Download Emergency Telephone No: 800-424-9300

TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: BLACK
Revision Date: 01/29/01
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Part Number:
Family:
Company:
e-STUDIO6CP Toner Cartridge -- Black
15A3106
Contains Toner
Toshiba America Business Solutions, Inc.
2 Musick
Irvine, CA 92618-163
Emergency Telephone No: 800-424-9300
SECTION 2 - GENERAL COMPOSITION OF TONER CONTAINED IN CARTRIDGE
COMPONENT
PERCENT (wt.)
CAS#
OSHA PEL
ACGIH TLV
Polyester Resin
Polypropylene Wax
Organic Boron Comp.
Carbon Black
Amorphous Silica
80-90
0.5-5
0.1-3
3-10
<3
41259-36-3
9003-07-0
114803-11-1
1333-86-4
68909-20-6
(1)
(1)
(1)
3.5 mg/m3(2)
80 mg/ m3
%SiO2
(1)
(1)
(1)
3.5 mg/m3(2)
10 mg/ m3
Notes:
(1) Specific workplace limits have not been established.
(2) Total dust, measured as carbon black.
SECTION 3 - HAZARDS IDENTIFICATION
The following information is based on data obtained from testing of the product or similar
products and on the characteristics of component chemicals:
Primary Routes of Entry: Toner is contained in cartridge. Exposure potential includes
incidental inhalation of toner dust and possible minimal skin contact during cartridge change.
There is no evidence that toner is absorbed through the skin.
Signs and Symptoms of Exposure: Toner on skin or mucus membranes (mouth, eyes & nose).
Medical Conditions Aggravated by Exposure: None known at intended levels of use.
Exposure to high airborne dust concentrations, including toner, may aggravate existing
respiratory conditions.
Physical Hazards : As with most finely divided dusts, explosion is possible when extremely high
concentrations of dust and an ignition source are present. Not a hazard under normal conditions
of use.
Page 1 of 5
TOSHIBA
M ATERIAL SAFETY DATA SHEET
e-STUDIO6CP FUSER OIL BOTTLE
Revision Date: 02/13/01
SECTION 1 - CHEMICAL PRODUCTS AND COMPANY IDENTIFICATION
Name:
Part Number:
Chemical Family:
Product Use:
Fuser Oil Bottle
15W0906
Bottle contains dimethylpolysiloxane oil
Container of fuser oil for use in Toshiba e-STUDIO6CP printers
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENT
Dimethylpolysiloxane
Notes:
PERCENT
(wt.)
100
CAS#
No Hazardous
Materials Present
OSHA PEL
ACGIH TLV
(1)
(1) Specific work place exposure limits have not been established.
SECTION 3 - HAZARDS IDENTIFICATION
Primary Routes of Entry: Skin contact.
Signs and Symptoms of Exposure: Oily skin.
Medical Conditions Aggravated by Exposure: None known at intended levels of use.
Physical Hazards: Spills can cause surfaces to be slippery.
POTENTIAL HEALTH EFFECTS:
Inhalation:
Skin Contact:
Eye Contact:
Short Term Exposure
-
Long Term Exposure
Short Term Exposure
-
Long Term Exposure
-
Short Term Exposure
-
Long Term Exposure
-
Low vapor pressure, inhalation unlikely unless
oil mist inhaled. Exposure not probable with
intended use.
No adverse chronic effects known.
Slight skin irritation possible in sensitive
individuals. Significant exposure unlikely with
intended use.
No adverse chronic effects known. Significant
exposure not probable with intended use.
Slight, temporary irritation possible as with any
oil.
No adverse chronic effects known. Significant
exposure not probable with intended use.
Page 1 of 4
(1)
TOSHIBA
Ingestion:
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP FUSER OIL BOTTLE
Revision Date: 02/13/01
Short Term Exposure - Swallowing small amounts is not likely to cause
harm. Swallowing large amounts may cause
digestive discomfort. Exposure not probable
with intended use.
Long Term Exposure - No adverse chronic effects known. Exposure
not probable with intended use.
SECTION 4 - FIRST AID MEASURES
Inhalation: If symptoms, such as shortness of breath or coughing are experienced,
remove source of contamination and move individual to fresh air. If symptoms persist,
seek medical attention.
Skin Contact: Remove contaminated clothing. Wash affected area with soap and water.
Should irritation occur, seek medical attention.
Eye Contact: Flush immediately with plenty of water. Remove contact lenses and
continue flushing for at least 15 minutes. Seek medical attention if irritation develops
and persists.
Ingestion: If conscious, stomach contents may be diluted by drinking several glasses of
water. To avoid aspiration of oil, do not induce vomiting. Seek medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Expected to be > 200 o C (open cup) Autoignition: Not available
Extinguishing Media: Water spray or fog, dry chemical, CO2 or foam.
Firefighting: NIOSH approved self-contained breathing apparatus may be required if a
large amount of fuser oil is involved.
Unusual Fire and Explosion Hazard: None
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, formaldehyde
and unidentified organics.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Occupational Spill: Soak up the spill with absorbent material and place in a closed
container for disposal. Ensure the spill is completely cleaned up because the residue is
slippery.
SECTION 7 - HANDLING AND STORAGE
Store in a cool location.
Keep the lid closed tightly.
Do not lay container on its side.
2
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP FUSER OIL BOTTLE
Revision Date: 02/13/01
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits: None established
Ventilation: Mechanical room ventilation recommended.
Eye Protection: Safety glasses with side shields recommended.
Protective Clothing: None required for intended use in printer.
Gloves: Impervious gloves recommended when handling large quantities of this
material.
Respirator: None required for intended use in printer.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Description: Clear liquid with slight odor
Pressurized: No
% Volatility: Not applicable
pH: Not applicable
Vapor Density (Air = 1): Not available
Evaporation Rate: Negligible
Melting Point: Not available
Water Solubility: Negligible
o
o
Boiling Point: > 600 F (315 C) @ 760 mmHg
Vapor Pressure: Expected to be < 5 mmHg @ 77 o F (25 o C)
Specific Gravity (H2 0 =1): Expected to be approx. 0.97
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable under normal storage conditions
Conditions to Avoid: None known
Incompatibilities: Oxidizers
Hazardous Decomposition: Carbon dioxide, carbon monoxide, silicon dioxide,
formaldehyde and other organics.
Hazardous Polymerization: This product will not polymerize.
SECTION 11 - TOXICOLOGY INFORMATION
Acute Toxicity: Dimethylpolysiloxanes are practically biologically inert polymers. LD50
expected to be > 24 g/kg (oral, rat).
SECTION 12 - ECOLOGICAL INFORMATION
Environmental impact rating (0-4): Not available
Acute Aquatic Toxicity: Not available
Degradability: Not available
Log Bioconcentration Factor (BCF): Not available
Log Octanol/Water Partition Coefficient: Not available
3
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP FUSER OIL BOTTLE
Revision Date: 02/13/01
SECTION 13 - WASTE DISPOSAL INFORMATION
This product is not a listed or hazardous waste in accordance with Federal Regulation 40
CFR Part 261 or the Code of California Regulations Title 22. If discarded in its
purchased form, this product would not be a hazardous waste either by listing or by
characteristic. However, under US EPA RCRA, it is the responsibility of the product
user to determine at the time of disposal whether a material has been contaminated and
should be classified as a hazardous waste.
Disposal is subject to local, state and federal regulations. Federal regulations prohibit
disposal of liquid waste in municipal solid waste landfills. This material can be mixed
with a solid absorbent and then disposed of at a landfill.
SECTION 14 - TRANSPORTATION INFORMATION
This product is not regulated as a hazardous material by the DOT.
SECTION 15 - REGULATORY INFORMATION
All ingredients are registered under the Toxic Substances Control Act (TSCA) or under
polymer exemption.
All ingredients are registered or considered registered (polymers) under European
Inventory of Existing Commercial Chemical Substances (EINECS/ELINCS).
None of the product ingredients are listed as Emergency Planning and Community Right-toKnow Act (EPCRA) - Section 302: Extremely Hazardous Substances (EHS).
None of the product components are present above the minimum quantities of listed chemicals in
EPCRA Section 313 Supplier Notification.
This product contains no known materials at levels which the State of California has
found to cause cancer, birth defects or other reproductive harm - California Proposition
65.
SECTION 16 - OTHER
Disclaimer: Data are most current known to Toshiba at the time of preparation and are
believed to be accurate. No warranty as to their accuracy or completeness is expressed or
implied.
4
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: YELLOW
Revision Date: 02/09/01
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Part Number:
Family:
Company:
e-STUDIO6CP Toner Cartridge -- Yellow
15A3108
Contains Toner
Toshiba America Business Solutions, Inc.
2 Musick
Irvine, CA 92618-163
Emergency Telephone No: 800-424-9300
SECTION 2 - GENERAL COMPOSITION OF TONER CONTAINED IN CARTRIDGE
COMPONENT
PERCENT (wt.)
CAS#
OSHA PEL
ACGIH TLV
Polyester Resin
Polypropylene Wax
Organic Boron Comp.
Organic Pigment
Amorphous Silica
75-90
4-6
3-5
3-10
<3
(1)
9010-79-1
114803-11-1
4531-49-1
68611-44-9
7631-86-9
(2)
(2)
(2)
(2)
80 mg/ m3
%SiO2
(2)
(2)
(2)
(2)
10 mg/ m3
Notes:
(1) Trade secret or patented molecule (NJTSRN 80100252-5001)
(2) Specific workplace limits have not been established
SECTION 3 - HAZARDS IDENTIFICATION
The following information is based on data obtained from testing of the product or similar
products and on the characteristics of component chemicals:
Primary Routes of Entry: Toner is contained in cartridge. Exposure potential includes
incidental inhalation of toner dust and possible minimal skin contact during cartridge change.
There is no evidence that toner is absorbed through the skin.
Signs and Symptoms of Exposure: Toner on skin or mucus membranes (mouth, eyes & nose).
Medical Conditions Aggravated by Exposure: None known at intended levels of use.
Exposure to high airborne dust concentrations, including toner, may aggravate existing
respiratory conditions.
Physical Hazards : As with most finely divided dusts, explosion is possible when extremely high
concentrations of dust and an ignition source are present. Not a hazard under normal conditions
of use.
Page 1 of 5
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: YELLOW
Revision Date: 02/09/01
POTENTIAL HEALTH EFFECTS:
Short Term Exposure
Inhalation:
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low inhalation toxicity. As with
exposure to high concentrations of any dust,
minimal respiratory tract irritation may occur
if excessive amounts of toner dust are inhaled.
Exposure not probable with intended use.
No adverse chronic effects known at expected
levels of use. Exposure not probable with
intended use.
Skin Contact:
Eye Contact:
Ingestion:
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate this toner is not a skin irritant and is of
low dermal toxicity. Toner is not a dermal
sensitizer. Exposure not probable with
intended use.
Rare individuals may note skin rash with
repeated contact. Exposure not probable with
intended use.
Toner may act as a mechanical irritant.
Exposure not probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low oral toxicity. Exposure not
probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
SECTION 4 - FIRST AID MEASURES
Inhalation: If symptoms, such as shortness of breath or persistent coughing are experienced,
remove source of contamination and move individual to fresh air. If symptoms persist, seek
medical attention.
Skin Contact: Wash affected area with soap and water. Should irritation occur, seek medical
attention.
Eye Contact: Do not rub eyes. Flush immediately with plenty of water. Remove contact
lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation develops
and persists.
Ingestion: If conscious, immediately wash mouth out with plenty of water. Seek medical
attention.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: YELLOW
Revision Date: 02/09/01
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not applicable
Autoignition: Not available
Lower Flammability Limit: 34.5 g/m3
Extinguishing Media: CO2 , water spray or fog, dry chemical, or foam.
Firefighting: NIOSH approved self-contained breathing apparatus may be required if a large
number of cartridges are involved.
Fire and Explosion Hazard: Like many finely divided materials, toner dust, in high
concentrations can form an explosive mixture in air which, if ignited, could result in a dust
explosion.
Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: High concentrations can form an explosive mixture in air which,
if ignited, could result in dust explosion.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, phenol derivatives and
low molecular weight organics.
NFPA Ratings (Scale 0 – 4)
Health = 1
Fire = 1
Reactivity = 0
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Occupational Spill: If a dust cloud is possible due to spills involving a large number of
cartridges, remove all sources of ignition such as open sparks, flames or static discharge to
prevent the ignition of the dust. Minimize dust generation during clean up. Sweep up spill with
non-metallic broom and dustpan. To avoid possible dust explosion, do not use vacuum cleaners
to cleanup spills. Contain for disposal. Oil permeated sweeping compound may assist in the
cleanup of large amounts of toner spilled on nonporous surfaces.
SECTION 7 - HANDLING AND STORAGE
Store away from oxidizing materials.
When handling, minimize generation of dust. Supply adequate ventilation.
STORE IN A COOL, DRY PLACE [below 95o F (35o C) recommended to prevent caking].
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation:
Eye Protection:
Protective Clothing:
Gloves:
Mechanical room ventilation is recommended.
None required for intended use in printer.
None required for intended use in printer.
None required for intended use in printer.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: YELLOW
Revision Date: 02/09/01
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Description: Cartridge contains toner; finely divided yellow solid with plastic-like odor.
Melting Point: Not available
Softening Point: 95-101o C
Pressurized: No
Boiling Point: Not applicable
pH: Not applicable
Specific Gravity (H20 = 1): 1.16 @ 20o C
Evaporation Rate: Not applicable, solid
Water Solubility: Insoluble
% Volatility: Not applicable, solid
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: Combustible atmospheres of toner dust. Ignition sources, excessive heat,
sparks and open flame.
Incompatibilities: Strong oxidizers, acids, and alkalines.
Hazardous Decomposition: Carbon dioxide, carbon monoxide, nitrogen oxides, phenol
derivatives and unidentified organics.
Hazardous Polymerization: This product will not polymerize.
SECTION 11 - TOXICOLOGY INFORMATION
Acute Toxicity: Not expected to be acutely toxic: LD50 (oral, rat) expected to be >2000 mg/kg,
based on data from similar toners.
Chronic Toxicity: Not expected to be chronically toxic. Industry tests on similar generic toner
showed no signs of overt toxicity. Rats exposed to high levels of toner showed a chronic
inflammatory response and a mild to moderate degree of lung fibrosis. There were no pulmonary
changes of any type at the lower toner exposure level, which is most relevant in regard to
potential human exposures. Toner is not listed by IARC, NTP, or OSHA.
SECTION 12 - ECOLOGICAL INFORMATION
Environmental Impact rating (0-4): Not available
Acute Aquatic Toxicity: Not available
Degradability: Not available
Log Bioconcentration Factor (BCF): Not available
Log Octanol/Water Partition Coefficient: Not available
SECTION 13 - DISPOSAL INFORMATION
If discarded, this product is not a hazardous waste either by listing or by characteristic. However,
it is the responsibility of the product user to determine at the time of disposal whether a material
has been contaminated and should be classified as a hazardous waste. Disposal is subject to
national and provincial regulations.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: YELLOW
Revision Date: 02/09/01
SECTION 14 - TRANSPORTATION INFORMATION
This product is not regulated as a hazardous material by the DOT.
SECTION 15 - REGULATORY INFORMATION
All ingredients are registered under the Toxic Substances Control Act (TSCA) or under
polymer exemption.
All ingredients are exempt, registered or considered registered (polymers) under the European
Inventory of Existing Commercial Chemical Substances (EINECS/ELINCS).
All ingredients are exempt, registered or considered registered (polymers) under the Canadian
Domestic Substances List (DSL/NDSL).
None of the product ingredients are listed as Emergency Planning and Community Right-toKnow Act (EPCRA) - Section 302: Extremely Hazardous Substances (EHS).
None of the product components are present above the minimum quantities of listed chemicals in
EPCRA Section 313 Supplier Notification.
This product contains no known materials which the State of California has found to cause
cancer, birth defects or other reproductive harm -California Proposition 65.
SECTION 16 - OTHER
Disclaimer: Data is most current known to Toshiba at the time of preparation and is believed to
be accurate. No warranty as to its accuracy or completeness is expressed or implied.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: MAGENTA
Revision Date: 02/09/01
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Part Number:
Family:
Company:
e-STUDIO6CP Toner Cartridge --- Magenta
15A3109
Contains toner
Toshiba America Business Solutions, Inc.
2 Musick
Irvine, CA 92618-163
Emergency Telephone No: 800-424-9300
SECTION 2 - GENERAL COMPOSITION OF TONER CONTAINED IN CARTRIDGE
COMPONENT
PERCENT(wt.)
CAS#
Polyester Resin
Polypropylene Wax
Organic Boron Compound
Organic Pigment
Amorphous Silica
75-90
0.5-5
0.1-3
3-10
<3
41259-36-3
9003-07-0
114803-11-1
980-26-7
68909-20-6
OSHA PEL
(1)
(1)
66(1)
(1)
80 mg/ m3
%SiO2
ACGIH TLV
(1)
(1)
(1)
(1)
10 mg/ m3
Notes: (1) Specific workplace limits have not been established.
SECTION 3 - HAZARDS IDENTIFICATION
The following information is based on data obtained from testing of the product or similar
products and on the characteristics of component chemicals:
Primary Routes of Entry: Toner is contained in cartridge. Exposure potential includes
incidental inhalation of toner dust and possible minimal skin contact during cartridge change.
There is no evidence that toner is absorbed through the skin.
Signs and Symptoms of Exposure: Toner on skin or mucus membranes (mouth, eyes & nose).
Medical Conditions Aggravated by Exposure: None known at intended levels of use.
Exposure to high airborne dust concentrations, including toner, may aggravate existing
respiratory conditions.
Physical Hazards : As with most finely divided dusts, explosion is possible when extremely high
concentrations of dust and an ignition source are present. Not a hazard under normal conditions
of use.
Page 1 of 5
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: MAGENTA
Revision Date: 02/09/01
POTENTIAL HEALTH EFFECTS:
Short Term Exposure
Inhalation:
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low inhalation toxicity. As with
exposure to high concentrations of any dust,
minimal respiratory tract irritation may occur
if excessive amounts of toner dust are inhaled.
Exposure not probable with intended use.
No adverse chronic effects known at expected
levels of use. Exposure not probable with
intended use.
Skin Contact:
Eye Contact:
Ingestion:
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate this toner is not a skin irritant and is of
low dermal toxicity. Toner is not a dermal
sensitizer. Exposure not probable with
intended use.
Rare individuals may note skin rash with
repeated contact. Exposure not probable with
intended use.
Toner may act as a mechanical irritant.
Exposure not probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low oral toxicity. Exposure not
probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
SECTION 4 - FIRST AID MEASURES
Inhalation: If symptoms, such as shortness of breath or persistent coughing are experienced,
remove source of contamination and move individual to fresh air. If symptoms persist, seek
medical attention.
Skin Contact: Wash affected area with soap and water. Should irritation occur, seek medical
attention.
Eye Contact: Do not rub eyes. Flush immediately with plenty of water. Remove contact
lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation develops
and persists.
Ingestion: If conscious, immediately wash mouth out with plenty of water. Seek medical
attention.
Advice to Doctor: There are no specific antidotes. Milk or water may be given to dilute the
product.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: MAGENTA
Revision Date: 02/09/01
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not applicable
Autoignition: Not available
Flammability Limits (%): Not applicable
Extinguishing Media: CO2 , water spray or fog, dry chemical, or foam.
Firefighting: NIOSH approved self-contained breathing apparatus may be required if a large
number of cartridges are involved.
Fire and Explosion Hazard: Like many finely divided materials, toner dust, in high
concentrations can form an explosive mixture in air which, if ignited, could result in a dust
explosion.
Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: High concentrations can form an explosive mixture in air which,
if ignited, could result in dust explosion.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, and low molecular
weight organics.
NFPA Ratings (Scale 0 – 4)
Health = 1
Fire = 1
Reactivity = 0
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Occupational Spill: If a dust cloud is possible due to spills involving a large number of
cartridges, remove all sources of ignition such as open sparks, flames or static discharge to
prevent the ignition of the dust. Minimize dust generation during clean up. Sweep up spill with
non-metallic broom and dustpan. To avoid possible dust explosion, do not use vacuum cleaners
to cleanup spills. Contain for disposal. Oil permeated sweeping compound may assist in the
cleanup of large amounts of toner spilled on nonporous surfaces.
SECTION 7 - HANDLING AND STORAGE
Store away from oxidizing materials.
When handling, minimize generation of dust. Supply adequate ventilation.
STORE IN A COOL, DRY PLACE.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation:
Eye Protection:
Protective Clothing:
Gloves:
Mechanical room ventilation is recommended.
None required for intended use in printer.
None required for intended use in printer.
None required for intended use in printer.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: MAGENTA
Revision Date: 02/09/01
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Description: Cartridge contains toner; finely divided magenta solid with plastic-like odor.
Melting Point: Not available
Softening Point: 95-110o C
Pressurized: No
Boiling Point: Not applicable
pH: Not applicable
Specific Gravity (H20 = 1): 1.1
Evaporation Rate: Not applicable, solid
Water Solubility: Insoluble
% Volatility: Not applicable, solid
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: Combustible atmospheres of toner dust. Ignition sources, excessive heat,
sparks and open flame.
Incompatibilities: Strong oxidizers, acids, or alkalines.
Hazardous Decomposition: Carbon dioxide, carbon monoxide, nitrogen oxides, phenol
derivatives and unidentified organics.
Hazardous Polymerization: This product will not polymerize.
SECTION 11 - TOXICOLOGY INFORMATION
Acute Toxicity: Not expected to be acutely toxic: LD50 (oral, rat) and LC50 (inhalation, rat)
expected to be >5000 mg/kg, based on data from similar toners.
Chronic Toxicity: Not expected to be chronically toxic. Industry tests on similar generic toner
showed no signs of overt toxicity. Rats exposed to high levels of toner showed a chronic
inflammatory response and a mild to moderate degree of lung fibrosis. There were no pulmonary
changes of any type at the lower toner exposure level, which is most relevant in regard to
potential human exposures. Toner is not listed by IARC, NTP, or OSHA.
SECTION 12 - ECOLOGICAL INFORMATION
Environmental Impact rating (0-4): Not available
Acute Aquatic Toxicity: Not available
Degradability: Not available
Log Bioconcentration Factor (BCF): Not available
Log Octanol/Water Partition Coefficient: Not available
SECTION 13 - DISPOSAL INFORMATION
If discarded, this product is not a hazardous waste either by listing or by characteristic. However,
it is the responsibility of the product user to determine at the time of disposal whether a material
has been contaminated and should be classified as a hazardous waste. Disposal is subject to
national and provincial regulations.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: MAGENTA
Revision Date: 02/09/01
SECTION 14 - TRANSPORTATION INFORMATION
This product is not regulated as a hazardous material by the DOT.
SECTION 15 - REGULATORY INFORMATION
All ingredients are registered under the Toxic Substances Control Act (TSCA) or under
polymer exemption.
All ingredients are exempt, registered or considered registered (polymers) under the European
Inventory of Existing Commercial Chemical Substances (EINECS/ELINCS).
All ingredients are exempt, registered or considered registered (polymers) under the Canadian
Domestic Substances List (DSL/NDSL).
None of the product ingredients are listed as Emergency Planning and Community Right-toKnow Act (EPCRA) - Section 302: Extremely Hazardous Substances (EHS).
None of the product components are present above the minimum quantities of listed chemicals in
EPCRA Section 313 Supplier Notification.
This product contains no known materials which the State of California has found to cause
cancer, birth defects or other reproductive harm -California Proposition 65.
SECTION 16 - OTHER
Disclaimer: Data is most current known to Toshiba at the time of preparation and is believed to
be accurate. No warranty as to its accuracy or completeness is expressed or implied.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: CYAN
Revision Date: 02/09/01
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
P/N:
Chemical Family:
Company:
Toshiba e-STUDIO6CP Toner Cartridge --- Cyan
15A3107
Contains toner
Toshiba America Business Solutions, Inc.
2 Musick
Irvine, CA 92618-1631
Emergency Telephone No: 800-424-9300
SECTION 2 - GENERAL COMPOSITION OF TONER CONTAINED IN CARTRIDGE
COMPONENT
Polyester Resin
Polypropylene Wax
Organic Boron Compound
Organic Pigment
Amorphous Silica
Notes:
PERCENT (WT.)
75-90
4-6
3-5
3-10
<3
CAS#
OSHA PEL
ACGIH TLV
(1)
9010-79-1
114803-11-1
147-14-8
68611-44-9
7631-86-9
(2)
(2)
(2)
(2)
80 mg/ m3
%SiO2
(2)
(2)
(2)
(2)
10 mg/ m3
(1) Trade secret or patented molecule (NJTSRN 80100252-5001)
(2) Specific workplace limits have not been established
SECTION 3 - HAZARDS IDENTIFICATION
The following information is based on data obtained from testing of the product or similar
products and on the characteristics of component chemicals:
Primary Routes of Entry: Toner is contained in cartridge. Exposure potential includes
incidental inhalation of toner dust and possible minimal skin contact during cartridge change.
There is no evidence that toner is absorbed through the skin.
Signs and Symptoms of Exposure: Toner on skin or mucus membranes (mouth, eyes & nose).
Medical Conditions Aggravated by Exposure: None known at intended levels of use.
Exposure to high airborne dust concentrations, including toner, may aggravate existing
respiratory conditions.
Physical Hazards : As with most finely divided dusts, explosion is possible when extremely high
concentrations of dust and an ignition source are present. Not a hazard under normal conditions
of use.
Page 1 of 5
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: CYAN
POTENTIAL HEALTH EFFECTS:
Short Term Exposure
Inhalation:
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low inhalation toxicity. As with
exposure to high concentrations of any dust,
minimal respiratory tract irritation may occur
if excessive amounts of toner dust are inhaled.
Exposure not probable with intended use.
No adverse chronic effects known at expected
levels of use. Exposure not probable with
intended use.
Skin Contact:
Eye Contact:
Ingestion:
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate this toner is not a skin irritant and is of
low dermal toxicity. Toner is not a dermal
sensitizer. Exposure not probable with
intended use.
Rare individuals may note skin rash with
repeated contact. Exposure not probable with
intended use.
Toner may act as a mechanical irritant.
Exposure not probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low oral toxicity. Exposure not
probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
SECTION 4 - FIRST AID MEASURES
Inhalation: If symptoms, such as shortness of breath or persistent coughing are experienced,
remove source of contamination and move individual to fresh air. If symptoms persist, seek
medical attention.
Skin Contact: Wash affected area with soap and water. Should irritation occur, seek medical
attention.
Eye Contact: Do not rub eyes. Flush immediately with plenty of water. Remove contact
lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation develops
and persists.
Ingestion: If conscious, immediately wash mouth out with plenty of water. Seek medical
attention.
Page 2 of 5
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: CYAN
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not applicable
Autoignition: Not available
Flammability Limits (%): Not applicable
Extinguishing Media: CO2 , water spray or fog, dry chemical, or foam.
Firefighting: NIOSH approved self-contained breathing apparatus may be required if a large
number of cartridges are involved.
Fire and Explosion Hazard: Like many finely divided materials, toner dust, in high
concentrations can form an explosive mixture in air which, if ignited, could result in a dust
explosion.
Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: High concentrations can form an explosive mixture in air which,
if ignited, could result in dust explosion.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, nitrogen oxides, phenol
derivatives and low molecular weight organics.
NFPA Ratings (Scale 0 – 4)
Health = 1
Fire = 1
Reactivity = 0
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Occupational Spill: If a dust cloud is possible due to spills involving a large number of
cartridges, remove all sources of ignition such as open sparks, flames or static discharge to
prevent the ignition of the dust. Minimize dust generation during clean up. Sweep up spill with
non-metallic broom and dustpan. To avoid possible dust explosion, do not use vacuum cleaners
to cleanup spills. Contain for disposal. Oil permeated sweeping compound may assist in the
cleanup of large amounts of toner spilled on nonporous surfaces.
SECTION 7 - HANDLING AND STORAGE
Store away from oxidizing materials.
When handling, minimize generation of dust. Supply adequate ventilation.
STORE IN A COOL, DRY PLACE [below 95o F (35o C) recommended to prevent caking].
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation:
Eye Protection:
Protective Clothing:
Gloves:
Mechanical room ventilation is recommended.
None required for intended use in printer.
None required for intended use in printer.
None required for intended use in printer.
T
Page 1 of 35˜˜
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: CYAN
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Description: Cartridge contains toner; finely divided cyan solid with plastic-like odor.
Melting Point: Not available
Softening Point: 95-101o C
Pressurized: No
Boiling Point: Not applicable
pH: Not applicable
Specific Gravity (H20 = 1): 1.16 @ 20o C
Evaporation Rate: Not applicable, solid
Water Solubility: Insoluble
% Volatility: Not applicable, solid
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: Combustible atmospheres of toner dust. Ignition sources, excessive heat,
sparks and open flame.
Incompatibilities: Strong oxidizers, acids, and alkalines.
Hazardous Decomposition: Carbon dioxide, carbon monoxide, phenol derivatives and
unidentified organics.
Hazardous Polymerization: This product will not polymerize.
SECTION 11 - TOXICOLOGY INFORMATION
Acute Toxicity: Not expected to be acutely toxic: LD50 (oral, rat) expected to be >2000 mg/kg,
based on data from similar toners.
Chronic Toxicity: Not expected to be chronically toxic. Industry tests on similar generic toner
showed no signs of overt toxicity. Rats exposed to high levels of toner showed a chronic
inflammatory response and a mild to moderate degree of lung fibrosis. There were no pulmonary
changes of any type at the lower toner exposure level, which is most relevant in regard to
potential human exposures. Toner is not listed by IARC, NTP, or OSHA.
SECTION 12 - ECOLOGICAL INFORMATION
Environmental Impact rating (0-4): Not available
Acute Aquatic Toxicity: Not available
Degradability: Not available
Log Bioconcentration Factor (BCF): Not available
Log Octanol/Water Partition Coefficient: Not available
SECTION 13 - DISPOSAL INFORMATION
If discarded, this product is not a hazardous waste either by listing or by characteristic. However,
it is the responsibility of the product user to determine at the time of disposal whether a material
has been contaminated and should be classified as a hazardous waste. Disposal is subject to
national and provincial regulations.
page 4 of 5
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: CYAN
SECTION 14 - TRANSPORTATION INFORMATION
This product is not regulated as a hazardous material by the DOT.
SECTION 15 - REGULATORY INFORMATION
All ingredients are registered under the Toxic Substances Control Act (TSCA) or under
polymer exemption.
All ingredients are exempt, registered or considered registered (polymers) under the European
Inventory of Existing Commercial Chemical Substances (EINECS/ELINCS).
All ingredients are exempt, registered or considered registered (polymers) under the Canadian
Domestic Substances List (DSL/NDSL).
None of the product ingredients are listed as Emergency Planning and Community Right-toKnow Act (EPCRA) - Section 302: Extremely Hazardous Substances (EHS).
None of the product components are present above the minimum quantities of listed chemicals in
EPCRA Section 313 Supplier Notification.
This product contains no known materials which the State of California has found to cause
cancer, birth defects or other reproductive harm -California Proposition 65.
SECTION 16 - OTHER
Disclaimer: Data is most current known to Toshiba at the time of preparation and is believed to
be accurate. No warranty as to its accuracy or completeness is expressed or implied.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: BLACK
Revision Date: 01/29/01
POTENTIAL HEALTH EFFECTS:
Short Term Exposure
Inhalation:
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Short Term Exposure
--
Long Term Exposure
--
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low inhalation toxicity. As with
exposure to high concentrations of any dust,
minimal respiratory tract irritation may occur
if excessive amounts of toner dust are inhaled.
Exposure not probable with intended use.
No adverse chronic effects known at expected
levels of use. Exposure not probable with
intended use.
Skin Contact:
Eye Contact:
Ingestion:
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate this toner is not a skin irritant and is of
low dermal toxicity. Toner is not a dermal
sensitizer. Exposure not probable with
intended use.
Rare individuals may note skin rash with
repeated contact. Exposure not probable with
intended use.
Toner may act as a mechanical irritant.
Exposure not probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
Testing and/or information on this or similar
toners, or on the constituents of this toner
indicate low oral toxicity. Exposure not
probable with intended use.
No adverse chronic effects known. Exposure
not probable with intended use.
SECTION 4 - FIRST AID MEASURES
Inhalation: If symptoms, such as shortness of breath or persistent coughing are experienced,
remove source of contamination and move individual to fresh air. If symptoms persist, seek
medical attention.
Skin Contact: Wash affected area with soap and water. Should irritation occur, seek medical
attention.
Eye Contact: Do not rub eyes. Flush immediately with plenty of water. Remove contact
lenses and continue flushing for at least 15 minutes. Seek medical attention if irritation develops
and persists.
Ingestion: If conscious, immediately wash mouth out with plenty of water. Seek medical
attention.
Advice to Doctor: There are no specific antidotes. Milk or water may be given to dilute the
product.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: BLACK
Revision Date: 01/29/01
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not applicable
Autoignition: Not available
Flammability Limits (%): Not applicable
Extinguishing Media: CO2 , water spray or fog, dry chemical, or foam.
Firefighting: NIOSH approved self-contained breathing apparatus may be required if a large
number of cartridges are involved.
Fire and Explosion Hazard: Like many finely divided materials, toner dust, in high
concentrations can form an explosive mixture in air which, if ignited, could result in a dust
explosion.
Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: High concentrations can form an explosive mixture in air which,
if ignited, could result in dust explosion.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, and low molecular
weight organics.
NFPA Ratings (Scale 0 – 4)
Health = 1
Fire = 1
Reactivity = 0
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Occupational Spill: If a dust cloud is possible due to spills involving a large number of
cartridges, remove all sources of ignition such as open sparks, flames or static discharge to
prevent the ignition of the dust. Minimize dust generation during clean up. Sweep up spill with
non-metallic broom and dustpan. To avoid possible dust explosion, do not use vacuum cleaners
to cleanup spills. Contain for disposal. Oil permeated sweeping compound may assist in the
cleanup of large amounts of toner spilled on nonporous surfaces.
SECTION 7 - HANDLING AND STORAGE
Store away from oxidizing materials.
When handling, minimize generation of dust. Supply adequate ventilation.
STORE IN A COOL, DRY PLACE.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation:
Eye Protection:
Protective Clothing:
Gloves:
Mechanical room ventilation is recommended.
None required for intended use in printer.
None required for intended use in printer.
None required for intended use in printer.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: BLACK
Revision Date: 01/29/01
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Description: Cartridge contains toner; finely divided black solid with plastic-like odor.
Melting Point: Not available
Softening Point: 95-110o C
Pressurized: No
Boiling Point: Not applicable
pH: Not applicable
Specific Gravity (H20 = 1): 1.1
Evaporation Rate: Not applicable, solid
Water Solubility: Insoluble
% Volatility: Not applicable, solid
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: Combustible atmospheres of toner dust. Ignition sources, excessive heat,
sparks and open flame.
Incompatibilities: Strong oxidizers
Hazardous Decomposition: Carbon dioxide, carbon monoxide, and unidentified organics.
Hazardous Polymerization: This product will not polymerize.
SECTION 11 - TOXICOLOGY INFORMATION
Acute Toxicity: Not expected to be acutely toxic: LD50 (oral, rat) and LC50 (inhalation, rat)
expected to be >5000 mg/kg, based on data from similar toners.
Chronic Toxicity: Not expected to be chronically toxic. Industry tests on similar generic toner
showed no signs of overt toxicity. Rats exposed to high levels of toner showed a chronic
inflammatory response and a mild to moderate degree of lung fibrosis. There were no pulmonary
changes of any type at the lower toner exposure level, which is most relevant in regard to
potential human exposures. Pure carbon black, a minor component of this toner, has been listed
by IARC as a group 2B (possible carcinogen) based on rat “lung particulate overload” studies.
Toner is not listed by IARC, NTP, or OSHA.
SECTION 12 - ECOLOGICAL INFORMATION
Environmental Impact rating (0-4): Not available
Acute Aquatic Toxicity: Not available
Degradability: Not available
Log Bioconcentration Factor (BCF): Not available
Log Octanol/Water Partition Coefficient: Not available
SECTION 13 - DISPOSAL INFORMATION
If discarded, this product is not a hazardous waste either by listing or by characteristic. However,
it is the responsibility of the product user to determine at the time of disposal whether a material
has been contaminated and should be classified as a hazardous waste. Disposal is subject to
national and provincial regulations.
TOSHIBA
MATERIAL SAFETY DATA SHEET
e-STUDIO6CP TONER CARTRIDGE: BLACK
Revision Date: 01/29/01
SECTION 14 - TRANSPORTATION INFORMATION
This product is not regulated as a hazardous material by the DOT.
SECTION 15 - REGULATORY INFORMATION
All ingredients are registered under the Toxic Substances Control Act (TSCA) or under
polymer exemption.
All ingredients are exempt, registered or considered registered (polymers) under the European
Inventory of Existing Commercial Chemical Substances (EINECS/ELINCS).
All ingredients are exempt, registered or considered registered (polymers) under the Canadian
Domestic Substances List (DSL/NDSL).
None of the product ingredients are listed as Emergency Planning and Community Right-toKnow Act (EPCRA) - Section 302: Extremely Hazardous Substances (EHS).
None of the product components are present above the minimum quantities of listed chemicals in
EPCRA Section 313 Supplier Notification.
This product contains no known materials which the State of California has found to cause
cancer, birth defects or other reproductive harm -California Proposition 65.
SECTION 16 - OTHER
Disclaimer: Data is most current known to Toshiba at the time of preparation and is believed to
be accurate. No warranty as to its accuracy or completeness is expressed or implied.