Download CSIR NET CHEMITRY SYLLABUS

CSIR NET CHEMITRY SYLLABUS
The syllabus for CSIR NET and GATE exams including other exams for Ph.D entrance
exams is almost same. The common syllabus for both part B & C of CSIR NET exam in
chemical sciences is given below.
Inorganic Chemistry :
1. Chemical periodicity
2. Structure and bonding in homo- and heteronuclear molecules, including shapes of
molecules (VSEPR Theory).
3. Concepts of acids and bases, Hard-Soft acid base concept, Non-aqueous solvents.
4. Main group elements and their compounds: Allotropy, synthesis, structure and
bonding, industrial importance of the compounds.
5. Transition elements and coordination compounds: structure, bonding theories, spectral
and magnetic properties, reaction mechanisms.
6. Inner transition elements: spectral and magnetic properties, redox chemistry, analytical
applications.
7. Organometallic compounds: synthesis, bonding and structure, and reactivity.
Organometallics in homogeneous catalysis.
8. Cages and metal clusters.
9. Analytical chemistry- separation, spectroscopic, electro- and thermoanalytical
methods.
10. Bioinorganic chemistry: photosystems, porphyrins, metalloenzymes, oxygen
transport, electron- transfer reactions; nitrogen fixation, metal complexes in medicine.
11. Characterization of inorganic compounds by IR, Raman, NMR, EPR, Mössbauer,
UV-vis, NQR, MS, electron spectroscopy and microscopic techniques.
12. Nuclear chemistry: nuclear reactions, fission and fusion, radio-analytical techniques
and activation analysis.
Physical Chemistry:
1. Basic principles of quantum mechanics: Postulates; operator algebra; exactly- solvable
systems: particle-in-a-box, harmonic oscillator and the hydrogen atom, including shapes
of atomic orbitals; orbital and spin angular momenta; tunneling.
2. Approximate methods of quantum mechanics: Variational principle; perturbation
theory up to second order in energy; applications.
3. Atomic structure and spectroscopy; term symbols; many-electron systems and antisymmetry principle.
4. Chemical bonding in diatomics; elementary concepts of MO and VB theories; Huckel
theory for conjugated p-electron systems.
5. Chemical applications of group theory; symmetry elements; point groups; character
tables; selection rules.
6. Molecular spectroscopy: Rotational and vibrational spectra of diatomic molecules;
electronic spectra; IR and Raman activities – selection rules; basic principles of magnetic
resonance.
7. Chemical thermodynamics: Laws, state and path functions and their applications;
thermodynamic description of various types of processes; Maxwell’s relations;
spontaneity and equilibria; temperature and pressure dependence of thermodynamic
quantities; Le Chatelier principle; elementary description of phase transitions; phase
equilibria and phase rule; thermodynamics of ideal and non-ideal gases, and solutions.
8. Statistical thermodynamics: Boltzmann distribution; kinetic theory of gases; partition
functions and their relation to thermodynamic quantities – calculations for model
systems.
9. Electrochemistry: Nernst equation, redox systems, electrochemical cells; DebyeHuckel
theory; electrolytic conductance – Kohlrausch’s law and its applications; ionic equilibria;
conductometric and potentiometric titrations.
10. Chemical kinetics: Empirical rate laws and temperature dependence; complex
reactions; steady state approximation; determination of reaction mechanisms; collision
and transition state theories of rate constants; unimolecular reactions; enzyme kinetics;
salt effects; homogeneous catalysis; photochemical reactions.
11. Colloids and surfaces: Stability and properties of colloids; isotherms and surface area;
heterogeneous catalysis.
12. Solid state: Crystal structures; Bragg’s law and applications; band structure of solids.
13. Polymer chemistry: Molar masses; kinetics of polymerization.
14. Data analysis: Mean and standard deviation; absolute and relative errors; linear
regression; covariance and correlation coefficient.
Organic Chemistry:
1. IUPAC nomenclature of organic molecules including regio- and stereoisomers.
2. Principles of stereochemistry: Configurational and conformational isomerism in
acyclic and cyclic compounds; stereogenicity, stereoselectivity, enantioselectivity,
diastereoselectivity and asymmetric induction.
3. Aromaticity: Benzenoid and non-benzenoid compounds – generation and reactions.
4. Organic reactive intermediates: Generation, stability and reactivity of carbocations,
carbanions, free radicals, carbenes, benzynes and nitrenes.
5. Organic reaction mechanisms involving addition, elimination and substitution
reactions with electrophilic, nucleophilic or radical species. Determination of reaction
pathways.
6. Common named reactions and rearrangements – applications in organic synthesis.
7. Organic transformations and reagents: Functional group interconversion including
oxidations and reductions; common catalysts and reagents (organic, inorganic,
organometallic and enzymatic). Chemo, regio and stereoselective transformations.
8. Concepts in organic synthesis: Retrosynthesis, disconnection, synthons, linear and
convergent synthesis, umpolung of reactivity and protecting groups.
9. Asymmetric synthesis: Chiral auxiliaries, methods of asymmetric induction –
substrate, reagent and catalyst controlled reactions; determination of enantiomeric and
diastereomeric excess; enantio-discrimination. Resolution – optical and kinetic.
10. Pericyclic reactions – electrocyclization, cycloaddition, sigmatropic rearrangements
and other related concerted reactions. Principles and applications of photochemical
reactions in organic chemistry.
11. Synthesis and reactivity of common heterocyclic compounds containing one or two
hetero atoms (O, N, S).
12. Chemistry of natural products: Carbohydrates, proteins and peptides, fatty acids,
nucleic acids, terpenes, steroids and alkaloids. Biogenesis of terpenoids and alkaloids.
13. Structure determination of organic compounds by IR, UV-Vis, 1 H & 13 C NMR and
Mass spectroscopic techniques.
Interdisciplinary topics:
1. Chemistry in nanoscience and technology.
2. Catalysis and green chemistry.
3. Medicinal chemistry.
4. Supramolecular chemistry.
5. Environmental chemistry.