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MTLE 4050/6963: Introduction to Polymers. R = 8.314 J/molK = 1.987 cal/molK NA = 6.02 ×1023 1/mol h = 6.623 ×10−34 Js = 4.136 ×10-15 eVs k = 1.38 ×10−23 J/K = 8.617 ×10−5 eV/K Mn = ∑ ni M i ∑ ni Mw = ∑ wi M i ∑ wi Đ= DPn ⋅ m = M n T= R 2 ( ) p φi = = c ω 1 k = υ0 = λ 2π 2π mr ω = 2πυ µ ΔE = hυ = Β0 µ υ L = Β0 Ι hΙ µ = γΙ ∑ ni M i2 ∑ ni M i Mn P(r / m) = − E / RT i 3 ∑e H2 C φ − E / RT i 1.5 4 C H2 H2 C 109.5o R SAW ( 1/2 ) =Rℓ2 Co ∝ NN SAW (mm) (m) θ C H2 ! 1 / 3, bad solv. # ν = " 1 / 2, θ solv., melt # 3 / 5, good solv. $ νv F0 ( mr ω 02 − ω 2 P(r / r) = P(m / r) = (rr) (r) (rm) / 2 (r) (mm) = (mmm) + (mmr) / 2 (rr) = (rrr) + (mrr) / 2 (mr) = (mmr) + 2(rmr) = (mrr) + 2(mrm) i=1 2 (mr) / 2 (m) P(m / m) = " 1+ cosθ %" 1+ cos φ % ' =ℓ N $ '$ # 1− cosθ &$# 1− cos φ '& e C= mAmB mA + mB (m) = (mm) + (mr) / 2 (r) = (rr) + (mr) / 2 Mw !I $ A = ln # o & = ε[c]ℓ "I% Io I mr = υ= P(m / mm) = (mmm) (mm) P(m / rm) = (mmr) (mr) P(m / mr) = 2(mrm) (mr) P(m / rr) = (mrr) 2(rr) 1" H" Abridged"Periodic"Table" 1.000" 6" R 2 = ℓ K N K = ℓ C∞ N ( 3 ! β $ − β 2 R2 P(R) = # & e " π% ) β= C" 3 2ℓ 2 N 7" N" 8" O" ( ) F" 12.101" 14.007" 15.999" 18.998" 14" 15" 16" 17" 30.974" 32.060" 35.453" 34" 35" Si" 28.085" P" S" Se" 3 ! β $ − β 2 R2 W (R)dR = # 4π R 2 dR & e " π% 9" 78.963" Cl" Br" 79.904" 53" I" 126.90" )