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1 Properties of the Three Key Subatomic Particles Charge Mass Location Name(Symbol) Relative Absolute(C)* Relative(amu)† Absolute(g) in the Atom Proton (p+) Neutron (n0) Electron (e-) 1+ +1.60218x10-19 1.00727 1.67262x10-24 Nucleus 0 0 1.00866 1.67493x10-24 Nucleus 1- -1.60218x10-19 0.00054858 1 amu = 1.66 x 10-24 g 9.10939x10-28 Outside Nucleus General Features of the Atom Atomic Symbols, Isotopes, Numbers A J Z The Symbol of the Atom or Isotope J = Atomic symbol of the element A = mass number; A = Z + N Z = atomic number (the number of protons in the nucleus) N = number of neutrons in the nucleus Isotope = atoms of an element with the same number of protons, but a different number of neutrons What makes up the mass of an atom? Calculate the mass of an atom of 19F from the masses of the protons, neutrons and electrons. 9 protons: 9 x 1.007 amu = 9.063 amu 10 neutrons: 10 x 1.009 amu = 10.09 amu 9 electrons: 9 x 0.0005486 amu = 0.004937 amu = 19.16 amu Compared to an “official” value of 18.998 amu ????????? Complete the table Symbol 37Cl 131I 23Na+ 1H 18O2- # p+ # n0 17 20 53 78 # e- 17 Mass # 37 53 131 11 12 10 23 1 0 1 1 8 10 10 18 Comparison to the earth • The earth has a mass of 6.0 x 1024 kg and a radius of 6400 km. • What is the density of the earth in g/cm3? • If the earth were to be compressed so that it had the same density as a gold nucleus, (2.9 x 1012 g/cm3) what radius would it have? Solutions 3 10 g 27 Mass 6.0 x 10 kg x 6.0 x 10 g 1 kg 24 105 cm 6400 x 105 cm 6.4 x108 cm r 6400 km x 1 km 3 4 3 4 8 Volume r 6.4 x10 cm 1.098 x1027 cm 3 3 3 27 6.0 x 10 g 3 density m / V 5.5 g / cm 3 1.098 x 1027 cm Solutions cont’d Let d 2.9 x10 g / cm 12 3 27 m 6 . 0 x 10 g 12 3 d 2.9 x 10 g / cm V V m 6.0 x 1027 g 15 3 V 2 . 069 x 10 cm d 2.9 x 1012 g / cm 3 4 3V 3 V r 3 r 3 4 r 3 (3) x (2.069 x1015 cm 3 ) 79000 cm 0.79 km 4 Tools of the Laboratory Figure B2.2 The Mass Spectrometer and Its Data Figure 24.2 A plot of neutrons vs. protons for the stable nuclides. 12 Periodic Table Elements that occur as molecules. Figure 2.16 1A 2A 3A 4A 5A 6A 7A 8A (1) (2) (13) (14) (15) (16) (17) (18) N2 O2 F2 P4 S8 Cl2 Se8 Br2 H2 I2 diatomic molecules tetratomic molecules octatomic molecules Figure 2.19 Some common monatomic ions of the elements. Can you see any patterns? Table 2.5 (partial) Some Common Polyatomic Ions Formul a NH4 + Name Formula Name H3O+ hydronium Cations ammonium Common Anions CH3COO- acetate CO3-2 carbonate CN- cyanide chromate OH- CrO4-2 hydroxide Cr2O7-2 dichromate ClO3- chlorate O-2 oxide NO2- nitrite SO4-2 sulfate NO3- nitrate PO4-3 phosphate MnO4- permanganate Prefixes (Greek) • One (1) mono• Two (2) di• Three (3) tri• Four (4) tetra• Five (5) penta• Six (6) hexa• Seven (7) hepta• Eight (8) octa• Nine (9) nona• Ten (10) deca2 | 16