Download eche 311 chemical thermodynamics

ECHE 311
CHEMICAL ENGINEERING THERMODYNAMICS
SPRING 2016, 11:40 AM-12:55 PM TTH, 2A14 (SWRG)
Professor:
Office:
Tel:
Email:
Web site:
Dr. Branko N. Popov
2C19 SWG Eng. Center
803-777-7314
[email protected]
http://www.che.sc.edu/faculty/popov/default.htm
Office Hrs:
By appointment at 777-7314 or
by email.
Teaching Assistants:
Van Der Munnik
Email:
[email protected]
Email:
Casali , Dominic
[email protected]
Email
Almaki Fahad
[email protected]
Textbook:
Smith, Van Ness, and Abbott, “Introduction to Chemical Engineering
Thermodynamics” 6th ed., McGraw-Hill.
Ref. Book : B. N. Popov Booklet of Solved Problem Examples - Free of charge
Undergraduate and TA should claim the booklet on Tuesday, January 12, 2016
Location: 2B 37 Swearingen Engineering Building , 301 main Street
Time: 09:00-11:30 or 13:30-16:30
Please sign when taking the booklet and return back after the final exam
Prerequisite:
ENGR 290, Thermodynamic Fundamentals
Course Objectives:
1.
Students will demonstrate the ability to derive and explain relations
between measureable and non-measureable thermodynamic properties,
and will be able to utilize property models to compute changes in
thermodynamic properties;
2. Students will demonstrate the ability to describe, model, and compute
the state of phase equilibrium for non-ideal mixtures.
3. Students will demonstrate the ability to describe, model, and compute
the state of reaction equilibrium for a single reaction in a single fluid
phase.
1
Computer Usage:
Extensive use of spreadsheets; MathCad or Maple and graphing packages.
Expected Knowledge:
To pass this course the student must demonstrate that he/she knows how to
 set up and solve phase equilibrium problems
 recognize
thermodynamic
fundamentals
and
distinguish
thermodynamic models(e.g. compressibility equation, Equations of
State, activity coefficient models, etc).
 calculate vapor-liquid equilibrium (bubble point, dew point and
flash).
 determine and locate-pure component thermo-chemical data.
 set up and solve problems in chemical reaction equilibrium
Grading:
2 exams
50% February 11th , March 24th /2015
Weekly Quizzes
5%
Attendance
5%
Homework’s
15% Follow ChE Handbook Format*
Final Exam
25% TH, April 28th @ 9:00 AM
Total 100%
*Homework must be submitted on time. Late homework will not be accepted unless valid
reasons exist. Exams (open book) will be related to the homeworks and lecture material.
2
ECHE 311 Approximate Schedule, SPRING 2016
Final Exam:
TH, April 28th @ 9 AM
Holidays: January 18th, Dr. Martin Luther King, Jr. Service Day; March 16-13 Sun-Sun, (Spring
Break),
Date
Topic and Reading
Comment
Unit 1 First and Second Law/Equation of States/Residual Properties
1/12
Orientation. Review of Basic Concepts: Mass and Energy Balances:
1/14
The Reversible Process, Enthalpy, Heat capacity: Read: SVNA Ch2 ,B. N.
Popov” Handouts “The Fist Law”: Read SVNA Ch 1,2,4, B .N .Popov
“Handouts”
1/19
Second Law, Entropy, Read SVNA Ch. 5 thru Section 5.9,
B.N. Popov Handouts ”The Second law of Thermodynamics,”
1/21
Properties of pure fluids: Equation of State-Virial Equation
Read SVNA Ch.3, Problem Solving (P.S.)
1/26
Cubic Equations of State, Problem Solving
1/28
Generalized Correlations for Gases and Liquids,
2/2
Property Relations Homogeneous Phases, SVNA Section 6.1 6.2
2/4
Fundamental Equations: Homogeneous Phases, Residual Properties: Read
3
SVNA Section 6.1 6.2, 6.3, (P. S).
2/9
2/11
Two phase systems / SVNA, Section 6.4, (P.S)
Generalized Properties Correlation for Gases: SVNA, Section 6.7, (P.S).
Review Unit 1.
EXAM 1-Unit 1
Unit 2 Solution Thermodynamics Theory: Phase Equilibrium
2/16
Criterion for Phase Equilibrium: Chemical Potential, Read SVNA
Ch.11 Section 11.1, and 11.2. (P.S)
2/18
Fugacity from an EOS-Pure Component, Read SVNA Section 11.5
2/23
Generalized Correlation for the Fugacity Coefficient (P.S)
2/25
Ideal Solutions
3/1
Solution Thermodynamics Liquid Phase Properties from VLE data:
Read SVNA Ch12
3/3
Activity Coefficients from experimental data (P.S.)
3/6-3/12
Spring brake
3/15
Models for the Excess Gibbs Energy and Margules Equation/ (P. S.)
3/17
Models for the Excess Gibbs Free Energy
3/22
Review Unit 2
3/24
EXAM 2 on Unit 2
Unit 3 Gamma/Phi Method/Electrolyte Equilibrium/Reaction
Equilibrium
3/29
Gamma-Phi method for VLE, Raoult’s law, Modified Raoult’s law,
Read SVNA Ch. 14, B .N .Popov “Handouts”
3/31
Dew point and Bubble point calculations
4/5
Flash calculations: Problem Solving
4/7
Reaction Equilibrium , Read SVNA Chapter15,
Section 13.1, 13.2, 13.3, 13.4 13.5, 13.6, 13.7
4/12
Application of equilibrium criteria to chemical reactions/
Standard Gibbs Free Energy change and the equilibrium constant
(Effect of Temperature, Van’t Hoff Equation Gas-Phase Reactions
4
4/14
Application of equilibrium criteria to chemical reactions/
Standard Gibbs free energy change and the equilibrium constant
(Effect of temperature, Van’t Hoff Equation gas-phase reactions
4/19
Application of equilibrium criteria to chemical reactions/
Standard Gibbs free energy change and the equilibrium constant
(Effect of temperature, Van’t Hoff Equation gas-phase reactions
4/21
Review Unit 3
4/25
Last Day of Classes
5