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Name ____________________________________ Period: _____ Lab Partners: ______________________________ Date _________________ LAB 4.5: Periodicity Purpose: To graph properties of elements on the periodic table to see how they relate to the atomic number Background information: Atomic radius is the radius of the neutral atom. Ionization energy is the energy needed to pull away the outermost electron to an infinite distance from the atom. Materials: Data for physical properties of elements Computer with graphing program or graph paper Data table: Atomic Number Atomic Radius (Å) 1 2 3 4 5 0.53 0.31 1.67 1.12 0.87 Ionization Energy (kJ/mol) 1312.0 2372.3 520.2 899.5 800.6 6 7 8 9 10 11 12 13 14 0.67 0.56 0.48 0.42 0.38 1.90 1.45 1.18 1.11 1086.5 1402.3 1313.9 1681.0 2080.7 495.8 737.7 577.5 786.5 15 16 17 18 19 0.98 0.88 0.79 0.71 2.43 1011.8 999.6 1251.2 1520.6 418.8 20 1.94 589.8 Data source: http://www.webelements.com/atoms.html downloaded 07 Jan 2009 Copyright © 2009 by Kendall Hunt Publishing Company Page 1 of 4 LAB 4.5: Periodicity Procedure: For graph paper: 1. Make a graph with the atomic number along the x axis and the atomic radius along the y axis. Connect the data points in a “connect-the-dots” style. We’re using this method instead of a best-fit line method because we want to see the trend of how the variables change, rather than find an average change. Remember to use as much of the paper as possible—stretch out the axis. 2. Make a similar graph with the atomic number along the x axis and the ionization energy along the y axis. For computer graphing: 1. Open the graphing/spreadsheet program on the computer (Microsoft Excel or other program as designated by your teacher). 2. Spreadsheets are organized with columns labeled with letters and rows labeled with numbers. Each cell is named with the letter and the number (cell 1A is in row 1 and column A). 3. Enter the following labels into cells 1A–1C: atomic number, atomic radius, ionization energy. 4. Fill in the spreadsheet with the data provided. 5. Highlight the block of cells in columns A and B with data (including the labels in row 1). 6. Insert and format the chart. Use the following instructions for Microsoft Excel. 7. From the Insert menu, choose Chart. 8. Select XY (Scatter). 9. Choose the type that has data points marked with straight lines connecting the data points (connect-the-dots style). Again, we’re using this type of graphing instead of a best-fit line because we are specifically looking for trends—how the values rise and fall as the atomic number changes, not the overall average of the values. 10. Select “Chart Tools” and “Layout”. Select “Axis Titles” and enter the correct titles for both the Primary Horizontal (“Atomic Number” as the x-axis label) and Primary Vertical axis (“Atomic Radius” as the y-axis label). 11. Select “Chart Title” and type “Periodic trends” as the chart title (also put your name in the title so that we know whose printout is whose). 12. Print a graph for each member of the group. 13. Repeat steps 5–12 for the cells with data in columns A and C. To highlight columns that are not next to each other, highlight column A, then hold the control button down while highlighting column C. The Primary Vertical axis should be labeled “Ionization Energy). Copyright © 2009 by Kendall Hunt Publishing Company Page 2 of 4 LAB 4.5: Periodicity Discussion 1. Atomic radius: a. As you move from left to right across the periodic table (for example, look at elements 11–18), what happens to the atomic radius? b. Is the trend fairly smooth, or is it spiky? c. As you move down the periodic table (for example, look at elements 3, 11, and 19), what happens to the atomic radius? d. Is the trend fairly smooth, or is it spiky? 2. Ionization energy: a. As you move from left to right across the periodic table (for example, look at elements 11–18), what happens to the ionization energy? b. Is the trend fairly smooth, or is it spiky? c. As you move down the periodic table (for example, look at elements 3, 11, and 19), what happens to the ionization energy? Copyright © 2009 by Kendall Hunt Publishing Company Page 3 of 4 LAB 4.5: Periodicity d. Is the trend fairly smooth, or is it spiky? 3. Both trends: a. Put the atomic radius graph on top of the ionization energy graph. Hold them up to the light so that you can see both at the same time. What do you notice about how they compare to each other? b. Based on your last question, are atomic radius and ionization energy directly or indirectly related? c. Give a reason why you might think that they’re related in the way that they are. How might the radius of the atom affect the amount of energy needed to pull off the outermost electron? Copyright © 2009 by Kendall Hunt Publishing Company Page 4 of 4