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Itaru Nakamura Publication List (03/2013) 1. Palladium Catalyzed Alkylative Dimerization between Pronucleophiles and Vinyltins Itaru Nakamura, Naofumi Tsukada, Mohammad Al-Masum, and Yoshinori Yamamoto J. Chem. Soc., Chem. Commun. 1997, 1583-1584. 2. Ring Opening in the Palladium-Catalyzed Hydrocarbonation of Methylenecyclopropanes with Pronucleophiles Naofumi Tsukada, Akinori Shibuya, Itaru Nakamura, and Yoshinori Yamamoto J. Am. Chem. Soc. 1997, 119, 8123-8124. 3. Ring Opening in the Hydroamination of Methylenecyclopropanes Catalyzed by Palladium Itaru Nakamura, Hitoshi Itagaki, and Yoshinori Yamamoto J. Org. Chem. 1998, 63, 6458-6459. 4. Inter- and Intramolecular Palladium-Catalyzed Hydrocarbonation of Methylenecyclopropanes with Carbon Pronucleophiles Naofumi Tsukada, Akinori, Shibuya, Itaru Nakamura, Haruo Kitahara, and Yoshinori Yamamoto Tetrahedron 1999, 55, 8833-8844. 5. Palladium-Catalyzed Hydroalkoxylation of Methylenecyclopropanes Drexel Camacho, Itaru Nakamura, Shinichi Saito, and Yoshinori Yamamoto Angew. Chem. Int. Ed. 1999, 38, 3365-3367. 6. Hydrofurylation of Alkylidenecyclopropanes Catalyzed by Palladium Itaru Nakamura, Shinichi Saito, and Yoshinori Yamamoto J. Am. Chem. Soc. 2000, 122, 2661. 7. Palladium-Catalyzed Addition of Alcohol Pronucleophiles to Alkylidenecyclopropanes Drexel Camacho, Itaru Nakamura, Shinichi Saito, and Yoshinori Yamamoto J. Org. Chem. 2001, 66, 270-275. 8. Novel [3+2] Cycloaddition of Alkylidenecyclopropanes with Aldehydes Catalyzed by Palladium Itaru Nakamura, Byoung Ho Oh, Shinichi Saito, Yoshinori Yamamoto Angew. Chem. Int. Ed. 2001, 40, 1298-1300. 9. Palladium-Catalyzed [3+2] Cycloaddition of Alkylidenecyclopropanes with Imines B.-H. Oh, I. Nakamura, S. Saito, Y. Yamamoto, Tetrahedron Lett. 2001, 42, 6203-6205. 10. Palladium-Catalyzed Inter- and Intramolecular Hydroamination of Methylenecyclopropanes with Amines Itaru Nakamura, Hitoshi Itagaki, Yoshinori Yamamoto Chemistry of Heterocyclic Compounds, 2001, 12, 1684-1692. 11. Palladium-catalyzed addition of ketones to alkylidenecyclopropanes. Drexel H. Camacho, Itaru Nakamura, Byoung Ho Oh, Shinichi Saito, Yoshinori Yamamoto, Tetrahedron Letters 2002, 43, 2903-2907. 12. Addition of Heteroaromatics to Alkylidenecyclopropanes Catalyzed by Palladium Itaru Nakamura, Amal I. Siriwardana, Shinichi Saito, Yoshinori Yamamoto J. Org. Chem. 2002, 67, 3445-3449. 13. Indenol Ether Formation from Arylalkynes Bearing ortho-Acetal. An Unprecedented Rearrangement in Palladium-Catalyzed Carboalkoxylation Itaru Nakamura, Gan B. Bajracharya, Yuya Mizushima, and Yoshinori Yamamoto Angew. Chem. Int. Ed. 2002, 41, 4328-4331. 14. Palladium-Catalyzed Hydrocarbonation of Methyleneaziridines with Carbon Pronucleophiles Byoung Ho Oh, Itaru Nakamura, Yoshinori Yamamoto Tetrahedron Lett. 2002, 43, 9625-9628. 15. Addition of hydrogen halides to alkylidenecyclopropanes: a highly efficient and stereoselective method for the preparation of homoallyl halides Amal. I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto Tetrahedron Lett. 2003, 44, 985-987. 16. Palladium-Catalyzed Hydrocarbonation and Hydroamination of 3,3-Dihexylcyclopropenes with Pronucleophiles Itaru Nakamura, Gan B. Bajracharya, Yoshinori Yamamoto J. Org. Chem. 2003, 68, 2297-2299. 17. Addition of water to arylidenecyclopropanes: a highly efficient method for the preparation of gem-aryl disubstituted homoallylic alcohols Amal. I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto Tetrahedron Lett. 2003, 44, 4547-4550. 18. Catalytic and thermal hydrocarbonation of methyleneaziridines Byoung Ho Oh, Itaru Nakamura, and Yoshinori Yamamoto ARKIVOC 2003, (xiii) 67-78. 19. Synthesis of 3-Methylenepyrrolidines by Palladium-Catalyzed [3+2] Cycloaddition of Alkylidenecyclopropanes with Imines Byoung Ho Oh, Itaru Nakamura, Shinichi Saito, Yoshinori Yamamoto Heterocycles 2003, 61, 247-257. 20. Palladium-Catalyzed Ring Opening Reaction of Methyleneaziridines with Carboxylic Acids. Synthesis of -Amidoketones Byoung Ho Oh, Itaru Nakamura, Yoshinori Yamamoto J. Org. Chem. 2004, 69 (8), 2856-2858. 21. Synthesis of indenes by ytterbium-catalyzed carboalkoxylation/Friedel-Crafts reaction of arylidenecyclopropanes with acetals Itaru Nakamura, Michiru Kamada, Yoshinori Yamamoto Tetrahedron Lett. 2004, 45(14), 2903-2906. 22. Synthesis of 5-Azaindolizine Derivatives by the Palladium-Catalyzed Intermolecular Formal [3+2] Cycloaddition of Alkylidenecyclopropanes with 1,2-Diazines Amal I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto J. Org. Chem. 2004, 69 (9), 3202-3204. 23. Intramolecular C–N Bond Addition of Amides to Alkynes using Platinum-Catalyst Tomohiro Shimada, Itaru Nakamura, Yoshinori Yamamoto J. Am. Chem. Soc. 2004, 126 (34), 10546-10547. 24. Synthesis of Pyridiylpyrrole Derivatives via the Palladium-Catalyzed Reaction of Acetylpyridines with Methyleneaziridines Amal I. Siriwardana, Kalum K. A. D. S. Kathriarachchi, Itaru Nakamura, Ilya D. Gridnev, Yoshinori Yamamoto J. Am. Chem. Soc. 2004, 126 (43), 13898-13899. 25. Catalytic Cyclization of ortho-Alkynylbenzaldehyde Acetals and Thioacetals. Unprecedented Activation of the Platinum Catalyst by Olefins. Scope and Mechanism of the Reaction Itaru Nakamura, Gan B. Bajracharya, Huanyou Wu, Kengo Oishi, Yuya Mizushima, Ilya D. Gridnev, Yoshinori Yamamoto J. Am. Chem. Soc. 2004, 126 (47), 15423-15430. 26. PtBr2-Catalyzed Consecutive Enyne Metathesis-Aromatization of 1-(1-Methoxy-but-3-enyl)-2-(1-alkynyl)benzenes. Dual Role of the Pt Catalyst Gan B. Bajracharya, Itaru Nakamura, and Yoshinori Yamamoto J. Org. Chem. 2005, 70 (3), 892-897. 27. Platinum-Catalyzed Tandem Carboalkoxylation-Claisen ortho-1,5-Dihydro-3H-2,4-dioxepine Group Itaru Nakamura, Gan B. Bajracharya, Yoshinori Yamamoto Chem. Lett. 2005, (2) 174-175. Rearrangement of Arylalkynes 28. Stepwise Delivery of Two Methoxy Groups of Arylaldehyde Acetals Across the Phenyl Ring. Controlled Palladium Catalysis Itaru Nakamura, Yuya Mizushima, Ilya D. Gridnev, Yoshinori Yamamoto J. Am. Chem. Soc. 2005, 127, 9844-9847.. Bearing an Vacant Site 29. Palladium-Catalyzed Addition of Nitrogen Pronucleophiles to Alkylidenecyclopropanes Amal I. Siriwardana, Michiru Kamada, Itaru Nakamura, Yoshinori Yamamoto J. Org. Chem. 2005, 70, 5932-5937. 30. Addition of 2-Oxazolidinones to Arylidenecyclopropanes: A Highly Efficient Methods for the Preparation of gem-Aryl Disubstituted Homoallylic Oxazolidinones Amal I. Siriwardana, Kalum K. A. D. S. Kathriarachchi, Itaru Nakamura, Yoshinori Yamamoto Heterocycles 2005, 66, 333-339. 31. Synthesis of 2,3-Disubstituted Benzofurans by Platinum-Olefin-Catalyzed Carboalkoxylation of o-Alkynylphenyl Acetals Itaru Nakamura, Yuya Mizushima, Yoshinori Yamamoto J. Am. Chem. Soc. 2005, 127. 15022-15023. 32. Palladium-Catalyzed Dimerization of Conjugated Diynes: Synthesis of (E)-1,2-Divinyldiethynylethenes Having Donor and Acceptor Chromophores at the Terminus of Alkyne Nirmal K. Pahadi, Draxel H. Camacho, Itaru Nakamura, and Yoshinori Yamamoto J. Org. Chem. 2006, 71 (3), 1152-1155. 33 Gold-Catalyzed Intramolecular Carbothiolation of Alkynes. Synthesis of 2,3-Disubstituted Benzothiophenes from -Alkoxylalkyl (ortho-Alkynyl)phenyl Sulfides Itaru Nakamura, Takuma Sato, Yoshinori Yamamoto Angew. Chem. Int. Ed. 2006, 45, 4473-4475 [Selected as Hot Paper].. 34. Thermally Induced and Silver Salt-Catalyzed [2+2] Cycloadditions of Imines to (Alkoxymethylene)cyclopropanes Itaru Nakamura, Tetsuya Nemoto, Yoshinori Yamamoto, and Armin de Meijere,. Angew. Chem. Int. Ed. 2006, 45, 5176-5179. 35. Gold- and Indium-Catalyzed Synthesis of 3- and 6-Sulofonylindoles from ortho-Alkynyl-N-Sulufonylanilines. Consecutive C-N and C-S Bond Formation through Intramolecular Aminosulfonylation Itaru Nakamura, Uichiro Yamagishi, Dschun Song, Sayaka Konta, Yoshinori Yamamoto Angew. Chem. Int. Ed. 2007, 46, 2284-2287 36. Synthesis of 1,2,3,4-Tetrasubstituted Pyrroles Derivatives via the Palladium-Catalyzed Reaction of 1,3-Diketones with Methyleneaziridines Kalum K. A. D. S. Kathriarachchi, Amal I. Siriwardana, Itaru Nakamura, Yoshinori Yamamoto Tetrahedron Lett. 2007, 48, 2267-2270. 37. Synthesis of 2,3-disubstituted benzofurans and indoles by -Lewis acidic transition metal-catalyzed cyclization of ortho-alkynylphenyl O,O- and N,O-acetals Itaru Nakamura, Yuya Mizushima, Uichiro Yamagishi, Yoshinori Yamamoto Tetrahedron 2007, 63, 8670-8676. 38. Thermally Induced [2+2] Cycloadditions of (Benzyloxymethylene)cyclopropane to Alkylidenemalononitriles Itaru Nakamura, Ryoko Nagata, Tetsuya Nemoto, Masahiro Terada, Yoshinori Yamamoto, Thomas Späth, and Armin de Meijere Eur. J. Org. Chem. 2007, 4479-4482. 39. Gold-catalyzed cyclization of (ortho-alkynylphenylthio)silanes; intramolecular capture of the vinyl-Au intermediate by the silicon electrophile Itaru Nakamura, Takuma Sato, Masahiro Terada, and Yoshinori Yamamoto Org. Lett. 2007, 9, 4081-4083. 40. Synthesis of 3- and 6-Sulfonylindoles from ortho-Alkynyl-N-sulfonylanilines by the Use of Lewis Acidic Transition Metal Catalysts Itaru Nakamura, Uichiro Yamagishi, Dschun Song, Sayaka Konta, and Yoshinori Yamamoto Chem. Asian J. 2008, 3, 285-295. 41. Synthesis of Multisubstituted 2-(Dihydrofuran-2(3H)-ylidene)acetates via Intramolecular Carboalkoxylation by Platinum-Olefin Catalyst System Itaru Nakamura, Ching Siew Chan, Toshiharu Araki, Masahiro Terada, and Yoshinori Yamamoto Org. Lett. 2008, 10, 309-312. 42. Chirality Transfer in Gold-Catalyzed Carbothiolation of ortho-Alkynylphenyl 1-Arylethyl Sulfides Itaru Nakamura, Takuma Sato, Masahiro Terada, and Yoshinori Yamamoto Org. Lett. 2008, 10, 2649-2651. [Highlighted in Synfacts 2008, 918] 43. Gold-catalyzed consecutive [1,2] alkyl migration-oxygen transfer reaction of 2-alkynyl-1-tetralones Ching Siew Chan, Toshiharu Araki, Itaru Nakamura, and Masahiro Terada Tetrahedron Lett. 2009, 50, 216-218. 44. Palladium-Catalyzed Indolization of N-Aroylbenzotriazoles with Disubstituted Alkynes Itaru Nakamura, Tetsuya Nemoto, Naozumi Shiraiwa, and Masahiro Terada Org. Lett. 2009, 11, 1055-1058. (45). Five-Bond Cleavage in Copper-Catalyzed Skeletal Rearrangement of O-Propargyl Arylaldoximes to -Lactam Itaru Nakamura, Toshiharu Araki, Masahiro Terada J. Am. Chem. Soc. 2009, 131, 2804-2805 (withdrawn), J. Am. Chem. Soc. 2011, 133, 6861 (Additions and Corrections). 45. Stereochemistry Control by Ester Group or Olefin Ligand in Platinum-Catalyzed Carboalkoxylation of 6-(1-Alkoxyethoxy)hex-2-ynoates Itaru Nakamura, Ching Siew Chan, Toshiharu Araki, Masahiro Terada, and Yoshinori Yamamoto Adv. Synth. Catal. 2009, 351, 1089-1100 [highlighted in Synfact 2009, 918]. 46. Platinum-Catalyzed Consecutive C-N bond Formation-[1,3] Shift of Carbamoyl and Ester Groups Itaru Nakamura, Yusuke Sato, Sayaka Konta, and Masahiro Terada Tetrahedron Letters 2009, 50, 2075-2077. 47. Platinum-Catalyzed Dehydroalkoxylation-Cyclization Cascade via N-O Bond Cleavage Itaru Nakamura, Yusuke Sato, and Masahiro Terada J. Am. Chem. Soc. 2009, 131, 4198-4199 [Highlighted in Synfact 2009. 309] 48. Pt-Catalyzed Multi-Substituted Benzo[b]selenophene Takuma Sato, Itaru Nakamura, and Masahiro Terada Eur. J. Org. Chem. 2009, 5509-5512. 49. Gold-Catalyzed Cyclization and Subsequent Arylidene Group Transfer of O-Propioloyl Oximes Itaru Nakamura, Masashi Okamoto, and Masahiro Terada Org. Lett. 2010, 12, 2453-2455. 50. Copper-Catalyzed Tandem [2,3]-Rearrangement and 6-3-Azatriene Electrocyclization in (E)-O-Propargylic ,-Unsaturated Oximes Itaru Nakamura, Dong Zhang, and Masahiro Terada J. Am. Chem. Soc. 2010, 132, 7884. J. Am. Chem. Soc. 2011, 133, 6861 (Addtions and Corrections). 51. Synthesis of Bi(benzo[b]thiophenyl)methans by Gold-Catalyzed Double Carbothiolation Itaru Nakamura, Masashi, Okamoto, Takuma Sato, Masahiro Terada Heterocycles, 2010, 82, 689-697. 52. Copper-Catalyzed Rearrangement of (Z)-Propynal Hydrazones via N-N Bond Cleavage Itaru Nakamura, Naozumi Shiraiwa, Ryo Kanazawa, and Masahiro Terada Org. Lett. 2010, 12, 4198-4200. 53. Regioselective Transformation of O-Propargylic Arylaldoximes to Four-Membered Cyclic Nitrones by Copper-Catalyzed Skeletal Rearrangement Nakamura, Itaru; Araki, Toshiharu; Dong, Zhang; Kudo, Yu; Kwon, Eunsang; Terada, Masahiro Org. Lett. 2011 13, 3616-3619. 54. Platinum-Catalyzed Cycloisomerization of 1,4-Enynes via 1,2-Alkenyl Rearrangement Takuma Sato, Toshiki Onuma, Itaru Nakamura, and Masahiro Terada Org. Lett. 2011, 13, 4992-4995. 55. Thermally-induced skeletal rearrangement of (Z)-O-propargylic -unsaturated aldoximes to multisubstituted pyridine oxides Itaru Nakamura, Dong Zhang, and Masahiro Terada Tetrahedron Lett. 2011, 52, 6470-6472. 56. Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Alkylaldoximes via N-O Bond Cleavage Itaru Nakamura, Tomoki Iwata, Dong Zhang, and Masahiro Terada Org. Lett 2012, 14, 206-209. 57. Cu-Catalyzed Skeletal Rearrangement of O-Propargylic Aryloximes into Four-Membered Cyclic Nitrones – Chirality Transfer and Mechanistic Insight Itaru Nakamura, Yu Kudo, Toshiharu Araki, Dong Zhang, Eunsang Kwon, Masahiro Terada Synthesis 2012, 44, 1542-1550. 58. Synthesis of Azepine Derivatives via Rh-Catalyzed Tandem 2,3- Rearrangement – Heterocyclization Itaru Nakamura, Masashi Okamoto, Yoshinori Sato, and Masahiro Terada Angew. Chem., Int. Ed. 2012, 51, 10816-10819 [Very Important Paper, highlighted at the front cover] Review 1. パラジウム触媒を用いる新合成プロセスの開拓 山本嘉則、中村達 化学工業 2001, 905-912. 2. Transition Metal-Catalyzed Reactions of Methylenecyclopropanes Itaru Nakamura, Yoshinori Yamamoto Adv. Synth. Catal. 2002, 344, 111-129. 3. Transition Metal-catalyzed Reactions in Heterocyclic Synthesis Itaru Nakamura, Yoshinori Yamamoto Chem. Rev. 2004, 104, 2127-2198. 4. 多置換ヘテロ環の構築を志向するπ酸性遷移金属触媒反応の開発 中村達 有機合成化学協会誌、2012, 70(6), 581-592 Commentary 1. Room-Temperature Alkyl-Alkyl Suzuki Cross-Coupling of Alkyl Bromides that Possess Hydrogens Itaru Nakamura, Yoshinori Yamamoto ChemTract 2002, 15, 102-105. Book 1. New Transformation with Lewis Acid and Transition Metal Catalysts. Application to the Synthesis of Polycyclic Ethers Yoshinori Yamamoto, Itaru Nakamura In My Favorite Organic Synthesis, The Society of Synthetic Organic Chemistry, Japan, 2002, pp250-251. 2. Nucleophilic Attack by Palladium Species Yoshinori Yamamoto, Itaru Nakamura Topics in Organomatallic Chemistry Vol. 14, Palladium in Organic Synthesis Tsuji, J. Ed.; Springer: 2005, pp211. 3. 「生体構成元素間σ結合活性化」を鍵とする触媒反応の開拓 中村 達 「飛翔する若手研究者」、化学と工業、2011, 889