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The Atom 1 The Atom: Learning Goals • Democritus: explain his ideas about the atom • Dalton: explain points of his atomic theory • Subatomic particles protons, neutrons, electrons: Identify them in terms of mass, charge, and position • Rutherford: describe atom’s internal structure from his model • Isotopes: identify similarities & differences • Atomic Number and Mass Number: calculate # of protons, neutrons, and electrons • Atomic Mass: calculate atomic mass of an element from isotopes 2 The Atom Warm-up Structure of the Atom The subatomic particles in an atom’s nucleus are the _______________ protons and _______________. neutrons electrons are The ______________ outside the nucleus in a “cloud.” protons and neutrons are in the nucleus of the atom. 3 The Atom We can determine the number of protons an atom has by looking at its Atomic Number ____________ _____________. 4 The Atom • Isotopes What is an Isotope? • An Isotope is a “Version” of the same element that contains a different number of NEUTRONS. Isotopes have the same number of protons (atomic #). Ex: Carbon-12 and Carbon-14 are ISOTOPES of Carbon. Both C-12 & C-14 have 6 protons. C-12 has 6 neutrons, but C-14 has 8 neutrons. 5 The Atom Defining the Atom Democritus • among first to suggest existence of atoms • believed atoms were indivisible & indestructible (ca. 460 BC – ca. 370 BC) 6 The Atom John Dalton Defining the Atom English Chemist & School Teacher (1766 – 1844) Dalton’s Atomic Theory (Early 1800’s) 1. Elements are made of atoms 2. Atoms of same element are identical; atoms of one element different from atoms of another element 3. Atoms of different elements can combine to form compounds 4. atoms cannot be changed chemically 7 The Atom Plum Pudding Atom Defining the Atom J.J. Thomson English Physicist Discovered electrons by making cathode ray tube (1856 – 1940) 1897: Discovered the electron 8 Ernest Rutherford The Atom Defining the Atom •Gold Foil Experiment •Shot alpha particles at gold foil •Some particles bounced off foil, indicating presence of nucleus 1911: Discovered that atoms have a nucleus Click on foil pic for youtube video 9 Niels Bohr The Atom Defining the Atom •Electron moves in a circular orbit at fixed distances from nucleus negative electrons on their orbitals 1913: Discovered electron orbitals 10 The Atom Defining the Atom RECAP - History and Discoveries Democritus (ca. 460 BC – ca. 370 BC) Greek Philosopher Existence of atoms; indivisible & indestructible John Dalton J. J. Thomson (1766 – 1844) English Chemist & School Teacher (1856 – 1940) English Physicist Atomic Theory: 4 key points Discovered electron; cathode ray tube; atom as “Plum Pudding”11 The Atom Defining the Atom RECAP - History and Discoveries Ernest Rutherford (1871 – 1937) British-New Zealand Chemist & Physicist Discovered NUCLEUS; Gold Foil Experiment Niels Bohr (1885 – 1962) Danish Physicist Discovered electron ORBITALS 12 The Atom • Review Who was the first to realize there was a smallest part of matter? Democritus 13 The Atom • Review Who discovered that atoms have a nucleus? Rutherford 14 The Atom Subatomic Particles: PROTONS • • • • • • Protons Identify the element! The number of protons cannot change. # of protons is same as Atomic Number Protons are located inside nucleus Protons have a Positive charge (+) Proton’s Mass is 1 amu 15 The Atom Subatomic Particles: NEUTRONS • • • • • Neutrons are located inside nucleus Neutrons have no charge at all (0) Neutron’s Mass is 1 amu The number of neutrons can CHANGE. # neutrons = Mass number – Atomic number • Oxygen’s # neutrons = 16 – 8 = 8 16 The Atom Subatomic Particles: ELECTRONS • • • • • Electrons are located outside of nucleus # of electrons is same as # protons in neutral atom Atomic number = # of electrons in neutral atom Electrons have a Negative charge (-) Electron’s Mass is 1/1840 amu • Because protons and electrons have equal but opposite charges, a neutral atom must contain equal numbers of protons and electrons 17 Subatomic Particles & Reading Periodic Table Squares The Atom 18 Subatomic Particles & Reading Periodic Table Squares The Atom 19 The Atom • Isotopes What is an Isotope? • An Isotope is a “Version” of the same element that contains a different number of NEUTRONS. Isotopes have the same number of protons (atomic #). Ex: Carbon-12 and Carbon-14 are ISOTOPES of Carbon. Both C-12 & C-14 have 6 protons. C-12 has 6 neutrons, but C-14 has 8 neutrons. 20 The Atom Defining the Atom Atomic Number and Mass Number Atomic Number Is the Number of Protons of the Nucleus Isotopes: Calculating # of neutrons 21 22