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Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
Chemical and Radiological Risk
in the Indoor Environment
(CheRRIE)
In situ measurements of
chemical compounds
Spyros Karakitsios, MSc, PhD
Environmental Engineering Laboratory (EnvE-Lab)
Department of Chemical Engineering, Aristotle University of Thessaloniki - 54124,
Greece
CheRRIE Closing event
November 30, 2015
Thessaloniki, GR
1
Location of the 50 residential
sites in Thessaloniki
CheRRIE Closing event
November 30, 2015
Thessaloniki, GR
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
2
Sampling and analysis
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
BTEX
Carbonyls
CheRRIE Closing event
November 30, 2015
Thessaloniki, GR
3
Excluding outdoor BTEX
contribution
CheRRIE Closing event
November 30, 2015
Thessaloniki, GR
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
4
Indoor concentrations
Indoor concentration (μg/m3)
30
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
5%-95%
Median
Mean
25
20
15
10
5
0
Benzene
Toluene
Ethylbenzene
Xylenes
BTEX
CheRRIE Closing event
November 30, 2015
Formaldehyde Acetaldehyde
Aldehydes
Thessaloniki, GR
5
BTEX concentrations
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
35
Benzene
Toluene
Ethylbenzene
Xylenes
30
Concentration (μg/m3)
25
20
15
10
5
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
Kalamaria
CheRRIE Closing event
Kentro
Ano Toumpa Stauroupoli
November 30, 2015
Polihni
Evosmos
Ampelokhpoi Neapoli Sykies TriandriaPylaia Peuka Panorama Thermi
Thessaloniki, GR
6
Carbonyl concentrations
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
40
Formaldehyde
Acetaldehyde
35
Concentration (μg/m3)
30
25
20
15
10
5
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
Kalamaria
CheRRIE Closing event
Kentro
Ano Toumpa Stauroupoli
November 30, 2015
Polihni
Evosmos
Ampelokhpoi Neapoli Sykies TriandriaPylaia Peuka Panorama Thermi
Thessaloniki, GR
7
Correlation of emissions to
sources
CheRRIE Closing event
November 30, 2015
Thessaloniki, GR
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
8
Contribution of materials to
concentrations
Wood
Based
Panels
5%
BENZENE
Carpets
6%
Floorings
40%
Paints and
Varnishes
37%
Paints and
Varnishes
40%
XYLENES
Carpets
9%
Floorings
31%
Gypsum
Products
and Plaster
boards
15%
CheRRIE Closing event
Carpets
5%
Floorings
57%
Paints and
Varnishes
25%
Wood
Based
Panels
44%
Wood
Based
Panels
4%
ETHYLBENZENE
FORMALDEHYDE
Carpets
6%
Floorings
20%
Paints and
Varnishes
11%
November 30, 2015
Gypsum
Products
and Plaster
boards
19%
Thessaloniki, GR
Wood
Based
Panels
7%
Carpets
4%
Floorings
35%
Paints and
Varnishes
46%
Gypsum
Products and
Plaster boards
11%
Gypsum
Products
and Plaster
boards
12%
Wood
Based
Panels
5%
TOLUENE
Wood
Based
Panels
2%
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
Gypsum
Products
and Plaster
boards
11%
ACETALDEHYDE
Paints and
Varnishes
36%
Carpets
5%
Floorings
44%
Gypsum
Products
and Plaster
boards
8%
9
Conclusions
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
• BTEX levels are lower than the ones measured in Greece in previous
years – carbonyl compound levels are lower than the ones found in
central and northern Europe
• Although wide variability was found among the different locations,
concentration levels are well correlated to the emissions
• Parameters that affect these correlations include:
•
Air exchange rate differences among dwellings; i.e. dwellings with similar
emissions might represent different concentration levels in the indoor air
•
the wide variability of the emission factors among similar materials, as
already identified in the laboratory analysis, as well as in the review study
•
the presence of building materials used, such as internal and external wall
ceiling finishes and thermal insulation that cannot be identified.
•
The use of domestic cleaning products affect significantly VOC
concentrations and especially BTEX levels
CheRRIE Closing event
November 30, 2015
Thessaloniki, GR
10
Dep. of Chemical Engineering
School of Engineering
Aristotle Univ. of Thessaloniki
Thank you for your kind
attention
www.enve-lab.eu
A connectivity perspective to environment-health interactions
CheRRIE Closing event
November 30, 2015
Thessaloniki, GR
11
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