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هذه األسئله إهداء من عبدهللا الحضري [email protected] ORGANIC CHEMISTRY – PHARMACY Choose the best answer: 1-Sulf drug unable the bacteria to a. divide b. grow c. breath 2-Alkyl halides (more - less - same) polar as hydrocarbon families. 3- CH3C = CH 2Br2 a. CH3CCl2 - CHCl2 b. CHCl2-C-HC c. CH3-CBr2-CHBr2 OH 4- R-CH-R oxidation (keton-thiol-aldehyde) ------------ OH 5- is: a. resorcinol b. catechol c. hydroquinone OH 1 R 6R-C-OH R a. 1o alcohol b. 2o alcohol c. 3o alcohol 7- (diethylether, phenol, glycerol) is widely used as general anesthetic. 8- Carboxylic acids and esters are reduced to give (alcohols, aldehydes, ketones) 9- Et2O is called: a. diethylether b. phenol c. ethene CH3 10-Oxidation of OH MnO4 1. H2O COOH 2. MnO 4 3. 11- Alcohols can dehydrate to form 2 a. alkenes b. phenol c. benzene OH 12- R-CH-H [O] O O H (R-C-H, R-COH , R-C-R) H 13- CH4+H2O (a 3H2+CO (b (c H2+C H2O+CO2 H 14- CH 3-CH 2NCH 2-CH 2-CH 3 (ethylmethyl propylamine , butyldimethylamine , ethyl propylamine) H 15-R-N-R is (primary-secondry-tertiary) amine O 16-CH 3-C-H is (benzaldehyde, acetaldehyde, formaldehyde) O 17-R-C-OH is (RCO2H, RCOOH, both) 3 18- Butane has molecular formula (C5H12 , C4H10 , C5H10) 19-H-C = C-H is a. acetylene b. methyl c. ethane SH 20is: a) ethanthiol b) cyclohexanethiol c) cresol Br CH3CHCH-CH 3 21- Br is: a. 3-bromo-2-chloro butane b. 2,3-dibromo butane c. 2-bromo-3-chloro pentane 22- is: a) Pentane b) Butane c) Propane 4 O OH 23. R-C-Cl OH O O-C-R 24-Alkanes are soluble in a. water b. non polar solvent c. polar solvent 25- The simplest alkane is: a. ethylene b. acetylene c. methane CH3 CH3 26-CH3-CH-CH2-CH2-CH2 is: a. 1-bromo-5-methyl-3-pentane b. 4-ethyl3-methylhexyne c. 1,4-dimethylpentane CH3 27a. 4,5-dimethyl cyclo hexane b. methyl cyclo pentane c. methyl cyclo hexane ether 5 28- R-X+Mg ( R-Mg-X , RMg , RX ). 29- Aniline has molecula formula: a. C6H5NH2 b. C6H6 c. C7H6 Cl 30- Cl a) m-dichloro benzene b) p-dichloro benzene c) o-dichloro benzene Put true or false 1. Atoms are composed of a negatively charged electron .T 2. Atomic number is the number of protons plus neutrons.F 3. Head to head overlap gives π bonds.F 6 4. Sp3 hybridization will form σ bonds.T 5. The most electro negative element is Florine .T 6. The electronegativity decrease horizontally from left to right.F 7. Summation of all individual bond polarity is the dipole moment.T 8. In Chain isomerism there will be cis and trans.F 9. Primary amin can form hydrogen bond.T 10. Alkenes have ageneral formula CnH2n .T Complete: 1. The equation of dipole moment is ---M-=qxd---------. 2. –Agent orange------is a 50:50 mixture of esters of 2,4-D and 2,4,5-T. CH 3 3. is called---Methyl cyclo butane----------- 7 4. 2CH3COOH+Na2 CO3 2CH3COONa+H2O+CO2 Cl CH3CH-CH3 5. chain isomerism CH3-CH2-CH2-Cl is 6CH3 CH 3 H2SO4 OH THF,CO 7- CH3-CH=CH-CH3 is called- ---2-butene----------------- 8- CH3CH-CH2CH3 is called HO 2- butanol------NH 2 9- is called----aniline------------ O 10- CH3-C-H is called---acetaldehyde------------ Write the general formula of: 8 1. Ketone 2. Alcohol 3. Carboxylic acid 4. Ester 5. Alkyl halide RCOR RCH2OH RCOOH RCOOR RX هذه األسئله إهداء من عبدهللا الحضري [email protected] 9