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PAGEOPH, Vol. 128, Nos. 3/4 (1988) 0033~553/88/040683M251.50 + 0.20/0 9 1988 Birkh/iuser Verlag, Basel Recycling of the Continental Crust SCOTT M . M C L E N N A N 1 Abstract--In order to understand the evolution of the crust-mantle system, it is important to recognize the role played by the recycling of continental crust. Crustal recycling can be considered as two fundamentally distinct processes: 1) intracrustal recycling and 2) crust-mantle recycling. Intracrustal recycling is the turnover of crustal material by processes taking place wholly within the crust and includes most sedimentary recycling, isotopic resetting (metamorphism), intracrustal melting and assimilation. Crust-mantle recycling is the transfer of crustal material to the mantle with possible subsequent return to the crust. Intracrustal recycling is important in interpreting secular changes in sediment composition through time. It also explains differences found in crustal area--age patterns measured by different isotopic systems and may also play a role in modeling crustal growth curves based on Nd-model ages. Crustal-mantle recycling, for the most part, is a subduction process and may be considered on three levels. The first is recycling with only short periods of time in the mantle ( < 10 m.y.). This may be important in explaining the origin of island-arc and related igneous rocks; there is growing agreement that 1-3% recycled sediment is involved in their origin. Components of recycled crustal material, with long-term storage (up to 2.5 b.y.) in the mantle as distinct entities, has been suggested for the origin of ocean island and ultrapotassic volcanics but there is considerably less agreement on this interpretation. A third proposal calls for the return of crustal material to the mantle with efficient remixing in order to swamp the geochemical and isotopic signature of the recycled component by the mantle. This type of recycling is required for steady-state models of crustal evolution where the mass of the continents remains constant over geological time. It is unlikely if crust-mantle recycling has exceeded 0.75 km3/yr over the past 1-2 Ga. Good evidence exists that selective recycling is an important process. Sedimentary rocks preserved in different tectonic settings are apparently recycled at different rates, resulting in a bias in the sediment types preserved in the geologic record. Selective recycling has important implications for the interpretation of Nd model ages of old sedimentary rocks and in the analysis of accreted terranes. Although there is evidence that continental crust was formed prior to 3.8 Ga, the oldest preserved rocks do not exceed this age. It is likely that the intense meteorite bombardment, which affected the earth during the period 4.56-3.8 Ga, coupled with rapid mantle convection, which resulted from greater heat production, caused the destruction and probable recycling into the mantle of any early formed crust. Although crust-mantle recycling is seen as a viable process, it is concluded that crustal growth has exceeded crust-mantle recycling since at least 3.8 Ga. Intracrustal recycling has not been given adequate consideration in models of crustal growth based on isotopic data (particularly Nd model ages). It is concluded that crustal growth curves based on Nd model ages, while vastly superior to those based on K/Ar or Rb/Sr, tend to underestimate the volume of old crust, due to crust-mantle and/or intracrustal recycling. Research School of Earth Sciences, The Australian National University, Canberra, A.C.T., 2601, Australia. Present address: Department of Earth and Space Sciences, State University of New York at Stony Brook, Stony Brook NY 11794-2100, U.S.A. 684 Scott M. McLennan PAGEOPH, Key words: Continentalcrust, crustal evolution,isotopes, mantle, recycling,sediment,subduction. 1. Introduction Recycling of continental material has played a central role in many of the important debates in earth sciences. For example, during the great discussion over the age of the earth during the second half of the nineteenth century, JOLY (1899) estimated the age by calculating the time required to accumulate the net sodium content of the oceans using estimates of the annual sodium flux from the continents (a variation of this approach was first proposed by Edmund HALLEY, 1717). FISHER (1900) pointed out the flaw in this argument by recognizing that much sodium is recycled back onto the continents as sedimentary material, thus considerable extending the 80-90 million year age calculated by Joly. The calculation of Joly, in fact, represents an estimate of the residence time of Na in sea water, which now is known to approach 200 million years (BROECKER and PENG, 1982). During the past 15-20 years, recycling of continental crust has become a major issue in the debate over crustal and mantle evolution. Two landmark publications are notable (ARMSTRONG, 1968; GARRELS and MACKENZIE, 1971). The suggestion, based on Pb isotopic data, that the continents have remained at near their present mass over the past ca. 2.5 Ga (e.g., PATTERSON and TATSUMOTO, 1964) was seen to be in conflict with Sr isotopic data that suggested continental growth throughout earth history (e.g., HURLEY et al., 1962). ARMSTRONG (1968) attempted to reconcile these views by suggesting a steady-state model of crustal evolution where considerable amounts of crustal material was recycled and remixed into the mantle. With regard to a very different problem, GARRELS and MACKENZIE (1971) proposed a recycling model to explain the mass-age distribution of sedimentary rocks. They argued that over Phanerozoic time, at least, the sedimentary mass remained constant and that the exponential mass-age relationship found for sediments was due to recycling, rather than continual accumulation. There are two very distinct types of continental recycling that are reflected in the publications of ARMSTRONG (1968) and GARRELS and MACKENZIE (1971). The first may be termed crust-mantle recycling. In this process, continental crust is returned to the mantle and either stored as a separate entity or remixed with the mantle. At a later time, this material may be incorporated into magmas erupted at the earth's surface and ultimately reaccreted to the continental crust. Such a process must be considered in questions dealing with island-arc and ocean island petrogenesis and with growth models of the continental crust. The second type of recycling may be termed intracrustal recycling. This is concerned with crustal material which loses its primary identity by processes taking place wholly within the crust. Examples include sediment-sediment recycling, isotopic resetting (related to metamorphism), intracrustal melting and assimilation. This process is important in Vol. 128, 1988 Recycling of the Continental Crust 685 questions of secular variations of sediment composition, area-age relationships of sediments and basement provinces, as well as the origin and preservation of crustal rock types. In this paper, the role of continental recycling in crustal and mantle evolution will be addressed. A clear distinction will be made between crust-mantle and intracrustal recycling and some of the pitfalls associated with confusing these processes will be considered. 1.1. Models of Crustal Evolution It is not within the scope of this paper to review all the arguments associated with the various models of crustal evolution. Such a discussion may be found in TAYLOR and MCLENNAN (1985). It is important, however, to describe briefly the importance which recycling plays in such models. Models of crustal evolution may be divided into two distinct catagories: growth models and steady-state models (Figure 1). The first takes what is considered a conventional view of isotopic data, where crustal rocks with mantle-like initial isotopic ratios (Sr, Pb, Nd, Hf) are taken to represent new additions to the crust from the mantle. In such models, continental crust often is considered too buoyant to ever be returned to the mantle in appreciable quantities (e.g., MOORBATH, 1978). I l I I _ I I I Armstrong I ~ 9 ~..e ~0~ ~ I ~ [ . 0 ~ [ I 0 ~ J 0.80 ~j - __ / - 0.20 L~ /J I / ~ - / 4.0 I :5.0 I I 2.0 I I 1.0 I Age (Ga) Figure 1 Examples of various crustal growth models. They can be divided into two varieties. The first with all of the growth early in earth history and later steady state (ARMSTRONG, 1968, 1981), and the second with continuous (HURLEY and RAND, 1969) or episodic (McLENNAN and TAYLOR, 1982; TAYLOR and McLENNAN, 1985; NELSON and DEPAOLO, 1985) growth throughout earth history. Steady state models explicitly require significant crust-mantle recycling. 686 Scott M. McLennan PAGEOPH, Crustal growth may be either continual or episodic in such models although most workers currently seem to favour episodic crustal growth with most of the continents ( > 50%) being in place by about 2.5 Ga (e.g., MOORBATH, 1978; VEIZER and JANSEN, 1979; DEWEY and WINDLEY, 1981; TAYLOR and MCLENNAN, 1981; 1985; MCLENNAN and TAYLOR, 1982; NELSON and DEPAOLO, 1985). In these models, the well-known exponential area-age relationship (based mainly on K-Ar data with some Rb-Sr data) for crustal provinces (HURLEY and RAND, 1969) may be attributed to intracrustal recycling processes (VEIZER and JANSEN, 1979). The steady-state models take a fundamentally different view. In these models, crustal material is returned to the mantle in substantial quantities and remixed in an efficient manner. Accordingly, their unique isotopic signature is swamped by the mantle and is not recognizable when returned to the crust. To accommodate the exponential basement age distribution (HURLEY and RAND, 1969), and the scarcity of rocks >2.9 Ga old, such models rely on an exponentially declining rate of crust-mantle recycling during earth history, in parallel with the declining heat generation of radioactive elements (ARMSTRONG, 1981). It is axiomatic that such a model predicts the isotopic data and consequently, the isotopes cannot be interpreted uniquely (ARMSTRONG, 1968; 1981; PATCHETT and CHAUVEL, 1984). Accordingly, independent evidence for the occurrence and magnitude of crustmantle recycling must be sought. A number of variations on these models has also been proposed. FYFE (1978) has supported the Armstrong models but added the further suggestion that over the more recent past the mass of the continents has actually diminished. REYMER and SCHUBERT (1984) have argued that a substantial portion of the crust (ca. 50%) was formed very early in earth history with the rest forming at a uniform rate over the past four billion years. It is commonly the case in scientific debate that divergent views become polarized and middle ground is ignored. Thus it is important to emphasize that crustal growth models are perfectly plausible even if recycling takes place on a large scale. The important criteria is that generation of new crust exceeds removal of crust to the mantle. The converse, however, is not the case and steady-state models are untenable without substantial crust-mantle recycling. 2. Recycling Within the Continental Crust Recycling of continental crust wholly within the continents (intracrustal recycling) occurs on many scales. For example, simple bioturbation can be considered as intracrustal recycling on a very fine scale whereas the generation of batholiths from intracrustal melting is an example of intracrustal recycling on a very large scale. It is well beyond the scope of this paper to address all of these recycling Vol. 128, 1988 Recycling of the Continental Crust 687 processes and only those which are particularly relevant to questions of crustmantle evolution will be addressed. A first order pattern in the preservation of may geological features is the exponential relationship between cumulative distribution and age (VEIZER and JANSEN, 1979). Examples of this include the distribution of sedimentary rocks, many ore deposits, oceanic crust and ages of crystalline basement of continents measured by either K-Ar or Rb-Sr age determinations (Figure 2). Such features are unlikely to be a consequence of simple accumulation. For example, the discrepancy between the area-age relationship of crystalline basement measured by different isotopic systems (Figure 2a) cannot be a primary feature and is related to secondary processes resulting in the resetting of isotopic systems. The exponential area-age relationship of oceanic crust (Figure 2b) is readily interpreted through recycling of oceanic crust into the mantle at subduction zones. 2.1. Sedimentary Recycling Sedimentary recycling can be viewed on two scales. The first is the direct turnover of sedimentary material (sediment-sediment recycling). Direct evidence of this process is seen in the petrographic examination of sedimentary rocks, where sedimentary rock fragments are a regular occurrence (PETTIJOHN et al., 1973). It is commonly held that, for Phanerozoic sedimentary rocks at least, the generation of I 0-4 75 I I a Basement ages (area) / / I ,// I I Ocean / C Sedimentlary i rocks (mass) -..//]1 (D > o g ~50 E ~25 (_3 r /7 I 3.0 f I 2.0 (Ga) I 1.0 150 I00 (Ma) 50 1.5 1.0 (Ga) 0.5 Age Figure 2 Cumulative per cent area (or mass) v e r s u s age for a number of geological features. An exponential relationship is commonly seen. In the cases shown, it is unlikely that simple accumulation is responsible and some form of recycling is taking place (VEIZER and JANSEN, 1979, 1985). The best example is the ocean crust (Figure 2b), where recycling into the mantle by plate tectonic processes is well established. Data from compilations of VE]ZER and JANSEN (1979, 1985). 688 Scott M. McLennan PAGEOPH, extensive quartz-rich sand bodies can only be achieved through substantial sedimentary recycling (PETTI~OHN et al., 1973; however, see JOHNSSON et al., 1988). Such petrographic measures of sediment recycling are useful, for example, in interpreting the plate tectonic setting of sandstones (e.g., DICKINSON and SUCZEK, 1979). It is this direct turnover of sedimentary debris that is considered in recycling models that attempt to explain the mass-age distribution of preserved sedimentary rocks (Figure 2c) (GARRELSand MACKENZIE,1971; VEIZER and JANSEN, 1979; 1985). The tendency for decreasing preservation with increasing age generally is not considered to be a primary feature. One reason for this is that the pre-human sediment flux to the ocean ( ~ 12.3 • 10 j5 g/yr; TAYLOR and MCLENNAN, 1985) is sufficient to produce about 20 times the present sediment mass over earth history. Thus, either some reworking of sediment must occur or the sedimentation rate would have to be drastically lower earlier in earth history. The most likely interpretations are that: 1) the sediment mass has remained essentially constant, at least over Phanerozoic time where reasonable records are available, and continually recycled or 2) there is a combination of accumulation and recycling. Arguments and mathematical formulation of these models can be found in GARRELSand MACKENZIE (1971), LI (1972), VEIZER and JANSEN (1979, 1985) and DACEY and LERMAN (1983). The second variety of sedimentary recycling encompasses a much broader definition. This is concerned with the recycling of continental crustal rocks significantly older than the stratigraphic age of the sediment, through sedimentary processes. Thus, it includes the recycling of old metamorphic rocks, old basement, as well as old sedimentary rocks. This view of sedimentary recycling has become important with the recent study of Nd-isotopes in sedimentary rocks, pioneered by MCCULLOCH and WASSERBURG (1978). The Nd-model age of a sediment dates the average age of extraction from the mantle of the various provenance components and thus gives the average provenance age of the sediment. As we will see below, this age frequently exceeds the stratigraphic age of the sediment due to the incorporation (recycling) of older material. Nd-isotopes in sedimentary rocks. The Nd model age of terrigenous sediments is a useful measure of the mean provenance age. A first-order observation is that for most young sedimentary rocks, the model age generally exceeds the stratigraphic age, whereas for sedimentary rocks older than about 2.5 Ga, the model age approximates the stratigraphic age (Figure 3a). Two interpretations of these data can be made. The first (ALLI~GRE and ROUSSEAU, 1984; O'NIONS et al., 1983) assumes that the sediment provides a representative sample of the penecontemporaneous exposed continental crust and the Nd isotopic systematics record the growth and recycling history of the continental crust. VEIZER and JANSEN (1979, 1985) have pointed out, however, that intracrustal recycling due to metamorphism and intracrustal melting is considerably less efficient than sediment--sediment recycling 9 ... " I 2,0 Jr- , :5.0 I $ 9 4.0 a I / " I 1.0 2.0 3.0 TSTRAT. (Ga) J OoO I I I 4.0 ' ] oOo oO I I 1.0 2.0 I00% closed I 3.0 oo / I 4.0 I " Figure 3 Plol of Nd model age (T~a4)r~ v e r s u s stratigraphic age (TsTgAT) for sedimentary rocks. The model ages use the depleted mantle parameters of TAYLOR and MCLENNAN (1985). Each point represents one or more samples from a given formation, lithology, etc. (from data compilation in TAYLOR and MCLENNAN, 1985; plus HENSEL et al., 1985; CLARKE and HALUDAY, 1985). 3(a) Nd model ages are similar to stratigraphic ages for samples > 2.0-2.5 Ga but become increasingly greater than stratigraphic age in post-Arehean sedimentary rocks. The favoured explanation is that during the Archean, the sedimentary mass was growing and preserved sedimentary rocks a,e mainly first-cycle whereas during the post-Archean, the mass of sediments was near constant and preserved sedimentary rocks were strongly influenced by sedimentary recycling processes. 3(b) Model showing the effects of recycling a sedimentary mass that has remained constant for 4.5 Ga (recycling parameters derived from VEIZER and JANSEN, 1985). Evolution calculated for a system which is closed to differing degrees; thus 90% closed represents a system which is recycled but in each cycling period (here taken at 250 Ma), 10% of the sediment is lost from the system (to the mantle, lower crust, etc.) and replaced by new mantle-derived material. In this model, "0'-age sediments are best explained by a system which is > 80% closed. For a system in which sediment-sediment recycling dominates, this represents an upper limit on crust-mantle recycling (VE~zER and JANSEN, 1985). 3(C) Model similar to that shown in Figure 3b, but where the sediment mass grows from 4.5 2.5 Ga, with no recycling. From 2.5 Ga, recycling modeled as in Figure 3b. This model fits the sediment Nd isotopic data best (VEIZER and JANSEN, 1985) and 'O'-age sediments require a system which is >85% closed. Models which incorporate shorter time intervals for mixing and recycling, allow growth in the sediment mass during the post-Archean or preferentially recycle young sediment, will increase the degree to which the system is closed. I 1.0 1.0 ~ o~176176 Eg2~ 4.0 - - I 0 ma < e 690 Scott M. McLennan PAGEOPH, and accordingly, the Nd-isotopic systematics of sedimentary rocks primarily record the growth and sediment--sediment recycling history of the sedimentary mass (while still recording any basement recycling which does occur) (also see GOLDSTEIN et al., 1984). All workers agree that, in principle, the Nd model age records the mean age of mantle derivation of the provenance rocks. In Figure 3, the Nd-isotopic data are also modeled in terms of the efficiency of sediment--sediment recycling (VEIZER and JANSEN, 1985). Two models are presented; one with the entire sedimentary mass present at 4.5 Ga and the other with sediment accumulation (with no recycling) to 2.5 Ga, with the entire sedimentary mass present by 2.5 Ga. As pointed out by VEIZER and JANSEN (1985), the latter model fits the sedimentary data best. In either case, the data cannot be modeled by a totally closed system but require the addition of young crustal material. The degree to which this new young mantle-derived material may be incorporated (i.e., openness) is not highly sensitive to the exact model (see Figures 3b,c) and suggests that the sedimentary system is about 10-20% open (i.e., 80-90% closed) to new additions of young crust during the post-Archean (VEIZERand JANSEN, 1985). In detail, the degree of openness is highly variable in sedimentary rocks. MCLENNAN et al. (1985) have pointed out that there is some control by plate tectonic setting on Nd isotopic composition of sediments, with high end values (low Nd model ages) coming from active tectonic zones (island arcs, continental arcs, back arcs). Similarly, HENSEL et al. (1985) found that Devonian-Carboniferous sediments deposited in association with a volcanic chain had Nd model ages only slightly in excess of stratigraphic age (TDM Nd = 0.75 Ga; TSTRAT ~ 0.35 Ga), indicating a substantial mantle-derived component. MICHARD et al. (1985) also noted that during the Phanerozoic, European sediments deposited during orogenic periods tended to have higher end values which generally correlate with lower Nd model ages. Much of the Nd isotopic data for young sediments, collected to date, have been from rivers draining trailing edge margins or from ocean basins adjacent to trailing edge margins (e.g., GOLDSTEIN et al., 1984). Thus it is possible that the present '0'-age sediment data base is biased towards older Nd model ages. It is also notable that in the geologic record, it is likely that there is a bias towards the preservation of cratonic sedimentary rocks (see below). This is because active margin sediments are recycled much faster than average sediment (VEIZERand JANSEN, 1985) and become less abundant in the sedimentary record (see Section 4.1). Sedimentary recycling and sediment composition. There is a long history of examining secular variations in sediment compositions. Long-standing arguments exist over the relative importance of compositional evolution of the upper crust (e.g., RONOV and MIGDISOV, 1971) versus chemical changes resulting from recycling (GARRELS and MACKENZIE, 1971). Recently, most workers agree that both processes may affect sediment composition (VEIZER, 1979; MCLENNAN and TAYLOR, 1980; TAYLOR and MCLENNAN, 1985). Vol. 128, 1988 Recycling of the Continental Crust 691 The Th/U ratio of sedimentary rocks is particularly susceptible to the effects of sedimentary recycling. During weathering, uranium may be oxidized from the insoluble U +4 to the soluble U +0. The U may be lost (to ocean crust, ore deposits, etc.) causing an increase in Th/U ratios. Much of the available high quality data on Th/U ratios in shales is summarized in Figure 4 (McLEYNAN and TAYLOR, 1980; TAYLOR and MCLENNAN, 1985). There is considerable spread in the data, but they indicate an increase in Th/U ratio over post-Archean time, related to a gradual decrease in U. This is consistent with successive periods of weathering and recycling. The sharp break in U abundances (also seen for Th) has been related to a change in upper crustal composition approximately at the Archean-Proterozoic boundary (MCLENNAN and TAYLOR, 1980) (see below). The Th/U ratio appears to remain near the planetary value of 3.8 during the Archean. Two interpretations are possible. The first is that the atmosphere was deficient in free oxygen prior to about 2.0-2.3 Ga (e.g., CLOUD, 1976), inhibiting I I I I I I , - - ' J ~ - 5.0 ~-.5 Th - , 9 U f r 3.5 I I I I I r I ~- I :s.o U (ppm) 2.0 1.0 I I 3.0 I I I 2.0 I ! 1.0 Age (Go) Figure 4 Plot of Th/U and U against age for fine-grained terrigenous sedimentary rocks. Data from compilation of TAYLOR and McLENNAN (1985). Uncertainties are great but the data are consistent with an increase in Th/U, due to a decrease in U, over post-Archean time. This would be consistent with the effects of successive weathering and recycling of the sedimentary mass. Archean U values, for sediments from low-grade terrains, are much lower, consistent with a differing composition for the upper crust (McLENNAN and TAYLOR, 1980). For Archean samples, Th/U ratios are near the planetary value of 3.8 (although, locally in high-grade terrains, they may rise to above 4). This could be due to a lack of recycling during this period and/or to the paucity of free oxygen in the Archean atmosphere resulting in little or no oxidation of U during weathering. 692 Scott M. McLennan PAGEOPH, the oxidation of uranium during weathering. Alternatively (or coincidentally), sediment-sediment recycling was considerably less important in controlling overall sediment composition during the Archean; with first cycle sediments dominating, resulting in less opportunity for fractionation of Th from U. This latter explanation is consistent with the Nd isotopic data which suggest that many preserved Archean sediments did not have a long recycling history (either as sediment or pre-existing crust). It is also consistent with the observation that in some Archean high-grade terrains, Th/U rise to fairly high values ( > 6) which, if not a metamorphic effect, would indicate considerable recycling at least on a local scale (TAYLOR et al., 1986). Insoluble trace elements (REE, Th, Sc) in fine-gained sedimentary rocks may be used as an index to monitor changes in upper continental crustal composition (see recent discussion in TAYLOR and MCLENNAN, 1985). A distinct break in sedimentary trace element characteristics, notable REE abundances and Th/Sc ratios, has been observed at the Arcbean-Proterozoic boundary (Figure 5) which is consistent with a change to more felsic upper crustal composition (MCLENNAN et al., 1980; TAYLOR and MCLENNAN, 1985). The data show no secular trend during postArchean time and this has been taken as evidence that there has been no change in upper crustal composition during that time (TAYLOR and MCLENNAN, 1985). VEIZER and JANSEN (1979) pointed out that intracrustal sedimentary recycling would inhibit or buffer the detection of changes in upper crustal composition in sedimentary rocks. This effect can be seen in Figure 5 where the expected evolution of sedimentary Th/Sc ratios are modeled for a given evolution in upper crustal composition (c~mparable to the magnitude of change seen across the ArcheanProterozoic boundary) and differing degrees of openness during the sedimentary recycling. Even when recycling is taken into account, for reasonable degrees of openness of about 10-20% (see Figure 3), the available sedimentary data would appear to argue against changes of the magnitude shown in Figure 5. Two important points can be made from the above discussion. First, sedimentary recycling may greatly buffer changes in sediment composition resulting from a change in upper crustal composition. Consequently, only elements or elemental ratios in sedimentary rocks which are extremely sensitive to bulk compositional differences (Th/Sc is the best example) provide reasonable indexes to changes in upper crustal composition. This latter point is important in relation to recent suggestions by GOLDSTEIN et al. (1984) and MILLER and O'NIONS (1985) that Archean and post-Archean upper crusts were of similar composition because average Sm/Nd ratios are indistinguishable in Archean and post-Archean sedimentary rocks. Sm/Nd ratios are not highly sensitive to changes in bulk composition and models which suggest changes in upper crustal composition (TAYLOR and MCLENNAN, 1985) predict only < 20% differences in Sm/Nd ratios between Archean and post-Archean upper crusts. This would be difficult to detect in sedimentary rocks without a large data base and recognizing such a change would be further hampered by any effects of sedimentary recycling. Vol. 128, 1988 Recycling of the Continental Crust I I I 693 I I :.3.0 2.0 ^~ c\O~ "~ :o~1 0 1 . ~ . -- ~_~v>d~ / /, i / ~ P ~ i ; . ~ _---- .- - Th , " i. i.o Sc 0.8 -- 0 . 6 L I I 3.0 l -- 0 . 4 I I 2.0 I I 1.0 Age (Go) Figure 5 Plot of Th/Sc against age for fine-grained terrigenous sedimentary rocks. Data from compilation of TAYLORand MCLENNAN(1985). Since Th is strongly concentrated in acidic, and Sc in basic rocks, this ratio is particularly sensitive to the composition of the upper continental crust. The sharp increase in Th/Sc ratio (factor 2.5) at the Archean-Proterozoic boundary is taken as evidence for a change in upper crustal composition. Th/Sc values remain constant throughout the post-Archean. A model is shown to illustrate how recycling, with the system being closed to differing degrees, may buffer the sedimentary response to changes in upper crustal composition. The solid line shows a model of upper crustal evolution from Th/Sc = 1.0 to 3.0 over 2.5 Ga. The dashed lines indicate the predicted response in sedimentary rocks for a recycling system which is closed to varying degrees. In spite of this buffering, changes in upper crustal composition, of magnitude similar to the change at the Archean-Proterozoic boundary (factor of 3 for Th/Sc) appear to be excluded by the available sedimentary data. Preferential recycling of young sediment would increase the expected response in the sedimentary system. Concentration data and modeling parameters of TAYLOR and MCLENNAN (1985) (see their Figure 5.10) are updated to be consistent with recycling constraints of VEIZER and JANSEN (1985). 2.2. Metamorphism and Isotope Resetting The possible resetting o f most isotop!c systems d u r i n g m e t a m o r p h i s m is well established, a l t h o u g h the c o n d i t i o n s required vary with the i n d i v i d u a l isotopes. It is generally recognized that K - A r systems m a y be reset at fairly low t e m p e r a t u r e s (ca. 200~ with R b - S r a n d U / T h - P b whole rock systems reset at m u c h higher temperatures a n d generally o n a smaller scale. Recent work (DEPAOLO et al., 1982; 694 Scott M. McLennan PAGEOPH, MCCULLOCH and BLACK, 1984; BLACKand MCCULLOCH, 1987) indicates that the Sm-Nd system can also be reset, at least on a local scale, at high temperatures (>__700~ where deformation has occurred. This observation is particularly relevant for Nd model age studies which use individual hand samples of commonly heterogeneous rock units. VEIZER and JANSEN (1985) have quantified these effects on a large scale by examining the area-age distribution of basement provinces using the K-Ar and Rb-Sr (plus some U-Pb) data (Figure 2a). The differences in the rates of recycling required to explain the discrepancies in the curves depend on the exact model of crustal growth which is adopted. For exposed rocks and for growth models similar to those of TAYLOR and MCLENNAN (1985) or VEIZER and JANSEN (1985) (see Figure 1), K-Ar has been reset about 7 times more efficiently and Rb-Sr has been reset about 3 times more efficiently than Sm-Nd systems in exposed rocks. The discrepancy between the area-age relationships for the various isotopic systems and the actual growth curve for the continental crust is due to recycling. For the Sm-Nd system, any difference may be due either to crust-mantle recycling or to intracrustal recycling (intracrustal melting, isotopic resetting, assimilation). The discrepancies between the Sm-Nd distribution and the Rb-Sr and K-Ar distributions are almost certainly due exclusively to intracrustal recycling. 2.3. Intracrustal Melting The role of intracrustal melting in the development of the continental crust is well documented. For example, the Andesite model for crustal growth during the Phanerozoic (TAYLOR, 1967, 1977) relies on intracrustal melting as the primary mechanism for the development of a granodioritic upper continental crust from accreted island-arcs and continental-arcs. The most exhaustive geochemical studies of granitic rocks have been conducted in south-east Australia (WHITE and CHAPPELL, 1983; MCCULLOCH and CHAPPEEL, 1982; CHAPPELL, 1984). Most granites here can be divided into I-type (igneous precursor) and S-type (sedimentary precursor), both of which are derived from melting within the crust. I-type granites represent a first stage recycling episode with the precursors probably having a fairly direct mantle origin, with only a short crustal residence prior to final intrusion. S-type granites are examples of second or third stage recycling with the precursor sediments having gone through at least one weathering event and possibly being derived from continental crust with a recycling history. The available isotopic data further support an intracrustal origin for many granitic rocks, at least during the Phanerozoic. The Nd data are particularly significant, and are summarized in Figure 6 (ALLt~GREand BEN OTHMAN, 1980; HAMILTONet al., 1980; MCCULLOCHand CHAPPELL,1982; DEPAOLO and FARMER, 1984). Granitic rocks older than about 2.0Ga have Nd-isotopic compositions /~ ++++++++++L+§ ~Nd -I0 9++~ ++- t++++++++++++++++++~+~+++++++++++++++*+++++++++++++++++++++§+++ / -15 -20 -2~ ++++++++++++++++++++~.~ + ++ ++ ++ ++ ++ ++ ++ ++ ++ ++ ++ + ~+ ++ ++ ++ ++ ++ +~ ~ . O ~ +++++++++++++++++5// ~+++++++++++++++4 ++++++++++++++~ +++++++++§ ++++++++++~++ +++++++++++~ ~ r ~++++++++++u +++++++++++ + + + + + §+ + + + ++++++++' +++++++++++++~ +++++ ++++ +++~ +++ ;Y 695 Recycling of the Continental Crust Vol. 128, 1988 l I I,O f.~ fr~ v /~_~ ~ ~ i,, I I 2.0 I I B.O I I 4.0 Age (Ga) Figure 6 Plot of end against crystallization age for granitic rocks. Data defining the shaded area are listed in ALLEGREand BENOTHMAN(1980) and HAMILTONet aL (1980); McCULLOCHand CHAPPELL(1982); DEPAOLOand FARMER(1984). Also shown are the evolution paths for typical mantle and typical crust of varying ages. Most younger granitic rocks have low end values inconsistent with a direct origin from the mantle. The data indicate an increasing importance of intracrustal melting after a significant crustal residence time, for the origin of granitic rocks during the post-Archean. consistent with derivation from mantle-like sources with or without a short period ( < 1 0 0 - 2 0 0 m . y . ) of crustal residence. Younger granites appear to be derived through remelting of older crustal sources with highly variable contributions from young mantle sources. TAYLOR and MCLENNAN (1981, 1985) have pointed out that Sm/Nd ratios usually decrease during intracrustal melting processes. This results in Nd model ages being minimum estimates of the mantle extraction ages of the crustal precursors (also see MCCULLOCH, 1988). Rare earth data for sedimentary rocks also provide important insight into the role of intracrustal melting through earth history. Sedimentary rocks of postArchean age are typified by negative europium anomalies in the REE patterns (Figure 7) with Eu/Eu* -- 0.65 on average. On the other hand, Archean sedimentary rocks rarely display anomalous Eu behavior (TAYLOR and MCLENNAN, 1985). Only locally, in sone high grade terrains are negative Eu anomalies found in Archean sedimentary rocks indicative of small cratonic environments (TAYLOR et al., 1986). 696 Scott M. McLennan I I I I I I I PAGEOPH I I , I I I I I I I I I I 1.0 u') <I) % tM o.9 "~ 0.8 I00 0c- (D "-.. K ArcheQn ~ 0_ rm ','o' E rm Q- IC- I I I I Lo Ce Pr Nd I I I I I I I I I I Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Figure 7 Chondrite-normalized REE diagram of average compositions of Archean and post-Archean sedimentary rocks. Inset shows a plot of Eu/Eu* against time for fine-grained terrigenous sedimentary rocks. Data from compilation in TAYLOR and MCLENNAN (1985). The presence of the Eu-anomaly in post-Archean sedimentary rocks is considered to be representative of the upper continental crust. Negative Euanomalies are most likely the product of intracrustal melting with residual Eu-enriched plagioclase being held in the lower crust. The sedimentary REE data indicate that intracrustal melting processes were of limited importance during the Archean but have been dominant in differentiating the continental crust during the post-Archean. In general, unfractionated or primary igneous rocks which are derived from the mantle do not have Eu-anomalies and this is taken as evidence that the continental crust as a whole is not anomalous with respect to Eu (TAYLOR and MCLENNAN, 1985). The most reasonable explanation for the presence of negative Eu-anomalies in post-Archean sedimentary rocks and hence the upper continental crust is widespread intracrustal melting to produce K-rich granitic rocks which typically yield negative Eu-anomalies. The Eu-anomalies in granitic rocks are the result of the fractionation of plagioclase, a mineral stable only to about 40 km depth, thus confirming an intracrustal origin. Both fractional crystallization and intracrustal melting may produce this effect but melting is judged as the dominant process within the crust. The fact that Eu-anomalies are rare in Archean sedimentary rocks is taken as evidence that intracrustal melting processes were of only local importance in the formation of the early Archean crust. This contrasts with the postArchean crust where the sedimentary REE data indicate that intracrustal melting has been a dominant process. Vol. 128, 1988 Recyclingof the ContinentalCrust 697 2.4. Assimilation The final process of intracrustal recycling under consideration is that of assimilation. This is where mantle derived magma interacts with the continental crust and is contaminated with it to a lesser or greater degree. DEPAOLO (1981) has provided the appropriate equations of mixing, which include the complicating factor of combined assimilation and fractional crystallization. There are many examples where crustal assimilation has been demonstrated or suggested. Examples include: 1) assimilation of lower continental crust by island-arc volcanics to explain the incompatible element and isotopic character of island arc volcanics (ARCULUS and JOHNSON, 1981). 2) assimilation of continental crust to explain the isotopic characteristics of some continental flood basalts (CARLSON et al., 1981; Cox and HAWKESWORTH, 1984) and some Archean volcanic rocks (e.g., COMPSTON et al., 1986). 3) contamination of granitic rocks with relatively young ages of mantle extraction by much older continental crust (PATCHETTand BRIDGWATER,1984; DEPAOLO and FARMER, 1984; DICKIN et al., 1984; PATCHETT and Kouvo, 1986). 4) mixing and reworking of old continental crust to explain the isotopic character of some Archean gneisses (TAYLOR et al., 1983; COLLERSONand MCCULLOCH, 1982). In some cases, the degree of crustal contamination can be very large. For example, CARLSONet al. (1981) proposed that as much as 25% crustal contaminant was present in the Columbia River basalts. COLLERSONand MCCULLOCH (1982) suggested that 3.0 Ga gneisses from Labrador were derived by mixing a mantle source with between 4~100% pre-existing 3.65 Ga Uivak-Nulliak gneisses (Figure 8). SPARKS (1986) has recently pointed out that eruption temperatures of magmas have likely decreased through geological time and accordingly, the process of assimilation may have been considerably more efficient during the Archean. 2.5. lntracrustal Recycling and Crustal Evolution It is important to identify and quantify the role of intracrustal recycling in crustal rocks. Recent attempts to generate crustal growth curves rely greatly on Nd model ages of upper crustal rocks to date the time of extraction from the mantle and, accordingly, give a 'true' crustal growth curve (McCuLLOCH and WASSERBURG, 1978; NELSON and DEPAOLO, 1985; MCCULLOCH, 1986; PATCHETT and ARNDT, 1986). However, if the role of intracrustal recycling (notably assimilation, isotopic resetting and decreases in Sm/Nd ratio during intracrustal melting) is not assessed (most efficiently by detailed zircon U-Pb data), the possibility of deriving mixed ages is always present (e.g., see PATCHETTand BRIDGWATER,1984). Thus, it is important to stress that crustal growth curves based on Nd model ages, while decidedly better than those based upon K-Ar and Rb-Sr age determinations, will only approach the 698 Scott M. McLennan I I0 - ~ O I I r I ~0- PAGEOPH, I I I ^ "..'"untie evm,..~..,..~ ~ =V~OlUfio - I Uiv~ksseNU~iaOgke 0 ~Nd -5 o7 _@o~ -I0 ..-7 -15 -20 .,/ / to ~ / - / I I l.O F I I 2.0 I I 30 I I 4.0 Age (Ga) Figure 8 Plot of end against time for Archean gneisses from Labrador (after COLLERSONand McCuLLOCH, 1982). Also shown is mantle evolution for typical mantle and that suggested by Sm-Nd data for the early Archean Uivak-Nulliak assemblages from Labrador, as well as the expected evolution of end for Uivak-Nulliak crust and new crust formed at about 3.0 Ga (the age of the late Archean gneisses). Late Archean gneisses have initial 143Nd/J44Nd ratios which are inconsistent with direct mantle derivation. The favoured interpretation is an origin by mixing 40-100% old crust with new mantle derived crust at 3.0 Ga. true g r o w t h components components because the pre-existing curve. Such m o d e l s will always tend to u n d e r e s t i m a t e the age o f s o m e o f a n y crustal segment, or give a mixed age. The difficulty in identifying o f o l d e r crust using N d m o d e l ages increases c o n s i d e r a b l y in older rocks difference in isotopic c o m p o s i t i o n between the m a n t l e a n d average crust is greatly d i m i n i s h e d (for example, see Figures 6 a n d 8). 3, Crust-Mantle Recycling C r u s t - m a n t l e recycling is the transfer o f c o n t i n e n t a l crust to the mantle. This m a y take place in at least four ways ( F i g u r e 9). The first a n d p r o b a b l y m o s t i m p o r t a n t is the s u b d u c t i o n o f sediments derived either from the u p p e r c o n t i n e n t a l crust or from Vol. 128, 1988 Recycling of the Continental Crust 699 Figure 9 Schematic diagram to illustrate the various mechanisms of crust-mantle recycling. Upper. Mechanisms for return of crustal material into the mantle, include: 1) subduction of sediment derived either from the upper continental crust or from volcanic arcs; 2) enrichment of continental crust-derived elements in the oceanic crust and subduction with the oceanic crust; 3) direct tectonic erosion of continental crust at subduction zones; 4) assimilation of continental crust by the mantle at the base of the crust. Lower. Mechanisms for the recycling of continental material from the mantle back into the continental crust, including: 1) direct return at volcanic arcs, with short residence times ( < 10 m.y.) in the mantle; 2) return, mainly in oceanic islands and continental alkali volcanics, after a long residence time (> 1 b.y.) in the mantle as a distinct entity; 3) efficient remixing with geochemical and isotopic signatures swamped by the mantle signatures, and return in all mantle-derived igneous rocks. the exposed volcanic arc (which here is considered as a less evolved part o f the continental crust). It has long been argued that such a transfer o f sediment is not plausible because o f simple density considerations (e.g., MOORBATH, 1978). Such objections are no longer tenable. It has been established that p r o n o u n c e d horst and graben structures are developed as the oceanic crust bends and descends into the mantle at subduction zones (e.g., HILDE, 1983; UYEDA, 1983). Such structures provide adequate traps which m a y ' d r a g ' sediment to mantle depths. Questions concerning the efficiency o f this process and the fate o f the subducted sediment are matters o f debate, but the physical plausibility o f sediment subduction appears established (also see KURTZ et al., 1986). A second m e t h o d o f recycling continental crust into the mantle is t h r o u g h the enrichment o f certain elements in oceanic crust by h y d r o t h e r m a l alteration and submarine weathering processes and subsequent subduction. Such processes have been reviewed by a n u m b e r o f authors (HOLLAND, 1978, 1984; FYFE, 1978, 1979, 1980; HART and STAUDIGEL,1982; ALBAREDE and MICHARD, 1986). In terms o f overall mass balance, FYFE (1978, 1979, 1980) has argued that a significant mass o f potassium m a y be added to the oceanic crust during submarine spilitization and 700 Scott M. McLennan PAGEOPH, may be transferred to the mantle this way. It has also been established, however, that substantial amounts of K (and other elements) are transferred from the lower ocean crust to the oceans via hydrothermal activity at mid-ocean ridges (HART and SXAUDmEL, 1982). The exact balance of these competing processes is a matter of debate (compare HART and STAUDICEL, 1982 and HOLLAND, 1984) and the magnitude of the net mass transfer of continental potassium into the oceanic crust must be considered as uncertain. Other elements of continental origin which may be subducted in significant amounts by this process include Mg, S and U (e.g., ALBAREDE and MICHARD, 1986). The two final transport mechanisms are less well established. The first is the direct tectonic erosion of continental crust at subduction zones (e.g., KARIG and KAY, 1981; ZmGLER et al., 1981; UYEDA, 1983). The most likely place that this is occurring is in the central part of the Andean arc (KULM et al., 1977). Whether or not this represents a significant flux remains in doubt (KARIG and KAY, 1981). The final transport mechanism is purely speculative and involves the assimilation of continental material directly into the mantle at the base of the crust. There is no direct information to indicate whether this mechanism occurs at all, let alone estimates of flux rates. The overall conclusion to be drawn at this point is that recycling of continental crust to mantle is essentially a subduction process. The possible fate of continental material which is recycled is also shown schematically in Figure 9. Return of recycled material to the continents can be considered on three different scales. The first is direct return of subducted material to arcs after only a short residence time at mantle depths ( < 10 m.y.). The second is return of subducted continental crust as ocean island volcanics (which ultimately may be accreted) or ultrapotassic continental lavas after long residence times in the mantle (up to ca. 2500 m.y.). The final mechanism is the return and efficient remixing of continental crust with the mantle so that the unique chemical and isotopic composition of the continental crust (regardless of its age) is swamped by the mantle signature. This final process is crucial for proposals of steady-state crustal evolution models. 3.1. Island-Arc Volcanics A recycled component of continental crust commonly is invoked to explain the chemical and isotopic composition of island-arc volcanic rocks (see review of GILL, 1981). It has been noted for some time that island-arc basalts are enriched in a number of incompatible elements, notably K, Ba, Sr and Pb, relative to MORB and oceanic island basalts. In addition, island arc volcanics have radiogenic Sr and Pb and unradiogenic Nd and Hf isotopic characteristics, compared to MORB. The interpretation of these characteristics has been debated actively for many years. Various proponents have argued for an upper continental crust sediment component (of varying magnitude) mixed with MORB sources (e.g., SUN, 1980; KAY, Vol. 128, 1988 Recycling of the Continental Crust 701 1980), contamination of MORB sources by lower continental crust during ascent (ARCULUS and JOHNSON, 1981) and ocean-island basalt components (as blobs in the mantle) mixed with MORB sources (MORRIS and HART, 1983). Of these three possible processes, the mixing of sediment is the only one which would indisputably represent crust-mantle recycling. The suggestion of contamination by lower continental crust would be an example of intracrustal recycling, since the lower crustal component remains within the crust. The suggestion of an OIB component may or may not represent an example of crust-mantle recycling, depending on one's views of OIB petrogenesis (see Section 3.2). If the arguments favouring an upper crustal sediment component are accepted (see MORRIS and HART, 1983; 1986; PERFIT and KAY, 1986 for a recent debate of the sediment vs OIB arguments), then Pb isotopes are most sensitive for providing quantitative constraints, because the ratio of Pb in upper crustal sediments to that i n the mantle is > 250, whereas the ratio is < 50 for Sr, Nd and Hf. The lead isotope data are consistent with a very small component of sediment in the range of < 1 3% (SUN, 1980). Be isotopes. The most persuasive evidence of sediment involvement in island-arc volcanism comes from the recent work involving l~ (BROWN et al., 1982). 1~ is produced primarily by spallation reactions on N and O in the upper atmosphere. The half-life is about 1.5 m.y., and 1~ is concentrated only in surficial sediments. Thus l~ is a powerful tracer of sedimentary material during the subduction process (BROWN et al., 1982). Table 1 lists much of the presently available data for island-arc, other volcanic and sedimentary rocks (BROWN et aI., 1981; TERA et al., 1986). It is notable that most non-arc volcanic rocks have very low l~ concentrations whereas marine sediments are enriched by a factor of > 10 4. Volcanic rocks from island arcs and continental arcs have highly variable l~ concentrations. The most important observation is that about one-half of the arcs so far studied have l~ concentrations considerably above those of other volcanics (a cut-off of about 1 x 10 6 atoms/g has been adopted for defining anomalously high values (TERA et al., 1986)), strongly suggesting the presence of a sediment component. Low values of l~ do not of course necessarily preclude the presence of a sediment component. The short half-life, combined with old sediment being involved (due to combinations of slow sedimentation rates, slow subduction rates and large trench-arc distances) can result in the decay of ~~ before the sediment interacts with the island-arc volcanic source (TERA et al., 1986). The exact amount of sediment indicated by the l~ data depends on the model for sediment subduction (e.g., graben fill only, mixture of l~ poor and rich layers during subduction, etc.), but generally is consistent with 1-10%. This is in agreement with the 1 3% sediment component indicated by the Pb isotopic data. An important point is that only the upper 50-100 m of pelagic sediment will Scott M. McLennan 702 PAGEOPH, Table 1 I~ in island arc volcanic rocks (in 106 g/atoms _4-_1s.d.). n l~ _ 1 s.d. Island arc voleanies Central America New Britain Aleutians Peru Japan Philippines Taiwan Mexico Sunda Marianas Cascades Halmahera 17 1 17 6 9 1 1 4 12 12 1 12 6.5 + 6.5 4.1 3.1 _+ 1.3 l 2.1 _ 3.0 1.1 + 1.42 0.8 0.6 0.5 + 0.3 0.4 + 0.2 0.3 _+ 0.3 0.3 0.2 __+0.1 Other volcanics Oceanic island and rift volcanics MORB Flood basalts 14 4 4 0.3 __+0.2 0.2 ___0.13 0.4 + 0.2 Marine sediments Non-marine sediments 16 10 5600 _ 1800 362 _ 67 Volcanic data from TERA et al. ( 1986); sedimentary data from BROWN et al. ( 1981). excluc~es one value of 15.3. 2 exclu/des one value of 13.5. 3 excludes one value of 0.9. contribute ~~ due to the short half life and slow sedimentation rate. Such sediment is most likely to be accreted or underplated (subcreted) to the base of the arc (KARIG and K a y , 1981), whereas the buried sediments with no ~~ are most likely to be subducted (KAY, 1984). The presence of l~ thus suggests that the entire sediment column is available for subduction, the sediment column is well mixed prior to or during subduction (a model favoured by TERA et al., 1986) or that only graben-fill sediment is involved. Role of arc-derived sediment. Most estimates of sediment involvement based on radiogenic isotope data are concerned only with sediments derived ultimately from the upper continental crust. Sediment derived directly from the volcanic arc will have isotopic characteristics identical to arc lavas (MCLENNAN et al., 1985), and insufficient time is available for significant isotopic evolution (Figure 10). Trace element characteristics may approach upper crustal values if intra-crustal differentiation has occurred within the arc and the arc is dissected to expose such material (e.g., Aleutians; MCLENNAN et al., 1985), however isotopic compositions will remain identical to the arc itself. -20 - -15 - -I0 - -,5 -- B I 0 A S I ~ ' ~ 2% ' ~ v ' ~~ 2~176 I I00 I I 200 Arc sediment (AS) Upper crust sediment (UCS) Depleted mantle (DM) I 400 200 13 Sr I 500 I .300 - I 0 2.31:560 .046 -30 86Sr ESr 87n- I 400 16 32 1.0 Nd I .140 .106 .217 6 -15 I0 t44Nd ~:Nd 147c, Figure 10 Plot of eNa against ~s, to show the effect of subducting upper continental crust-derived and island arc-derived sediment. The modeling shows that sediment derived from the upper crust has a significant isotopic effect when mixed with depleted mantle (mixing shown as thin lines), whereas arc-derived sediment must evolve (evolution shown as heavy lines with arrows) for a considerable period of time before an effect will be seen. For subduction occurring 1.1~2.0 billion years ago, the effects of subducting upper crust sediment would have been considerably less because intracrustal recycling effects were less and the isotopic composition of sediments would have been closer to the contemporaneous mantle (see Figure 3). ~Nd 0 I0 o/o~ I Lo E 0 C3 (3 ~0 oo < o 704 Scott M. McLennan PAGEOPH, It is possible that anomalous l~ concentrations would be produced in arc lavas by the subduction of arc-derived material. Sediments which are deposited rapidly, such as many non-marine sediments, have highly elevated 1~ concentrations, although about 10 times lower than pelagic sediments (Table 1). Thus, if such sediment were to be deposited in the trench and transferred rapidly (say < 35 m.y.) to depths required for involvement in island arc volcanism, then it could play a significant role. In any case, attempts to correlate anomalous 1~ abundances with other isotopic characteristics must be done with caution. The main point here is that it is not possible to distinguish the role of arc-derived sediment in island-arc volcanics. Considerable amounts of such sediment could be subducted without detection. This is important when considering oceanic island volcanic petrogenesis (see below). 3.2. Ocean Island Basalts and Ultrapotassic Lavas The differences in geochemistry between MORB and ocean island basalts (OIB) has long been recognized (e.g., GAST, 1968), with OIB being considerably enriched in most incompatible elements in comparison to MORB or the primitive mantle. This was first interpreted as resulting from OIB being derived by much smaller degrees of partial melting of sources similar to MORB (GAST, 1968). Nd and Sr isotopic data suggest a long-term depletion of incompatible elements in the source of many OIB, similar to MORB sources (e.g., CARLSON et al., 1978; HOFMANN and WroTE, 1982), indicating the incompatible element enrichment is a recent event. However, such a model is at odds with the Pb isotopic data which indicate that the MORB and OIB sources have been distinct for the past ca. 2.0 billion years (e.g., SUN, 1980). More recent workers have suggested a number of alternative models including derivation of OIB from: 1. primitive mantle (e.g., SCHILLING, 1973). 2. primitive mantle contaminated with MORB source material (e.g., WASSERBURG and DEPAOLO, 1979). 3. metasomatized mantle OIB source regions (e.g., MENZIES and MURTHu 1980). 4. A recent hypothesis has received considerable attention. This suggests ocean island basalts are derived from partial melting of ancient subducted oceanic crust mixed with depleted mantle (MORB) sources (CHASE, 1981; HOFMANN and WHITE, 1982). In this model, oceanic crust is subducted and stored in the mantle as a separate entity. After sufficient time (ca. 1-2 b.y.) internal heating causes instability and partial melts separate and rise to the surface, interacting with surrounding upper mantle. Such a model does not require a sediment component, and in fact altered MORB crust and sediment may be geochemically and isotopically distinct (see ZINDLER and HART, 1986). In any case, a sediment component in the subducted oceanic crust would represent a significant reservoir of incompatible elements (see WEAVER et al., 1986). Vol. 128, 1988 Recycling of the Continental Crust 705 H f isotopes and O I B genesis. As with island-arc petrogenesis, interpretation of Sr, Nd and Pb isotopic data is somewhat equivocal with respect to the role of a sedimentary component. The short half-life of l~ excludes it as a tracer for processes operating over such long time scales (1-2 b.y.). PATCHETT et al. (1984) have pointed out that Lu is fractionated from H f during sedimentary processes (related to zircon fractionation during sorting) and that shales and pelagic sediments have considerably higher L u / H f ratios than sandstones, which are mainly preserved on the continents. This fractionation allows for the monitoring of a sedimentary component over long-time scales. PATCHETT et al. (1984) analysed a number of sediments for L u / H f and Sm/Nd ratios and modeled the results to determine if the OIB Nd and H f isotopic data are consistent with a sediment component (Figure 11). The modeling indicates that the OIB data would be consistent with about a 2% component of mixed turbidite and pelagic sediment which had evolved in the mantle for about 2 b.y. PATCHETT et al. E I I I i i I I I I0 I 20 3O 2_010 -20 - ~ M O R B Pelogic -:50 Mix 2 -40- -50 - Turbidite 1 '- 0 ~ 2 Ga I -50 I -20 I -I0 I 0 ~Nd Figure 11 Plot of ~ur against end to show the evolution (heavy lines with arrows) of typical pelagic and deep sea turbidite sediments. Mixing calculations (thin lines) indicate that ocean island basalts can be explained by mixing depleted mantle with about 2% of sediment comprising a 1.2/I blend of turbidite/pelagic. It is considered unlikely that turbidite and pelagic sediment would be mixed at such a constant ratio and, accordingly, the sediment explanation has not been favoured (PATCHETT e l al., 1984). Adapted from PATCHETTet al. (1984). 706 Scott M. McLennan PAGEOPH, (1984) have pointed out, however, that the ratio of pelagics to turbidite sediment would have to be constant (at about 1 : 1.2) and well mixed for most OIB's. This was considered unlikely and PATCHETT et al. (1984) concluded that recycled sediment probably was not the primary cause of the Hf-Nd isotopic characteristics of OIB. Role of arc-derived sediments. In contrast with the origin of island-arc volcanics, the subduction of arc-derived sediment may be relevant to the question of OIB genesis. All workers agree that if subducted oceanic crust is the source of OIB, then it would have to reside in the mantle for considerable periods of time, of the order of 1.0-2.5 b.y. (CHASE, 1981; HOFMANN and WHITE, 1982; PATCHETT et al., 1984). Most arc-derived sediments have trace element characteristics which would result in considerable evolution, on this time scale, of their isotopic characteristics (high Rb/Sr, U/Pb; low Sm/Nd, Lu/Hf), and high enough abundances to provide a significant effect on mass balances (Figure 10). Subduction of Precambrian sediment. Models suggesting a role of subducted oceanic crust (with or without sediment) require a 1.0-2.5 b.y. residence in the mantle. Modeling of sediment subduction and storage has only considered modern or comparatively young sediment compositions (PATCHETTe t al., 1984; WEAVER et al., 1986). An obvious question is whether Precambrian deep sea sedimentation (pelagic and turbidites) was different, and whether these differences were sufficient to affect the models? Trace element and isotopic data on Precambrian deep sea sediments are meagre but some qualitative observations can be made which are relevant to this question. It is unlikely that the composition of the upper continental crust has changed appreciably over the past 2.5 b.y. Thus, elements which are transferred nearly quantitatively into clastic sediments will similarly be unchanged over this period (TAYLOR and MCLENNAN, 1985). Accordingly, it is unlikely if Sm/Nd or Lu/Hf ratios have changed significantly in the terrigenous fraction of deep sea sediments over this time. On the other hand, ancient sediments were less affected by intracrustal recycling processes and, accordingly, their isotopic composition was closer to the contemporaneous mantle (Figure 3). In addition, a number of elements of isotopic significance, including Rb, Sr, U and Pb are affected by many secondary processes. Other possible differences in ancient sediments which could significantly affect any isotopic modeling include the following: l) Evolution of calcareous microplankton during the Mesozoic, resulting in a change in the sites of carbonate deposition from the shelves to the deep oceans (FISCHER, 1984). 2) Introduction of significant amounts of free oxygen at about 2.3-2.0 Ga (e.g., CLOUD, 1976) resulting in a change in behavior of uranium at surficial conditions (see Figure 4). Vol. 128, 1988 Recycling of the Continental Crust 707 3) Differing effects of biogenic processes (and debris) in sedimentary geochemistry. 4) Importance of iron-formations as a deep-sea chemical sediment prior to about 1.8 Ga (CLouD, 1976; ERIKSSON, 1983). 5) Increased heat flow resulting in ocean sediments being considerably more influenced by hydrothermal processes and less influenced by upper continental crust (FRYER et al., 1982; VErZER et al., 1982). From this discussion, it is concluded that it is likely that sediment subducted > 1.0 b.y. ago could have had a very different composition than that of today. It is equally possible that differences could have been significant enough to seriously affect isotopic evolution, although there are so few relevant data that a judgement cannot be made as to whether such differences would diminish or enhance suggestions of a sediment component in OIB. However, the possible differences indicate that considerable caution is warranted in the use of modern sediment compositions to model subduction of ancient sediment. Some inferences regarding crust-mantle recycling early in earth history may be obtained from studies of diamonds. There is general agreement that diamonds are mantle derived and recent He, Nd and Sr isotopic data for garnet inclusions raises the possibility that diamonds may have ages in excess of 3.0 Ga (OZIMAe t al., 1983; RICHARDSON et al., 1984). Suggestions of a recycled crustal component in diamonds have been made on the basis of carbon isotopic data (e.g., M~LLEDGE et al., 1983) and noble gas data (HONDA et al., 1987). Ultrapotassic lavas. The ultrapotassic lava suite possesses a number of geochemical and isotopic characteristics broadly similar to alkali basalts found in ocean islands. Such rocks comprise only a trivial volume on any global balance, however, the identification of a sediment component in their source could be important in understanding quite fundamental processes of mantle and crust evolution. The ultrapotassic suite is notable for its variable Pb isotopic composition, often with high 2~176 and low 2~176 (NELSON et al., 1986). Accordingly, the possibility of an ancient sediment component also has been suggested in the origin of these rocks (NELSON et al., 1986). Many of the uncertainties associated with this interpretation, outlined for the origin of OIB, equally apply for the ultrapotassic suite. 3.3. Limits on C r u s t - M a n t l e Recycling The overall limits on the mass of continental crust which may be returned to the mantle are not well constrained. Whether or not crust may be returned by direct assimilation at the base of the crust is not known and no judgement can be made. Tectonic erosion at subduction zones is a more likely phenomenon. DEWEY and WINDLEY (1981) suggest an upper limit of 0.48 x 1015 g/yr or 0.17 km3/yr (for a crustal density of 2.8 g/cc), based on the apparent erosion of western South America. 708 Scott M. McLennan PAGEOPH, It is most likely that direct subduction of sedimentary rocks is the most efficient mechanism for transferring continental crust to the mantle. If we accept the evidence from island-arc volcanics for a sediment component, this provides a minimum estimate. The most recent estimate of Mesozoic-Cenozoic arc accretion rates is 1.1 km3/yr (REYMER and SCHUBERT, 1984) or 3.1 • 1015 g/yr. If we adopt a 2% by mass sediment component, this represents 0.06 x l015 g/yr or 0.02 km3/yr of crustal material. An extreme value on sediment subduction rates over the past 100-200 m.y. may be derived from the total amount of continental crustal material which is delivered to the ocean floor annually. The most recent review of the DSDP and seismic records is that of HOWELL and MURRAY (1986). They conclude (p. 448) that the sedimentary flux from the continents to the oceans is 1.65 km3/yr. Allowing a correction for density, this is equivalent to about 1.5 km3/yr of continental crust. The actual amount available for subduction must be considerably less than this figure since much sediment is recycled back onto the continent during accretionary processes associated with subduction and continental collisions (HOWELL and MURRAY, 1986). Perhaps the best constraints can be obtained by examining long-term global sediment recycling rates (see Section 2.1). This approach was first proposed by VEIZER and JANSEN (1985). For the mass-age relationship of the entire sedimentary mass (Figure 2c), the calculated recycling rate will depend on the model adopted for the accumulation history. An upper limit on recycling can be determined by assuming the entire sedimentary mass has been in place for the past 4.5 b.y. Such a model implies a recycling rate of 11.6 x 10 Is g/yr or 4.1 km3/yr of crustal material (VEIZER and JANSEN, 1985). Because the Nd model age of sediments greatly exceeds their stratigraphic age over the post-Archean (Figure 3a), it is clear that much of this recycling is intracrustal in nature. In Figure 3b, the sediment Nd model age data are modeled for a sediment mass which is closed to differing degrees. It is apparent that young mantle-derived material is required to explain the 1.5 Ga average Nd model age of young sediments. The sediment which these new additions replace represents an upper limit on sediment subduction for a sediment mass which is constant or growing (see Figure 3c) through earth history (because most of the earth's degassing occurred earlier in its history, it is unlikely if the sediment mass has diminished through time; GARRELS and MACKENZIE, 1971). From Figure 3b, the sediment mass is at least 80% closed. This provides an upper limit of sediment subduction of 2.3 x 1015 g/yr (0.82 km3/yr of crust). A lower value is imposed for a model of sediment evolution where the sediment mass grows during the Archean and reaches its present mass at about 2.5 Ga, with recycling being the dominant process since then. This explains the Nd model age data best (VEIZER and JANSEN, 1985; Figure 3c). This modeling suggests a recycling rate of 10.8 • 1015 g/yr (VEIZER and JANSEN, 1985) with the system being at least 85% closed, implying an upper limit on sediment subduction of 1.6 x 1015g/yr or 0.57 km3/yr of crust. Vol. 128, 1988 Recycling of the Continental Crust 709 Table 2 Some estimates of recycling of continental crust into the mantle. Mass ( 10~5g) Volume ( km3) 2.5 7.5 1-3 1.22 0.44 7.0 _+Z8 2.5 _+ 1.0 MCLENNAN and TAYLOR, 1983 REYMER and SCHUBERT, 1984 <8.4 1.65 <3,0 0.59 VEIZER and JANSEN, 1985 TAYLOR and McLENNAN, 1985 This paper <-4,1.1 + 0.5 <2.8 <2.1 --<0.4_+0.2 < 1.0 <0.75 Reference ARMSTRONG, 1981 DEWEY and WINDLEY, 1981 DEPAOLO, 1983 Method of estimate Isotope mixing model for steady-state system Sediment accumulation on ocean floor plus tectonic erosion Hf, Nd isotope analysis of mantle derived rocks Sedimentation rates Estimates of sediment subduction, tectonic erosion and K-fixation in oceanic crust Sediment recycling rates Sediment recycling rates Sediment recycling rates and tectonic erosion Mass and Volume conversions assume 2.8 g/cm3 for continental crust for 2.5 g/cm3 for sediment. It s h o u l d b ~ e m p h a s i z e d t h a t these values also represent u p p e r limits on / . s e d i m e n t s u b d t r c n o n for the recycling m o d e l s being considered. It is n o t r e q u i r e d t h a t the lost sediment be r e m o v e d to the mantle, b u t only isolated f r o m the s e d i m e n t a r y mass. Thus, sediment which is stored, for example, in the lower c o n t i n e n t a l crust is included, a n d this region m a y be i m p o r t a n t . M e t a s e d i m e n t a r y lithologies are c o m m o n in lower crustal x e n o l i t h suites from a r o u n d the w o r l d (e.g., D u P u v et al., 1979; PADOVANI a n d CARTER, 1977; LEYRELOUp et al., 1982). Also, if there has been some g r o w t h in the sediment m a s s over the p a s t 2.5 G a , the a m o u n t available for c r u s t - m a n t l e recycling w o u l d also be lower. It can be safely c o n c l u d e d t h a t the present rate o f c r u s t - m a n t l e recycling is n o t well constrained. A lower limit o f negligible mass transfer can be argued. A r e a s o n a b l e u p p e r limit o f sediment s u b d u c t i o n plus a n u p p e r limit on tectonic e r o s i o n w o u l d suggest that no m o r e t h a n 1.0 km3/yr a n d p r o b a b l y significantly less than 0.75 km3/yr o f crustal m a t e r i a l has been recycled into the m a n t l e o v e r the recent past. This is c o m p a r e d with o t h e r estimates in T a b l e 2. 4. Selective R e c y c l i n g It is possible that certain types o f c o n t i n e n t a l crust ( n o t a b l y sediments) m a y be preferentially recycled either i n t r a c r u s t a l l y o r between crust a n d mantle. This has 710 Scott M. McLennan PAGEOPH, been proposed by a number of workers to explain various characteristics of sediment and basement distribution and composition. Several examples of selective recycling will be examined below. 4.1. Selective Recycling of Sediments GARRELS and MACKENZIE (1971) recognized that some sediments were more readily weathered and eroded and concluded that differential recycling rates may affect different sediments. Thus, evaporites are eroded and recycled more rapidly than carbonates which in turn are eroded more rapidly than shales and sandstones. From this observation, GARRELS and MACKENZIE (1971) speculated that a bias may exist in the relative proportions of differing lithologies preserved through time. According to this model, the relative lithological proportions being deposited during the past have always been maintained and the apparent differing proportions of lithologies seen over geological time (e.g., RONOV, 1983) is "a function of differential recycling. VEIZER (1988) has recently argued that erosion of different sediment types cannot be considered in isolation since they are generally interlayered. Consequently, Veizer argues that any differential recyling of sedimentary lithologies is probably related to a preferential association of sediment type with tectonic setting (see below). VEIZER and JANSEN (1985) have further refined this concept of differential recycling of sediments. They examined the area-age relationships of sediments 9 deposited in differing tectonic environments and calculated recycling rates (Table 3). These rates differ by more than a factor of ten with the half life of the different Table 3 Recycling rates for sediments from differing tectonic settings (VEzzER and JANSEN, 1985). Tectonic setting All sediments Abyssal and pelagic Active margin basins (e.g., back-arc basins, Mediterranean) Deep sea fans Passive margin basins Immature orogenic belts Mature orogenic belts (within continents) Platforms Preferred recycling constant ( • 10 l~ Half-life (Ma) 40 + 3 126 235 40 144 15 337 - 223 _+ 51 230 _+ 55 88 _+ 8 85 _+ 35 30 25 80 100 < 1350 540 18.4 _+ 0.5 18.6 _+ 0.5 380 380 Mass (1021 g) 2701 217 Vol. 128, 1988 Recycling of the Continental Crust 711 sediments ranging from 25 m.y. to about 380 m.y. This compares with a half life for the entire sedimentary mass of about 235 m.y. One consequence of this is that if significant amounts of sediment are subducted to the mantle, sediment deposited in certain tectonic environments is likely to be preferentially affected. Thus, the conclusion arrived at above, that it may be inappropriate to consider average sediment in modeling is reinforced. This observation also has important implications for understanding accretionary processes at continental margins and for the study of allochthonous terranes. These will be addressed below. 4.2. Preferential Recycling of Young Continental Crust It has long been recognized that crust formation ages tend to cluster at given times. MOORBATH (1976) recognized five major periods of rock-forming events based mainly on Rb-Sr dating, at 3.8-3.5, 2.8-2.5, 1.9-1.6, 1.2q3.9, 0.5~0.0 Ga. Nd model age data are less abundant but groupings at about 3.8-3.6, 2.7-2.6, 2.3-2.1 (Australia), 2.0-1.7 (North America), 1.5-1.3, 1.1 Ga have so far been recognized (e.g., MCCULLOCH and WASSERBURG, 1978; NELSON and DEPAOLO, 1985; MCCULLOCH, 1986; PATCHETT and ARNDT, 1986). GURNIS and DAVIES (1985, 1986) have examined some of the possible implications of selectively recycling young continental crust, on the area-age distribution of continental basement rocks. This modeling indicated that it is possible to generate apparent peaks in crust formation ages for a continental crust that had a regular growth rate but in which young crust was preferentially recycled (GuRNIS and DAVIES, 1986). These authors assumed that only crust-mantle recycling was involved (in spite of widespread evidence for intracrustal recycling; see Section 2), however, their conclusions seem equally valid if the preferential recycling is intracrustal or a combination of intracrustal and crust-mantle. The suggestion of preferential recycling of young crust would appear to have merit in sedimentary systems. Young crust tends to be elevated in response to young tectonic activity and thus is prone to erosion and recycling. For example, TAYLOR et al. (1983) found that Nd isotopic data indicated that Pleistocene loess deposits preferentially sampled comparatively young orogenic regions. The results from VEIZER and JANSEN (1985; see Table 3) also support the suggestion that sediments in young orogenic belts and active continental margin basins are recycled at a greater rate than those from older tectonic provinces. One implication of preferential intracrustal recycling of young crust is that the average Nd model age of young sediments would tend to give an age younger than the mean age of the upper continental crust (see Figure 3). In addition, it would also allow for the sedimentary system to be considerably more closed (Figures 3b,c) thus further restricting the mass of sediment presently available for crust-mantle recycling (see Section 3.3). 712 Scott M. McLennan PAGEOPH, 4.3. Preferential Recycling o f High Heat Production Crust A number of lines of evidence suggests that the Archean continental crust contained lower concentrations of the heat producing elements (e.g., TAYLOR and MCLENNAN, 1981, 1985; MORGAN, 1984). TAYLOR and MCLENNAN (1985) have interpreted these data as indicating differing compositions for the Archean and post-Archean crusts. MORGAN (1985) has provided an alternative model in which during the Archean, when radioactive heat production was greater, crust with high concentrations of heat producing elements (K, Th, U) was preferentially recycled during orogenic episodes and low heat producing crust survived preferentially. In this model, final stabilization of the crust with high concentrations of K, Th and U did not occur until the Proterozoic. There are two problems with the recycling model of MORGAN (1985). Clastic sedimentation is closely related to orogenic activity (POTTER, 1976; READING, 1982). Most Archean sedimentary rocks are synorogenic in character (e.g., LOWE, 1980, 1982; MCLENNAN, 1984; OJAKANGAS, 1985). It would be expected, accordingly, that these sediments should record in their abundances of K, U and Th the signature of this high heat production crust which is being recycled. In Table 4, the concentrations of K, Th and U are compared for average Archean mudstone (derived mainly from turbidite-shale sequences) and average post-Archean mudstones (TAYLOR and MCLENNAN, 1985). The Archean sediments are depleted by a factor of two in heat producing elements (and other incompatible elements), in conflict with the preferential recycling model. The Nd model age data for sedimentary rocks equally lend no support to this recycling model. Archean sediments have Nd model ages indistinguishable from their stratigraphic ages (Figure 3a), thus greatly restricting the role of recycling. Early Proterozoic sedimentary rocks show some indication of recycling but not on the scale suggested by the preferential recycling model, where model ages well in excess of 2.7-2.8 Ga might be expected. The evidence for preferential recycling of high heat production crust throughout the Archean (MORGAN, 1985) is thus not persuasive and an interpretation of differing bulk compositions of Archean and post-Archean crusts is still favoured. Table 4 Heat producing elements in Archean and post-Archean mudstones. K (%) Th (ppm) U (ppm) Heat production (~W m-3) Archean Post-Archean 1.9 6.3 1.6 1.08 3.1 14,6 3.1 2.22 Data from TAYLORand MCLENNAN(1985). Vol. 128, 1988 Recycling of the Continental Crust 713 5. Recycling, Accretion and Terrane Analysis The fate of sediments that reach subduction zones, either transported on the oceanic crust (pelagic and terrigenous sediments) or derived from the continental margin (terrigenous sediments) is a question of great concern. Major debate centers on the relative role of sediment accretion versus underplating (subcretion) versus subduction (e.g., KARIG and KAY, 1981; MOORE et al., 1982; HILDE, 1983). A common approach (e.g., GILLULY, 1971; FYFE, 1978, 1979) is to consider a simple equation: Sediment reaching subduction zone - Sediment preserved in accretion wedge -- Sediment subducted Such an equation is inadequate without also considering the effects of sedimentary recycling. Once accretionary prisms are exposed to erosion, it is likely that sediment will be removed and recycled either directly back onto the incoming oceanic plate or indirectly via other sedimentary basins. The magnitude of the effects will depend on the recycling rate and the time scale over which the subduction zone has evolved. The speed at which the recycling can occur is remarkably rapid (Table 3). Another, somewhat related, area of recent interest is the concept of terrane analysis (e.g., SCHERMER et al., 1984). It is now recognized that many areas of the continents are comprised of exotic tectonic blocks which have been transported greater or lesser distances; their present tectonic setting may be unrelated to the original setting. In order to understand, in detail, the history of continental growth and development, it is necessary to unravel the history of individual terranes and understand the relationships of one to another. The prime tool in such investigations is detailed stratigraphic study of sedimentary and volcanic rocks which provides evidence of their origin. The present understanding of crustal recycling provides an important caveat to this field of research. Notably, it is to be expected that such terrane analyses become less reliable as older rocks are considered because of the effects of crustal recycling. It can be seen from Table 3 that tectonic environments, particularly those at continental margins, are recycled at vastly different rates. Over time scales of 50-100 million years, the geologic record would be expected to produce a severe bias in the preservation of crustal rocks originating from differing tectonic settings. 6. Recycling on the Early Earth Current views of earth accretion (see review of TAYLOR, 1982) appear to favour the planetesimal model (WETHERILL, 1980) According to this hypothesis, approximately 100 million years after To (4.56 Ga) are required for the accumulation of the 714 Scott M. McLennan PAGEOPH, earth to near its present mass. On the other hand, present data indicate no rocks greater than about 3.8 Ga in age are present on the earth. A major outstanding question is whether continental crust formed during this 800 million year 'gap' and if it did, what happened to it? There is evidence suggestive of the presence of continental crust prior to 3.8 Ga. Initial 143Nd/144Ndratios in early Archean volcanic rocks between 3.6-3.8 Ga from Greenland (HAMILTON et al., 1978, 1983), West Australia (HAMILTON et al., 1981), India (BASU et al., 1981) and South Africa (HAMILTON et al., 1979; CARLSON et al., 1983) indicate derivation form a mantle already depleted in Nd relative to Sin. This depletion could be interpreted to be the result of an earlier extraction of continental crust from the mantle. Some care must be taken with this interpretation. Sm-Nd isochrons for early Archean volcanics almost invariably include both felsic and mafic lithologies in order to obtain a spread in Sm/Nd ratio for precise dates. However, the genetic relationship between such samples often is uncertain and it is possible that the data represent mixing lines of populations with different initial 143Nd/144Nd ratios. Evidence from Kambalda (MCCULLOCHand COMPSTON,1981; CLAOUE-LONG et al., 1984; COMPSTON et al., 1986) indicate that extremely large errors can be generated from such procedures. In spite of this complication, the Nd-isotopic data do suggest the likelihood of depleted mantle (due to crust extraction?) prior to 3.8 Ga but the magnitude of the depletion and its extent are uncertain. More direct evidence for early continental crust comes from U-Pb dating of individual zircon grains (FROUDE et al., 1983). Data from zircons in Archean metaquartzites from Western Australia indicate ages as old as 4.2 Ga. If continental crust were present on the earth prior to 3.8 Ga, there is little doubt that it would have been affected profoundly by recycling processes. The amount of heat produced by K, Th, and U would have been at least three times as great as at present. In addition, considerable heat was probably available from gravitational energy released during accretion. It is not clear if there was an equivalent to the lunar 'magma ocean', which may be unique to the moon, but extensive early melting seems likely (TAYLOR, 1982). In any case, convection on the early earth was almost certainly considerably more vigorous, with resulting increased plate production rates, to accommodate the loss of heat (e.g., BICKLE, 1978). This would have facilitated any recycling associated with such processes (SMITH, 1981, 1982). Perhaps more important to early recycling was the influence of meteorite bombardment. It is now well established that intense meteorite bombardment was endemic within the solar system during its early history and that the earth could not have escaped such activity (TAYLOR, 1982). The cratering record is best documented on the lunar surface where tectonic acitvity has been minimal since accretion and observations may be made comparatively easily. In Figure 12 a model for the lunar cratering record is shown in which a smoothly declining rate is assumed (HARTMANN, 1980). The cratering density on the Earth would have been as much as twice as large as the Moon, due to increased gravitational attraction Vol. 128, 1988 Recycling of the Continental Crust I I I I I 715 I I I 2O Lunar accretion E I j M o d e l (for smooth decline) 0 .+- \ 0 \ c- \ __1 0 ._J LO I 4,0 ~ I Lunor surface record I I I 15.0 2.0 Age (Go) I I 1.0 Figure 12 Plot of lunar cratering rate against time for a model which assumes a smoothly declining rate through time. A similar or even more intense cratering flux would have affected the earth. The greatly increased cratering rate during the period 4.5-3.8 Ga would have had a profound effect on any crust forming on the earth at that time. Adapted from HARTMANN(1980). (SMITH, 1981). The effects of this b o m b a r d m e n t on any terrestrial crust would have been profound, as testified by the lunar highland regolith, and efficient recycling both within the crust and into the mantle are likely. Conservative estimates of the lunar cratering record in the period 4.4-3.8 G a (WILHELMS, 1985) indicate that 80 ringed basins, with diameters > 300 km were formed. In addition, 104 craters with diameters in the range 30-300 km were also formed. Extrapolation of these rates to the early Earth in the same time interval indicate a minimum of 200 ringed basins with diameters > 300 km and > 104 craters in the range 30-300 km diameter. The effect of one such ringed basin (Orientale; 900 km diameter) on the m o o n (TAYLOR and MCLENNAN, 1985; see their Figure 12.7) indicates rather clearly that the preservation of significant amounts of crust formed on the early earth prior to 3.8 G a is not to be expected. There is no clear evidence to indicate the extent of early continental crust, although the limited isotopic data would support at least local continental crust extraction prior to 3.8 Ga. The combination of high heat production and intense meteorite b o m b a r d m e n t during the period 4.56-3.8 G a would certainly have been of importance for recycling into the mantle of any continental crust which may have formed during this period. 716 Scott M. McLennan PAGEOPH, 7. Crustal Recycling and Crustal Growth A final matter is to try to asses the overall effects that crustal recycling has had on the evolution of the continental crust and make a judgement on the overall rate of crustal growth. This writer is of the opinion that much of the divergence in views of crustal growth models has arisen from the failure to clearly distinguish between intracrustal recycling and crust-mantle recycling. Two examples will suffice. The first, stated previously, is the practice of equating to crust-mantle recycling, the difference between long term continental margin sediment accretion and sediment delivery to subduction zones. This however, must represent an upper limit on sediment subduction because of the process of sediment-sediment recycling. In another example, GURNIS and DAVIES (1986) stated that "Crustal growth curves are the same as crustal age distributions only in the absence of crustal recycling into the m a n t l e . . . " . This statement similarly ignores the effects of intracrustal recycling, which can have many of the same effects on crustal age distributions (but with differing effects for different isotope systems, as discussed above) as does crustmantle recycling. Models which have favoured a steady-state system for the continental crust require a present day crust-mantle recycling rate of 1-3 km3/yr (ARMSTRONG,1981; DEPAOLO, 1983). In the modeling of ARMSTRONG (1981), an exponentially increasing rate of recycling with increasing age was required to reproduce the HURLEY and RAND (1969) basement area-age distribution. However, the area-age relation for Nd-model ages differs considerably from the K-Ar distribution (Figure 13), and the quantitative effects on how the recycling rate varies over time are yet to be assessed for the Armstrong model. DEPAOLO (1983) used a somewhat different approach by modeling the difference between measured initial Nd and Hf isotopic compositions of mantle derived rocks of various ages and those expected from their Sm/Nd and Lu/Hf ratios; the difference was attributed to crust-mantle recycling (see PATCHETT and CHAUVEL, 1984 for criticism of this approach). This modeling implied 2.5 ___1.0 km3/yr for crust-mantle recycling which may or may not have increased back through time. In this paper, the upper limit on the present crust-mantle recycling rate was determined to be 1.0 km3/yr, with a favoured rate considerably less than 0.75 km3/ yr. It would appear that the steady-state model is only valid if the lower limit of required recycling and the upper limit of potential recycling are adopted. Accordingly, a growth model seems more plausible, although some recycling can by no means be excluded. Most recent attempts to balance crustal growth and recycling have reached similar conclusions (DEWEY and WINDLEY, 1981; REYMER and SCHUBERT, 1984; HOWELL and MURRAY, 1986). A second factor which must be considered in formulating a crustal growth model is the possibility of preferential recycling of young crust (either intracrustal or crust-mantle) to give apparent peaks in radiometric age distributions (GURNIS Vol. 128, 1988 Recycling of the Continental Crust I I I I I I I 717 I i I r L,oG~e,lI f /~r~,~e,, / I / / Taylor& Mciennan t,~'"~~'' - (m ~deI)//c,~-','~ .\~'~~~'o [,,~ "9" |'/ _ // - T / /Nelson & I /,~ / DePaolo ' h -o.6o ~S - :,:_. o / /Hurley 8~ "[ -~ ,o o I 4.0 :5.0 2.0 Age (Ga) 1.0 Figure 13 Plot of cumulative per cent area against age for K-Ar basement ages (HURLEYand RAND, 1969) and Nd model ages for North America (adapted from NELSON and DEPAOLO, 1985). Also shown is a model for crustal growth adapted from TAYLOR and MCLENNAN (1985). The difference between the K-Ar distribution and Nd model age distribution is almost certainly a function of intracrustal recycling. Assuming the measured Nd model ages are representative of the entire crust, differences between Nd model age distribution and the true crustal growth curve could be due to intracrustal and/or crust-mantle recycling. In either case, the Nd model age distribution, while approaching the true growth curve, will tend to minimize the amounts of old crust. a n d DAVIES, 1985, 1986). This is not c o n s i d e r d to be an a d e q u a t e e x p l a n a t i o n for the a p p a r e n t g r o w t h o f c o n t i n e n t a l crust at the end o f the A r c h e a n because the p e a k in r a d i o m e t r i c ages correlates with o t h e r changes, including greater crustal heat g e n e r a t i o n (MORGAN, 1984), changes in u p p e r crustal c o m p o s i t i o n (e.g., MCLENNAN et al., 1980) a n d changes in S7Sr/S6Sr ratios in seawater (e.g., VEIZER a n d JANSEN, 1979). O n the o t h e r hand, such a process c a n n o t be excluded as an e x p l a n a t i o n for o t h e r p e a k s in isotopic ages, such as those d u r i n g the P r o t e r o z o i c (NELSON a n d DEPAOLO, 1985; MCCULLOCH, 1986), where a d d i t i o n a l evidence for crustal g r o w t h is n o t present. Because the S m - N d isotopic system is least susceptible to resetting, it is clear t h a t the c o n t i n e n t a l a r e a - a g e r e l a t i o n s h i p based on this system w o u l d m o s t closely represent the ' t r u e ' crustal age d i s t r i b u t i o n curve (e.g., MCCULLOCH a n d WASSERBURG, 1978; PATCHETT a n d BRIDGWATER, 1984; NELSON a n d DEPAOLO, 1985; 718 Scott M. McLennan PAGEOPH, MCCULLOCH, 1986; PATCHETTand ARNDT, 1986). An important assumption is that the isotopic data, providing a measure of surface area, are representative of the entire continental crust. In Figure 13, the growth curve derived from the Nd model age data for North America (NELSON and DEPAOLO, 1985) is compared to the K-At curve of HURLEY and RAND (1969). Also shown is a model for crustal growth proposed by TAYLOR and MCLENNAN (1985). The difference between the Nd-model age curve and the K-Ar curve (or Rb-Sr curve) is best ascribed to recycling processes taking place wholly within the crust (see above, VEIZER and JANSEN, 1979, 1985). There is an additional discrepancy between the model of TAYLOR and MCLENNAN (1985) (or that of VEIZER and JANSEN, 1979; ARMSTRONG, 1981; DEWEY and WINDLEY, 1981 and others) and the Nd model age curve. Two factors are considered to be important. First, it has been argued above that intracrustal recycling processes, notably intracrustal melting (causing changes in Sm/Nd) and assimilation, can affect Nd model ages. In addition, some degree of crust-mantle recycling probably takes place. Using the models of VE~ZER and JANSEN (1985), on the order of < 1 kmS/yr of total recycling (intracrustal plus crust-mantle) would be required to explain the discrepancy. Secondly, a time of major crust generation during the period of about 2.3-2.1 Ga (Australia) and 2.0-1.7 Ga (North America) has been emphasized recently (PATCHETT and BRIDGWATER, 1984; NELSON and DEPAOLO, 1985; PATCHETT and ARNDT, 1986; PATCHETT and Kouvo, 1986; MCCULLOCH, 1986. The magnitude of this event has not been satisfactorily determined because the role of the older crust (intracrustal recycling) and the possibility of preferential recycling of young crust (GuRNIS and DAVIES, 1985, 1986) have not been fully assessed. In any case, if the amount of crust generated during this time is < 15-20%, it would be consistent with the crustal growth model of TAYLOR and MCLENNAN (1985). 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