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Ultrafast electron dynamics in metallic quantum well nanostructures Using femtosecond time-resolved two-photon photoemission (2PPE) we analyze hot electron lifetimes in Pb films on Si(111). In this system occupied and unoccupied electronic quantum well states disperse with Pb coverage characteristically as seen in the figure. There the 1PPE and 2PPE intensity is depicted for occupied and unoccupied states, respectively.