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Dental Curing Lights Visible-Light Activation • Photo-initiator reacts with amine co-activator (electron donner- tertiary amine) • Forms free radicals • Initiates addition polymerization Polymerization IPT • Initiation – production of reactive free radicals – chemical, light, heat • Propagation – monomer units – polymer network • Termination Polymerization Shrinkage • 1.5-7 % volume • Open margins – – – – Microleakage Staining Post-op sensitivity Recurrent caries Important terms about LCU • Emission Spectrum (Wavelengths of Light) Colour • Radiant power (mW) • Radiant exitance (mW/cm2) • Misleading terms such as intensity, power density or brightness The eye is sensitive only to the visible part of the electromagnetic spectrum Emission Spectrum (Wavelengths of Light) I. Camphorquinone (CQ) is the traditional initiator used in most RBCs and it is mostly activated by blue light peaking at 468 nm wavelength II. Trimethylbenzoyldiphenylphosphine oxide (Lucirin TPO, ranging from 375 to 410 nm) III.1-phenyl-1,2-propanedione (PPD, maximum wavelength ≈ 410 nm) Radiant exitance (mW/cm2) ➢Irradiance received at a surface (mW/cm2). ➢ It can only reflect an average value over the total surface area ➢ It does not take into account any non-uniformity in the light output across the tip of the LCU, or the distance from the tip. Photo-polymerization • Many light curing options – – – – Halogen Plasma-arc Laser LED Quartz-Tungsten-Halogen • Most common dental curing light • Quartz – encasing structure • Tungsten – filament coil Quartz-Tungsten-Halogen • Halogen gas – protects filament • oxidation Quartz-Tungsten-Halogen • Filters – band-pass • restricts broader light to narrow blue light – 400-500 nm – range of photo-initiators Quartz-Tungsten-Halogen • QTH bulb – 30-50 hours useful life – Not uniform out put Plasma-Arc (PAC) • Two tungsten electrodes – small gap • Pressurized chamber – xenon gas • High-voltage spark – ionizes gas • White light Plasma-Arc (PAC) • High levels of IR and UV – extensive filtering • down to 400-500 nm Plasma-Arc (PAC) • High irradiance - > 2000 mW/cm2 - Claim 1-3 sec cure • Expensive - Bulbs >$600 - Heat generation - Rapid polymerization Argon Laser • High energy - Coherent, monochromatic - Wave length 470 nm CQ max absorption • Curing time 3-10 sec + DC • Very expensive • Warning signs required Light-Emitting Diodes (LED) • Semiconductors – electrically-excited atoms • Gallium-indium-nitride • Narrow emission spectrum – 430-490 nm • peak at 470 nm • near max absorption of camphorquinone • efficient LED Curing Lights • Long lasting light source – minimal aging (Bulb life is 100 time more than QTH) – minimal decrease in output • Less lateral heat production – minimal or no fan necessary • No filters • Typically cordless+ Work on battery Duke Compendium 2001 LED Curing Lights • First generation – high cost – Led cans – low irradiance • < 300 mW/cm2 • increase exposure time 60 sec needed for 2 mm composite Leonard J Esthet Rest Dent 2002 LED Curing Lights • Second generation – – – – – Lower cost Led chips ‘pads’ Large metal heat sinks Internal cooling fans higher irradiance Price J Can Dent Assoc 2003 • 600-1000 • curing depth similar to halogen But half of time needed mW/cm2 Soh Oper Dent 2004 LED Curing Lights • Third generation - higher irradiance • 1000-3000 mW/cm2 • Polywave spectrum which is suitable for new photo initiators PPD+TPO+MAPO+BAPO • Familiar with all time\power profiles • Ex :pulse delay soft start Ex:- Polywave -Blue phase 20 I Polymerization Modes 1. Uniform continuous cure:A light of constant intensity is applied to a composite for a specific period of time. 2-Step cure:The composite is first cured at low energy, then stepped up to high energy, each for a set duration. “Soft-Start” Polymerization • Stepped – short, low initial burst – full intensity • Ramped – gradual increase from initial low level • Pulsed delayed – short, low level burst – delay 3-5 min – full intensity Curing Modes High Intensity Pulsed Standard Intensity Ramped Stepped Pulse Delay Time (seconds) Yap PPAD 2004 Optical Safety • Do not look directly at light • Protection recommended – glasses – shields • May impair ability to match tooth shades Maintenance • Periodic visual inspection of unit – light guide – filters – bulb • Check irradiance – radiometer Strydom SADJ 2002 Contamination of Light Tip • Reduces passage of light • Reflects light – increases heat build-up – shortens bulb life • Remove debris – polishing kit – blade – replace light guide Radiometer • Consists of photosensitive diode – specific for light • Measures useful light output at curing tip – hand-held – built-in • Light-specific radiometers – QTH – LED Hand-held Radiometers • Numerical – analog – digital Built-in Radiometers • Indicator lights – range type • Numerical “Turbo” Light Guides Factors that affect light curing of composite 1. 2. 3. 4. Exposure Intensity Temperature Distance and angle between light and resin 5. Angle and path of the light 6. Thickness of resin 7. Operatory lighting 8. Incandescent lighting 9. Fluorescent lighting 10. Improving working time 11. Air inhibition 12. Curing through tooth structure 13. Shade of resin 14. Type of filler 15. Amount of photoinitiator 16. Heat generated by light-curing units 17. Room-light polymerization Clinical recommendations when using a curing light `