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Field-Portable Spectroscopy Introduction • Field-portable spectroscopy has traditionally been used in remote sensing applications. • The technology can be used for on site analysis of soils and agricultural inputs and products. • Field-portable spectroscopy utilizes diffuse reflectance of light in the visible (350-750 nm) and near infrared (750-2,500 nm) wavelength regions of the electromagnetic spectrum (Fig. 1). • The measured spectrum (Fig. 2) contains interpretable information White light dispersed by a prism into the colors of the optical spectrum. about the composition, structure, and concentration of substances in a sample. Applications • Obtaining spectra of end-members (e.g. green and dry vegetation, Increasing Frequency 50,000 cm-1 X-Ray UV 12,820 cm-1 Vis 4,000 cm-1 NIR surface soils, bright and dark targets) for spectral unmixing and calibration of remote sensing imagery. 400 cm-1 FIR, Microwave MIR • Rapid soil and organic resource characterization at remote or difficult field locations where transport of samples is difficult. • Mobile laboratories for soil and plant testing. 200 nm 380 nm 780 nm 2,500 nm Oxisols Lake plain soils Vertisols 25,000 nm Increasing Wavelength Figure 1: The electromagnetic spectrum 0.35 Absorption (Log1/R) 0.3 0.25 Sediment plume in Nyakach Bay 0.2 0.15 0.1 0.05 0 350 850 1350 1850 2350 Wavelength (nm) Figure 2. Visible near infrared spectrum of a soil sample. Spectral unmixing of visible near infrared spectra of three contrasting soil types measured in the field for a Landsat image over Lake Victoria region in western Kenya. The green colour of the sediment plume emanating from the River Nyando in Nyakach Bay indicates the principal source is alluvial soils of the lake plain. Instrumentation • Field-portable instruments can run on battery power. • Reflected light is gathered through a fibre-optic cable. An integrating sphere with an external light source can be used. Key Advantages/Limitations • Portable • External white reference is required • Useful for field applications • Little sample preparation • Rapid acquisition of unprocessed samples • Low cost instrument • Visible wavelength range gives • No internal reference or validation available • Instrument needs annual service at factory • Reproducibility across instruments and over time is information on iron oxides in soil unknown • Readings are sensitive to movement of the fibre-optic Field-portable spectrometer fitted with an integrating sphere containing an integrated light source. In this example a soil sample contained in a Petri dish is being scanned. Contact: World Agroforestry Centre (ICRAF), P.O. Box 30677-00100 Nairobi, Kenya. Tel: +254 020 722 4000. www.worldagroforestry.org cable