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COVER SHEET TO ACCOMPANY THE ORGANIC CHEMISTRY FINAL EXAM: May 2007 Combined Gas Law Equation: Ideal Gas Equation: P1V1T2 = P2V2T1 PV MW = gRT or PV = nRT or d = g/v = P MW/RT Dalton’s Law of Partial Pressures: Ptotal = ntotalRT/V = P1 + P2 + P3 + … + Pn Vcylinder = r2h R = .0821 liter-atm/mole-Kelvin Vsphere = 4r3/3 R = 62,400 ml-Torr/mole-Kevin Acircle = r2 = .25D2 R = .0426 ft3-psi/mole-Kelvin 760 Torr = 760 mmHg = 1 atm = 14.7 lb/in2 = 1013 mBar Atriangle = .5bh r = d/t 16 drams = 1 ounce (wt ounces) d = m/v 12 troy ounces = 1 pound E = mc2 K.E. = .5mv2 1 calorie = 4.184 joules q = mcT C = 5/9(F – 32) or M = n/V = g/V-MW 252 calories = 1 BTU 1 atomic mass unit = 1.6611 x 10-24 grams 1 joule = 1 Kg-m2/sec2 F = 9C/5 + 32 c = 300,000,000 m/sec In the metric system one milliliter and one cubic centimeter represent the same volume In the metric system, one milliliter of liquid water has a mass of one gram One mole of any gas at STP takes up (or occupies) 22,400 ml of space Mass of one electron = 9.11 x 10-28 grams Mass of one proton = 1.672 X 10-24 grams Mass of one neutron = 1.674 x 10-24 grams 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f146d107p68s25g186f147d108p69s26g187f148d109p610s2 1 ft3 = 28.32 liters 454 g = 1 pound HELLO HELLO HELLO !!!! THE LIGHTS ARE ON! 2.54 cm = 1 inch 946 ml = 1 quart 1 gallon = 3.784 liters Carbon atoms always make four bonds!!! IS ANYONE HOME? Oxygen atoms always make two bonds! FOR THOSE OF YOU WHOM ARE STILL URACS!!! Hydrogen atoms are so so boring – all they ever do is make one bond!!! Carboxy group Formyl group H N Ethynyl group Ethenyl group ol = alcohol H ane = single bonds yne = triple bond al = aldehyde Amino group oic acid = carboxylic acid ene = double bond one = ketone