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Exam-I Review (2014) (15% of total grade) Geochem/Habitable Planet EESC 3101 • (Lectures 1-8) Format: Short answer, sketches, short calculations, interpreting plots Bring calculator, pencils/pen, may use periodic table and nuclide chart in room Closed book, based on lecture material and problem sets - key topics outlined below: Basic Chem Review Nuclear: A, Z, N, nuclide chart, valley of stability, radioactive decay mechanisms (beta, positron, e capture, alpha and fission) Chemistry: electron orbitals, ions, cations, anions, bonds, ionic size solid solution, charge-coupled substitution, trace elements Noble gases, alkalis, alkaline earths, halogens, rare earths, transitions, actinides Siderophile, lithophile, chalcophile Nucelosynthesis Big Bang (H, He); Stellar Fusion (what burns, what is created, T) Evolution of our Sun R-, S-, P-, X- process; Special: H, He, Z=5, Z=8, A=209, Tc Odd-even, multiples of 4, magic numbers (50, 82, 126) How to explain abundance of nuclides in our solar system Our Solar System Meteorite origins and classes (iron, achondrites, carbonaceous chondrites) Solar abundances, atomic absorption; Planets, density and composition Condensation T and differentiation of the solar nebula; refractory, volatile Terrestrial planets = 16O, 24Mg, 28Si, 56Fe (why not others?) Ages and Isotopes Rb-Sr, radioactive decay and isochron method; initial v. radiogenic Nd = Np (e t -1) + Ndi - know this equation - decay constant vs. half-life U-Th-Pb system and half lives, initial Pb (all or none?) Pb 207/206 model ages, sketch concordia diagram; Age of CAI, achondrites U-Th steady-state constraints on nucleosynthetic production in galaxy Extinct Nuclides (26Al-26Mg, 182Hf-182W); constraints on age of solar nebula Early Earth-Core-Moon Oldest rocks, zircons, concordia; Extinct Nuclides (182Hf) and constraints on core formation Basic Earth structure, evidence for core; Mass balance Goldschmidt's elements (litho-, chalco-, sidero-phile), and examples Light elements in core - candidates, silicon evidence Pressure-depth, P = pgz, GPa and kb Optional (topic of Tuesday’s lecture); TBD Moon density, volatiles (K/U), oxygen isotopes, Hf iso. Capture, co-accretion, impact theories K/T boundary impact, Ir, Os isotopes and evolution