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Itaru Nakamura
Publication List (03/2013)
1. Palladium Catalyzed Alkylative Dimerization between Pronucleophiles and Vinyltins
Itaru Nakamura, Naofumi Tsukada, Mohammad Al-Masum, and Yoshinori Yamamoto
J. Chem. Soc., Chem. Commun. 1997, 1583-1584.
2. Ring Opening in the Palladium-Catalyzed Hydrocarbonation of Methylenecyclopropanes with Pronucleophiles
Naofumi Tsukada, Akinori Shibuya, Itaru Nakamura, and Yoshinori Yamamoto
J. Am. Chem. Soc. 1997, 119, 8123-8124.
3. Ring Opening in the Hydroamination of Methylenecyclopropanes Catalyzed by Palladium
Itaru Nakamura, Hitoshi Itagaki, and Yoshinori Yamamoto
J. Org. Chem. 1998, 63, 6458-6459.
4. Inter- and Intramolecular Palladium-Catalyzed Hydrocarbonation of Methylenecyclopropanes with Carbon
Pronucleophiles
Naofumi Tsukada, Akinori, Shibuya, Itaru Nakamura, Haruo Kitahara, and Yoshinori Yamamoto
Tetrahedron 1999, 55, 8833-8844.
5. Palladium-Catalyzed Hydroalkoxylation of Methylenecyclopropanes
Drexel Camacho, Itaru Nakamura, Shinichi Saito, and Yoshinori Yamamoto
Angew. Chem. Int. Ed. 1999, 38, 3365-3367.
6. Hydrofurylation of Alkylidenecyclopropanes Catalyzed by Palladium
Itaru Nakamura, Shinichi Saito, and Yoshinori Yamamoto
J. Am. Chem. Soc. 2000, 122, 2661.
7. Palladium-Catalyzed Addition of Alcohol Pronucleophiles to Alkylidenecyclopropanes
Drexel Camacho, Itaru Nakamura, Shinichi Saito, and Yoshinori Yamamoto
J. Org. Chem. 2001, 66, 270-275.
8. Novel [3+2] Cycloaddition of Alkylidenecyclopropanes with Aldehydes Catalyzed by Palladium
Itaru Nakamura, Byoung Ho Oh, Shinichi Saito, Yoshinori Yamamoto
Angew. Chem. Int. Ed. 2001, 40, 1298-1300.
9. Palladium-Catalyzed [3+2] Cycloaddition of Alkylidenecyclopropanes with Imines
B.-H. Oh, I. Nakamura, S. Saito, Y. Yamamoto,
Tetrahedron Lett. 2001, 42, 6203-6205.
10. Palladium-Catalyzed Inter- and Intramolecular Hydroamination of Methylenecyclopropanes with Amines
Itaru Nakamura, Hitoshi Itagaki, Yoshinori Yamamoto
Chemistry of Heterocyclic Compounds, 2001, 12, 1684-1692.
11. Palladium-catalyzed addition of ketones to alkylidenecyclopropanes.
Drexel H. Camacho, Itaru Nakamura, Byoung Ho Oh, Shinichi Saito, Yoshinori Yamamoto,
Tetrahedron Letters 2002, 43, 2903-2907.
12. Addition of Heteroaromatics to Alkylidenecyclopropanes Catalyzed by Palladium
Itaru Nakamura, Amal I. Siriwardana, Shinichi Saito, Yoshinori Yamamoto
J. Org. Chem. 2002, 67, 3445-3449.
13. Indenol Ether Formation from Arylalkynes Bearing ortho-Acetal. An Unprecedented Rearrangement in
Palladium-Catalyzed Carboalkoxylation
Itaru Nakamura, Gan B. Bajracharya, Yuya Mizushima, and Yoshinori Yamamoto
Angew. Chem. Int. Ed. 2002, 41, 4328-4331.
14. Palladium-Catalyzed Hydrocarbonation of Methyleneaziridines with Carbon Pronucleophiles
Byoung Ho Oh, Itaru Nakamura, Yoshinori Yamamoto
Tetrahedron Lett. 2002, 43, 9625-9628.
15. Addition of hydrogen halides to alkylidenecyclopropanes: a highly efficient and stereoselective method for the
preparation of homoallyl halides
Amal. I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto
Tetrahedron Lett. 2003, 44, 985-987.
16. Palladium-Catalyzed Hydrocarbonation and Hydroamination of 3,3-Dihexylcyclopropenes with Pronucleophiles
Itaru Nakamura, Gan B. Bajracharya, Yoshinori Yamamoto
J. Org. Chem. 2003, 68, 2297-2299.
17. Addition of water to arylidenecyclopropanes: a highly efficient method for the preparation of gem-aryl disubstituted
homoallylic alcohols
Amal. I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto
Tetrahedron Lett. 2003, 44, 4547-4550.
18. Catalytic and thermal hydrocarbonation of methyleneaziridines
Byoung Ho Oh, Itaru Nakamura, and Yoshinori Yamamoto
ARKIVOC 2003, (xiii) 67-78.
19. Synthesis of 3-Methylenepyrrolidines by Palladium-Catalyzed [3+2] Cycloaddition of Alkylidenecyclopropanes with
Imines
Byoung Ho Oh, Itaru Nakamura, Shinichi Saito, Yoshinori Yamamoto
Heterocycles 2003, 61, 247-257.
20. Palladium-Catalyzed Ring Opening Reaction of Methyleneaziridines with Carboxylic Acids. Synthesis of
-Amidoketones
Byoung Ho Oh, Itaru Nakamura, Yoshinori Yamamoto
J. Org. Chem. 2004, 69 (8), 2856-2858.
21. Synthesis of indenes by ytterbium-catalyzed carboalkoxylation/Friedel-Crafts reaction of arylidenecyclopropanes
with acetals
Itaru Nakamura, Michiru Kamada, Yoshinori Yamamoto
Tetrahedron Lett. 2004, 45(14), 2903-2906.
22. Synthesis of 5-Azaindolizine Derivatives by the Palladium-Catalyzed Intermolecular Formal [3+2] Cycloaddition of
Alkylidenecyclopropanes with 1,2-Diazines
Amal I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto
J. Org. Chem. 2004, 69 (9), 3202-3204.
23. Intramolecular C–N Bond Addition of Amides to Alkynes using Platinum-Catalyst
Tomohiro Shimada, Itaru Nakamura, Yoshinori Yamamoto
J. Am. Chem. Soc. 2004, 126 (34), 10546-10547.
24. Synthesis of Pyridiylpyrrole Derivatives via the Palladium-Catalyzed Reaction of Acetylpyridines with
Methyleneaziridines
Amal I. Siriwardana, Kalum K. A. D. S. Kathriarachchi, Itaru Nakamura, Ilya D. Gridnev, Yoshinori Yamamoto
J. Am. Chem. Soc. 2004, 126 (43), 13898-13899.
25. Catalytic Cyclization of ortho-Alkynylbenzaldehyde Acetals and Thioacetals. Unprecedented Activation of the
Platinum Catalyst by Olefins. Scope and Mechanism of the Reaction
Itaru Nakamura, Gan B. Bajracharya, Huanyou Wu, Kengo Oishi, Yuya Mizushima, Ilya D. Gridnev, Yoshinori
Yamamoto
J. Am. Chem. Soc. 2004, 126 (47), 15423-15430.
26. PtBr2-Catalyzed Consecutive Enyne Metathesis-Aromatization of 1-(1-Methoxy-but-3-enyl)-2-(1-alkynyl)benzenes.
Dual Role of the Pt Catalyst
Gan B. Bajracharya, Itaru Nakamura, and Yoshinori Yamamoto
J. Org. Chem. 2005, 70 (3), 892-897.
27. Platinum-Catalyzed Tandem Carboalkoxylation-Claisen
ortho-1,5-Dihydro-3H-2,4-dioxepine Group
Itaru Nakamura, Gan B. Bajracharya, Yoshinori Yamamoto
Chem. Lett. 2005, (2) 174-175.
Rearrangement
of
Arylalkynes
28. Stepwise Delivery of Two Methoxy Groups of Arylaldehyde Acetals Across the Phenyl Ring.
Controlled Palladium Catalysis
Itaru Nakamura, Yuya Mizushima, Ilya D. Gridnev, Yoshinori Yamamoto
J. Am. Chem. Soc. 2005, 127, 9844-9847..
Bearing
an
Vacant Site
29. Palladium-Catalyzed Addition of Nitrogen Pronucleophiles to Alkylidenecyclopropanes
Amal I. Siriwardana, Michiru Kamada, Itaru Nakamura, Yoshinori Yamamoto
J. Org. Chem. 2005, 70, 5932-5937.
30. Addition of 2-Oxazolidinones to Arylidenecyclopropanes: A Highly Efficient Methods for the Preparation of
gem-Aryl Disubstituted Homoallylic Oxazolidinones
Amal I. Siriwardana, Kalum K. A. D. S. Kathriarachchi, Itaru Nakamura, Yoshinori Yamamoto
Heterocycles 2005, 66, 333-339.
31. Synthesis of 2,3-Disubstituted Benzofurans by Platinum-Olefin-Catalyzed Carboalkoxylation of o-Alkynylphenyl
Acetals
Itaru Nakamura, Yuya Mizushima, Yoshinori Yamamoto
J. Am. Chem. Soc. 2005, 127. 15022-15023.
32. Palladium-Catalyzed Dimerization of Conjugated Diynes: Synthesis of (E)-1,2-Divinyldiethynylethenes Having
Donor and Acceptor Chromophores at the Terminus of Alkyne
Nirmal K. Pahadi, Draxel H. Camacho, Itaru Nakamura, and Yoshinori Yamamoto
J. Org. Chem. 2006, 71 (3), 1152-1155.
33 Gold-Catalyzed Intramolecular Carbothiolation of Alkynes. Synthesis of 2,3-Disubstituted Benzothiophenes from
-Alkoxylalkyl (ortho-Alkynyl)phenyl Sulfides
Itaru Nakamura, Takuma Sato, Yoshinori Yamamoto
Angew. Chem. Int. Ed. 2006, 45, 4473-4475 [Selected as Hot Paper]..
34. Thermally Induced and Silver Salt-Catalyzed [2+2] Cycloadditions of Imines to (Alkoxymethylene)cyclopropanes
Itaru Nakamura, Tetsuya Nemoto, Yoshinori Yamamoto, and Armin de Meijere,.
Angew. Chem. Int. Ed. 2006, 45, 5176-5179.
35. Gold- and Indium-Catalyzed Synthesis of 3- and 6-Sulofonylindoles from ortho-Alkynyl-N-Sulufonylanilines.
Consecutive C-N and C-S Bond Formation through Intramolecular Aminosulfonylation
Itaru Nakamura, Uichiro Yamagishi, Dschun Song, Sayaka Konta, Yoshinori Yamamoto
Angew. Chem. Int. Ed. 2007, 46, 2284-2287
36. Synthesis of 1,2,3,4-Tetrasubstituted Pyrroles Derivatives via the Palladium-Catalyzed Reaction of 1,3-Diketones
with Methyleneaziridines
Kalum K. A. D. S. Kathriarachchi, Amal I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto
Tetrahedron Lett. 2007, 48, 2267-2270.
37. Synthesis of 2,3-disubstituted benzofurans and indoles by -Lewis acidic transition metal-catalyzed cyclization of
ortho-alkynylphenyl O,O- and N,O-acetals
Itaru Nakamura, Yuya Mizushima, Uichiro Yamagishi, Yoshinori Yamamoto
Tetrahedron 2007, 63, 8670-8676.
38. Thermally Induced [2+2] Cycloadditions of (Benzyloxymethylene)cyclopropane to Alkylidenemalononitriles
Itaru Nakamura, Ryoko Nagata, Tetsuya Nemoto, Masahiro Terada, Yoshinori Yamamoto, Thomas Späth, and Armin
de Meijere
Eur. J. Org. Chem. 2007, 4479-4482.
39. Gold-catalyzed cyclization of (ortho-alkynylphenylthio)silanes; intramolecular capture of the vinyl-Au intermediate
by the silicon electrophile
Itaru Nakamura, Takuma Sato, Masahiro Terada, and Yoshinori Yamamoto
Org. Lett. 2007, 9, 4081-4083.
40. Synthesis of 3- and 6-Sulfonylindoles from ortho-Alkynyl-N-sulfonylanilines by the Use of Lewis Acidic Transition
Metal Catalysts
Itaru Nakamura, Uichiro Yamagishi, Dschun Song, Sayaka Konta, and Yoshinori Yamamoto
Chem. Asian J. 2008, 3, 285-295.
41. Synthesis of Multisubstituted 2-(Dihydrofuran-2(3H)-ylidene)acetates via Intramolecular Carboalkoxylation by
Platinum-Olefin Catalyst System
Itaru Nakamura, Ching Siew Chan, Toshiharu Araki, Masahiro Terada, and Yoshinori Yamamoto
Org. Lett. 2008, 10, 309-312.
42. Chirality Transfer in Gold-Catalyzed Carbothiolation of ortho-Alkynylphenyl 1-Arylethyl Sulfides
Itaru Nakamura, Takuma Sato, Masahiro Terada, and Yoshinori Yamamoto
Org. Lett. 2008, 10, 2649-2651. [Highlighted in Synfacts 2008, 918]
43. Gold-catalyzed consecutive [1,2] alkyl migration-oxygen transfer reaction of 2-alkynyl-1-tetralones
Ching Siew Chan, Toshiharu Araki, Itaru Nakamura, and Masahiro Terada
Tetrahedron Lett. 2009, 50, 216-218.
44. Palladium-Catalyzed Indolization of N-Aroylbenzotriazoles with Disubstituted Alkynes
Itaru Nakamura, Tetsuya Nemoto, Naozumi Shiraiwa, and Masahiro Terada
Org. Lett. 2009, 11, 1055-1058.
(45). Five-Bond Cleavage in Copper-Catalyzed Skeletal Rearrangement of O-Propargyl Arylaldoximes to -Lactam
Itaru Nakamura, Toshiharu Araki, Masahiro Terada
J. Am. Chem. Soc. 2009, 131, 2804-2805 (withdrawn), J. Am. Chem. Soc. 2011, 133, 6861 (Additions and Corrections).
45. Stereochemistry Control by Ester Group or Olefin Ligand in Platinum-Catalyzed Carboalkoxylation of
6-(1-Alkoxyethoxy)hex-2-ynoates
Itaru Nakamura, Ching Siew Chan, Toshiharu Araki, Masahiro Terada, and Yoshinori Yamamoto
Adv. Synth. Catal. 2009, 351, 1089-1100 [highlighted in Synfact 2009, 918].
46. Platinum-Catalyzed Consecutive C-N bond Formation-[1,3] Shift of Carbamoyl and Ester Groups
Itaru Nakamura, Yusuke Sato, Sayaka Konta, and Masahiro Terada
Tetrahedron Letters 2009, 50, 2075-2077.
47. Platinum-Catalyzed Dehydroalkoxylation-Cyclization Cascade via N-O Bond Cleavage
Itaru Nakamura, Yusuke Sato, and Masahiro Terada
J. Am. Chem. Soc. 2009, 131, 4198-4199 [Highlighted in Synfact 2009. 309]
48. Pt-Catalyzed Multi-Substituted Benzo[b]selenophene
Takuma Sato, Itaru Nakamura, and Masahiro Terada
Eur. J. Org. Chem. 2009, 5509-5512.
49. Gold-Catalyzed Cyclization and Subsequent Arylidene Group Transfer of O-Propioloyl Oximes
Itaru Nakamura, Masashi Okamoto, and Masahiro Terada
Org. Lett. 2010, 12, 2453-2455.
50. Copper-Catalyzed Tandem [2,3]-Rearrangement and 6-3-Azatriene Electrocyclization in
(E)-O-Propargylic ,-Unsaturated Oximes
Itaru Nakamura, Dong Zhang, and Masahiro Terada
J. Am. Chem. Soc. 2010, 132, 7884. J. Am. Chem. Soc. 2011, 133, 6861 (Addtions and Corrections).
51. Synthesis of Bi(benzo[b]thiophenyl)methans by Gold-Catalyzed Double Carbothiolation
Itaru Nakamura, Masashi, Okamoto, Takuma Sato, Masahiro Terada
Heterocycles, 2010, 82, 689-697.
52. Copper-Catalyzed Rearrangement of (Z)-Propynal Hydrazones via N-N Bond Cleavage
Itaru Nakamura, Naozumi Shiraiwa, Ryo Kanazawa, and Masahiro Terada
Org. Lett. 2010, 12, 4198-4200.
53. Regioselective Transformation of O-Propargylic Arylaldoximes to Four-Membered Cyclic Nitrones by
Copper-Catalyzed Skeletal Rearrangement
Nakamura, Itaru; Araki, Toshiharu; Dong, Zhang; Kudo, Yu; Kwon, Eunsang; Terada, Masahiro
Org. Lett. 2011 13, 3616-3619.
54. Platinum-Catalyzed Cycloisomerization of 1,4-Enynes via 1,2-Alkenyl Rearrangement
Takuma Sato, Toshiki Onuma, Itaru Nakamura, and Masahiro Terada
Org. Lett. 2011, 13, 4992-4995.
55. Thermally-induced skeletal rearrangement of (Z)-O-propargylic -unsaturated aldoximes to multisubstituted
pyridine oxides
Itaru Nakamura, Dong Zhang, and Masahiro Terada
Tetrahedron Lett. 2011, 52, 6470-6472.
56. Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Alkylaldoximes via N-O Bond Cleavage
Itaru Nakamura, Tomoki Iwata, Dong Zhang, and Masahiro Terada
Org. Lett 2012, 14, 206-209.
57. Cu-Catalyzed Skeletal Rearrangement of O-Propargylic Aryloximes into Four-Membered Cyclic Nitrones –
Chirality Transfer and Mechanistic Insight
Itaru Nakamura, Yu Kudo, Toshiharu Araki, Dong Zhang, Eunsang Kwon, Masahiro Terada
Synthesis 2012, 44, 1542-1550.
58. Synthesis of Azepine Derivatives via Rh-Catalyzed Tandem 2,3- Rearrangement – Heterocyclization
Itaru Nakamura, Masashi Okamoto, Yoshinori Sato, and Masahiro Terada
Angew. Chem., Int. Ed. 2012, 51, 10816-10819 [Very Important Paper, highlighted at the front cover]
Review
1. パラジウム触媒を用いる新合成プロセスの開拓
山本嘉則、中村達
化学工業 2001, 905-912.
2. Transition Metal-Catalyzed Reactions of Methylenecyclopropanes
Itaru Nakamura, Yoshinori Yamamoto
Adv. Synth. Catal. 2002, 344, 111-129.
3. Transition Metal-catalyzed Reactions in Heterocyclic Synthesis
Itaru Nakamura, Yoshinori Yamamoto
Chem. Rev. 2004, 104, 2127-2198.
4. 多置換ヘテロ環の構築を志向するπ酸性遷移金属触媒反応の開発
中村達
有機合成化学協会誌、2012, 70(6), 581-592
Commentary
1. Room-Temperature Alkyl-Alkyl Suzuki Cross-Coupling of Alkyl Bromides that Possess Hydrogens
Itaru Nakamura, Yoshinori Yamamoto
ChemTract 2002, 15, 102-105.
Book
1. New Transformation with Lewis Acid and Transition Metal Catalysts. Application to the Synthesis of Polycyclic
Ethers
Yoshinori Yamamoto, Itaru Nakamura
In My Favorite Organic Synthesis, The Society of Synthetic Organic Chemistry, Japan, 2002, pp250-251.
2. Nucleophilic Attack by Palladium Species
Yoshinori Yamamoto, Itaru Nakamura
Topics in Organomatallic Chemistry Vol. 14, Palladium in Organic Synthesis Tsuji, J. Ed.; Springer: 2005, pp211.
3. 「生体構成元素間σ結合活性化」を鍵とする触媒反応の開拓
中村 達
「飛翔する若手研究者」、化学と工業、2011, 889
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