons in their outermost energy level o Atoms are most stable when their outer most energy level is filled o Most atoms are not stable in their natural state o Tend to react (combine) with other atoms in order to become more stable (undergo chemical reactions) o In chemical reactions bonds are broken; atoms rearranged and new chemical bonds are formed that store energy Chemical Bonds Types o Ionic bonds Some atoms become stable by losing or gaining electrons Atoms that gain electrons are called negative ions (Anions) Atoms that loose electrons are called positive ions (Cations) Because positive and negative electrical charges attract each other ionic bonds form o Covalent bonds Sometimes electrons are shared by atoms instead of being transferred. Formed when two atoms share one or more pairs of electrons The structure that results when atoms are joined together by covalent bonds is called a molecule Polar bonds o Ionic bonds are polar (one side has more electrons than the other) o Covalent bonds between elements with different number of protons in their nucleus can be polar if the molecular structure is not perfectly symmetric. For example: In water, oxygen has a higher number of protons and pulls electrons more than hydrogen can. The result is a polar bond where electrons are shared unequally between oxygen and hydrogen. Wall der Waals Forces o Polar molecules have one side more negative than the other. o The negative side attracts the positive side of another molecule o When molecules are close together, a slight attraction can develop between the oppositely charged regions of nearby molecules. o Unlike chemical bonds, atoms are not joined together by the sharing of electrons. o This is a physical connection based on magnetism/electricity and attraction between different charges o This connections is what holds molecules together to form a substance