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Balancing Chemical Equations Balancing Chemical Equations Law of Conservation of Mass Do you remember this law? The Law of Conservation of Mass states: that mass is neither created nor destroyed in any chemical reaction. Can you provide an example that illustrates this law? Law of Conservation of Mass Because mass can be neither created nor destroyed during a chemical change… the balancing of equations requires the same number of atoms on both sides of a chemical reaction. But Before We Balance Equations…. we must learn how to count the number of atoms in a given formula! Totaling Atoms Using PSEC Parentheses Count up the total number of atoms inside the parentheses Subscripts Multiply the total number of atoms inside the parentheses by the subscript value Extras Add any extra atoms that were not yet accounted for to the total Coefficients Multiply the total number of atoms (from PSE) by the coefficient Examples 2Ba(NO3)2 P – 4 atoms total N 1 O 3 4 atoms 4(NH4)3PO4 Parentheses P – 5 atoms total N 1 H 4 5 atoms S – 8 atoms total Subscripts E – 9 atoms total Extras E – 20 atoms total C – 18 atoms total Coefficients C – 80 atoms total (4)(2) = 8 atoms 8 + 1 = 9 atoms (9)(2) = 18 atoms S – 15 atoms total (5)(3) = 15 atoms 15 + 5 = 20 atoms (20)(4) = 80 atoms Law of Conservation of Mass The mass of all the reactants (the substances going into a reaction) must equal the mass of the products (the substances produced by the reaction). Reactant + Reactant = Product Example: Iron (II) Sulfide iron + sulfur Fe + S iron (II) sulfide FeS Note that in a chemical equation, by convention, we use the arrow “ " instead of the equals “ = ". Balancing Equations 2 3 ___ Al(s) + ___ Br2(l) ---> ___ Al2Br6(s) Learning Through Example Magnesium Oxide Mg + O2 MgO Then all you do is list the atoms that are involved on each side of the arrow Mg + O2 MgO Mg O Mg O Then start balancing: [1] Just count up the atoms on each side Mg + O2 MgO 1 Mg 1 2 O 1 [2] The numbers aren’t balanced so then add “BIG” numbers to make up for any shortages Mg + O2 2 MgO And adjust totals 1 Mg 1 2 2 O 1 2 But the numbers still aren’t equal, so add another “BIG” number 2 Mg + O2 2 MgO 2 1 Mg 2 2 O 2 And adjust totals again NOW BOTH SIDES HAVE EQUAL NUMBERS OF ATOMS WE SAY THAT THE EQUATION IS BALANCED!! Try to balance these equations using the same method: [1] Na + Cl2 NaCl [2] CH4 + O2 CO2 + H2O [3] Li + HNO3 LiNO3 + H2 [4] Al + O2 Al2O3 How did you do?? Here are the answers: [1] 2 Na + Cl2 2 NaCl [2] CH4 + 2 O2 CO2 + 2 H2O [3] 2 Li + 2 HNO3 2 LiNO3 + H2 [4] 4 Al + 3 O2 2 Al2O3