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Chemical Olympiad 2014 Tie #2 2014 1 Tie #2 South Wales West Local Section Round 1 INDIVIDUAL ROUND Read & Learn the Given Reduced Periodic Table You are given an summary form of the Periodic Table and two minutes in which to try and remember the relevant points. The Table will then be collected and questions are specifically related to the content of the Table you have just seen. CAPTAIN WHO WON THE TOSS TO DECIDE WHICH TEAM GOES FIRST YEAR 8/9 1 2 YEAR 9 YEAR 10 Give the name of the element Atomic No. 2 in the Table HELIUM Give the name of the element Atomic No 1 in the Table HYDROGEN 1 Give the name of one of the elements in the Group below He in the given Table 2 Give the name of one of the elements in the Group below F in the given Table. 1 What element lies below Be in the Table. (Clue: it burns very brightly in air) 2 What element lies to the left of F in the Table, and has At. No. 8 YEAR 11 1 (a) Choose an element from the Transition row and give (b) a typical commercial use of that element. 2 (a) Choose another element from the Transition row and give (b) a typical commercial use of that element. Read out the scores Neon,Argon,Krypton, Xenon or Radon Chlorine, Bromine or Iodine MAGNESIUM OXYGEN Many answers possible. QM to decide on quality of answers. Many answers possible. QM to decide on quality of answers. Chemical Olympiad 2014 Tie #2 2014 2 Tie #2 South Wales West Local Section Round 2 BUZZER ROUND CHEMICAL CHANGES YEAR 8/9 YEAR 9 Which of the following involves a chemical reaction? (a) freezing water (b) toasting bread (c) crushing apples (d) magnetising iron Which of these results in chemical change? (a) mixing iron and sulphur powders (b) adding lime to vinegar (c) adding milk to tea (d) mixing salt with water Energy is needed to make a mixture of methane and YEAR oxygen react. The mixture explodes when a lighted 10 splint is applied. What type of energy is supplied by the splint: TOASTING BREAD ADDING LIME TO VINEGAR ACTIVATION ENERGY (a) catalyst energy (b) activation energy (c) potential energy or (d) renewable energy When ammonium nitrate is added to water an YEAR endothermic process occurs and…. 11 (a) temperature falls or (b) heat is given out or (c) surroundings get hotter, or (d) temperature rises. Read out the scores TEMPERATURE FALLS Tie #2 2014 Chemical Olympiad 2014 3 Tie #2 South Wales West Local Section Round 3 Team Progression Round This is a team round and written answers will be received by the question master from the captain of each team. Each team can go on with no penalties until they have the correct answer. Clue 1 It is a substance involved in photosynthesis. Clue 2 It could be described as a covalent hydride of a non-metal. ( 6 points) Clue 3 It is the essential reactant in the hydrolysis of fats to fatty acids, proteins to amino acids, and polysaccharides to monosacharides. (4 points) Clue 4 It releases two gases on electrolysis, and exists on Earth in the three states of solid, liquid, and gas (2 points) Clue 5 Approximately 66% of the human body, 75% of the human brain is composed of this substance (1 point) Answer WATER Chemical Olympiad 2014 Tie #2 2014 4 Tie #2 South Wales West Local Section Round 4 INDIVIDUAL ROUND Chemistry in the Pharmacy CAPTAIN WHO LOST THE TOSS TO DECIDE WHICH TEAM GOES FIRST YEAR 8/9 1 2 YEAR 9 YEAR 10 What painkiller whose name starts with P can be bought over the counter. PARACETAMOL (PANADOL) What painkiller whose name starts with A can be bought over the counter. ASPIRIN 1 What type of drug would the doctor obtain from the hospital pharmacy to put you to sleep before an operation. 2 What type of drug is prescribed in capsules or tablets to counteract bacterial infections. 1 What drug is prescribed for rheumatism, but is mis-used as a performance drug by athletes. 2 Very acute pain is often controlled by an injection of a drug obtained from the Opium Poppy YEAR 11 1 Pharmacies now sell a wide variey of hair – styling kits. What chemical is used to produce a blonde effect? 2 Disinfectants often contain phenols. What type of organic compound is a phenol? Read out the scores ANAESTHETIC ANTIBIOTICS (or PENICILLINS) STEROIDS MORPHINE PEROXIDE Aromatic alcohol? OH attached to Benzene Ring? Carbolic acid? Chemical Olympiad 2014 Tie #2 2014 5 Tie #2 South Wales West Local Section ROUND 5 BUZZER ROUND A ‘BLOCKBUSTER’ ROUND In each case the answer is one word starting with the letter ‘N’ YEAR What ‘N’ is a tough and elastic synthetic fibre? 8/9 NYLON Oxides of this ‘N’element cause acid rain, while YEAR another is used as a dentist’s anaesthetic gas. 9 NITROGEN What ‘N’ is a silvery metal often used with silver YEAR in electroplating. 10 NICKEL YEAR What ‘N’ is an addictive alkaloid used in e-cigarettes. 11 Read out the Scores NICOTINE Chemical Olympiad 2014 Tie #2 2014 6 Tie #2 South Wales West Local Section ROUND 6 INDIVIDUAL ROUND Who wants to be a millionaire? The idea comes from the TV programme, but there are no cash prizes to be won! You will be asked a question and given 4 possible answers, only one of which is correct. For a correct answer you get 2 points. If you have doubts, you may go 50:50 or ask a friend (any specified individual in your team) in which case a correct answer wins only 1 point. If a wrong answer is given, the question passes to the opposing team who will NOT be allowed a life line, but will be given one point for a correct answer. CAPTAIN WHO WON THE TOSS TO DECIDE WHICH TEAM GOES FIRST YEAR 1 Which of the following is not a gas at standard temperature and pressure? OXYGEN 8/9 CHLORINE NITROGEN Which one of the following is not a chemical element? 2 YEAR 9 1 Ca Ag Pb Sh or Sh What test could be used on a test tube full of oxygen to show that it was really oxygen? (a) Burns with a pop (b) Relights a glowing splint (c) Extinguishes a lighted splint (d) Lime water turns milky 2 MAGNESIUM MAGNESIUM Which is not the definition of a state of matter? Solid Emulsion Liquid Gas (b) Relights a glowing splint Emulsion Chemical Olympiad 2014 Tie #2 2014 7 Tie #2 South Wales West Local Section Round 6 continued YEAR 10 1 2 The mass number of an atom gives the…… (a) Number of protons in the nucleus (b) Number of protons + neutrons in the nucleus (c) Number of electrons in the outer energy level (d) Number of protons + electrons Oil floats on water, the most accurate reason for this is because………. (a) Oil is less dense than water. (b) Oil is immiscible in water (c) Oil is both less dense and immiscible in water (d) Water is heavier than oil YEAR 11 1 How many bonds are present in a molecule of methane, and what type of bonding is it? (a) 3 and covalent (b) 4 and ionic (c) 4 and covalent (d) 8 and covalent (b) Number of protons + neutrons in the nucleus (c) Oil is both less dense and immiscible in water (c) 4 and covalent Noble gases are chemically inert because:2 (a) They have too many electrons in their outer shell (b) They have too few electrons in their outer shell (c) There is a stable arrangement of electrons in shells (d) They have no electrons READ OUT THE SCORES Stable arrangement of electrons in shells Chemical Olympiad 2014 Tie #2 2014 8 Tie #2 South Wales West Local Section Round 7 INDIVIDUAL ROUND Acids and Bases CAPTAIN WHO LOST THE TOSS TO DECIDE WHICH TEAM GOES FIRST YEAR 8/9 1 Which of the following substances contain an acid? (a) an orange 2 (b) distilled water (c) washing powder Which of the following substances contain a base? (a) washing soda YEAR 9 1 1 (b) 5 (c) 7 (b) 5 (c) 7 We can react an acid and a base together to produce a salt. What is the correct name for this type of reaction. Is it (a) combustion (b) oxidation or (c) neutralisation (a) oxygen 1 (c) neutralisation (b) hydrogen (b) hydrogen or (c) carbon dioxide Which one of the following statements is true? (a) A strong acid has a high pH number 2 7 (d) 14 2 Salts can be made by reacting metals with acids. What gas is given off in this reaction? Is it YEAR 11 14 (d) 14 Which of the following pH numbers indicates a neutral substance? (a)1 YEAR 10 (c) vinegar (a) washing soda Which of the following pH numbers indicates a strong base? (a) 1 2 (b) Coca Cola (a) an orange (b) A strong acid is partially ionised in water or (c) A strong acid is 100% ionised in water When an acid and base react, salt and water are formed. Pick the correct salt produced when dilute ammonium reacts with nitric acid (a) ammonium chloride (b) ammonium sulphate or (c) ammonium nitrate (c) 100% ionised (c) ammonium nitrate Chemical Olympiad 2014 Tie #2 2014 9 Tie #2 South Wales West Local Section Read out the scores Round 8 BUZZER ROUND PROPERTIES, SYMBOLS AND ELEMENTS NAME THE ELEMENT AS AN ANSWER EACH QUESTION CARRIES TWO POINTS. In addition there is a challenging question which carries one bonus point. The winner of the initial two points may confer with his team to answer it.. YEAR 8/9 YEAR 9 YEAR 10 YEAR 11 Its purity is measured in carats, its symbol is Au. What is it? GOLD ……………………………………………………………………… ……………….. (Bonus to winning team who can confer, for 1 point –give one chemical property of gold) Unreactive to acid It is added to water to kill dangerous bacteria. Its symbol is Cl CHLORINE ………………………………………………………………………. ………………... (Bonus to winning team who can confer, for 1 point –how many isotopes does chlorine have?) TWO It exists in two allotropic forms – red and white. Its symbol is P PHOSPHORUS ………………………………………………………………………. ………………… (Bonus to winning team who can confer, for 1 point – in what form is phosphorus used as fertiliser) Phosphate It is an artificial radioactive element produced in nuclear reactors. Its symbol is Pu. PLUTONIUM ………………………………………………………………………. ……………….. (Bonus to winning team who can confer, for 1 point –what main type of radiation would be produced by a radioactive isotope of plutonium?) α – radiation /particles Read out the scores Tie #2 2014 Chemical Olympiad 2014 10 Tie #2 South Wales West Local Section Tie Breaker - All hands on the Buzzer Which alloy consists of copper and tin and gives its name to a period of time before the Iron Age? BRONZE