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BIOSYNTHESIS OF NONESSENTIAL AMINO ACIDS AMINOTRANSFERASE FROM MAJOR PATHWAY INTERMEDIATES oxaloacetate α-ketoglutarate aspartic acid glutamic acid pyruvate alanine AMIDATIONS ATP + NH 3 ADP + P i glutamic acid ATP+ glutamine glutamine glutamic acid aspartic acid + AMP + P P i asparagine α-KETOGLUTARATE FAMILY ATP glutamate ADP Pi NAD(P)H/H + NAD(P) + glutamate-5-phosphate glutamic acid H 2O NAD(P)H/H + NAD(P) + ∆ 1-pyrroline-5-carboxylate glutamate-5-semialdehyde α-ketoglutarate urea cycle glutamate-5-semialdehyde ornithine arginine 3-PHOSPHOGLYCERATE FAMILY NAD + 3-phosphoglycerate tetrahydrofolate NADH/H + α-ketoglutarate glutamic acid 3-phosphohydroxypyruvate H 2O 3-phosphoserine 5,10-methylene tetrahydrofolate serine + H 2O glycine serine homocysteine H 2O serine NH 4+ H 2O cystathionine cysteine + α-ketobutyrate TYROSINE O2 Pi + tetrahydrobiopterin phenylalanine dihydrobiopterin tyrosine + H 2O proline