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Ch. 10- Modern Atomic Theory Rutherford’s Atom- but where are the electrons really? The positively charged nucleus deflects some of the alpha particles! What is the nucleus made up of ? Key Vocab 10.2 Electromagnetic radiation- energy (_____) transferred in the form of ___________ waves Wavelength (__) – distance b/w ___ __________ wave peaks Frequency (___) – the # of wave peaks that pass a __________ per given ____________ photons- a _________ of electromagnetic energy, its energy is proportional to its __________ (___) The equations that deal with energy of ER radiation E= λ= What is the frequency of red light, with a wavelength of 7.000 x 10¯5 cm? What is the frequency of blue light, with a wavelength of 475 nm? Problems What is the frequency of red light, with a wavelength of 7.000 x 10¯5 cm? What is the frequency of blue light, with a wavelength of 475 nm? Determine the E of each. Which will be higher in E? Real-life Chemistry- Global Warming 10.3 Emission of Energy by Atoms Energy from flame is absorbed by the ions in solution 1. atoms/ions get excited 2. excess energy released in form of _____ as atom moves to a lower energy of state and 3. emits _______ of light Applications: Notes about burning rainbows Metal ion (from cmpd?) Color of Flame The Bohr Model and Quantized Energy Levels Niels Bohr’s model of the H atom: 1885-1962 -quantized energy levels -circular orbits (we know this is not true now!) Quantized Energy Levels Excited atom- an atom with excess energy (it’s the ______ that are being excited) Ground state- lowest possible energy state The energy in the released photon = Poor Bohr…not quite correct! Orbitals are nothing like orbits!! 1921- Louis de Brogllie introduces wave/particle duality of matter Schrödinger- develops Schrodinger eq’n to better approx. behavior of atoms more complicated than hydrogen (1926) The quantum (wave) mechanical model Orbital – potential area of space where the electron may be Principal energy levels are quantized The shapes Quiz: Section 10.9 What are valence electrons, what are core electrons, and which ones are the important ones for bonding? Electron Spin Pauli Exclusion Principle- an atomic orbital can hold a maximum of two electrons, and those two electrons must have opposite spins 1st things 1st: Vocabulary time Electron configuration: the pattern of how the e’s of an element fill into available orbitals Ex: Li: 1s22s1 Orbital diagram: a representation of electron configuration using arrows for the electrons Two more vocab terms before act-out Valence electrons – the electrons in the highest principal energy level, the most important for bonding! Core electrons – the inner, non-bonding electrons Bitty Bit of Review, then Some New Write out the full electron configurations of the following: N: Si: V: Some rules for e. configs. • The s orbitals of the n+1 level will fill before the ___________ of the ____ level • The lanthanide series are the elements that fill in the ____ orbitals • The actinide series are the elements that fill in the ____ orbitals Determine the abbreviated electron configurations for the following and give the number of valence electrons Sr: Mo: As: Main-group elements Elements in groups 1,2, 13-18 Every member of a group has the same ____________ but these electrons are in different ____________ Atomic Properties Metals-have luster -ductile (pulled into -conductors of pounded to + Atomic Properties Non-metals -opposite of metals Metalloids -elements that show both _______ and ___________ properties Atomic Properties Ionization Energy Trends Atomic Properties Atomic Size