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U n S i v a e r n pub# CSU4 s C a l i f o r Chemical Safety Update i t y o f Environmental Environmental Health Health and and Safety Safety F r a n c i s n i c INCOMPATIBLE MATERIAL Certain combinations of chemicals are explosive, poisonous, or extremely hazardous in some way. Most chemicals are listed on the Material Safety Data Sheet (MSDS) in the following manner: Chemicals which are listed in different chemical classes must NEVER be stored together. The following list is a sample of some of the more hazardous combinations. Do Not Contact: With Any of the Following: Alkali Metals: Calcium [Ca] Potassium [K] Sodium [Na] Carbon Dioxide [CO2] Carbon Tetrachloride [CCl 4] Other Chlorinated Hydrocarbons Water [H2O] Acetic Acid [H3C-COOH] Chromic Acid [CrO3] Ethylene Glycol [HOCH2CH2OH] Nitric Acid [HNO3] [OH]-Containing Compounds Acetone [H3C-CO-CH3] Concentrated Sulfuric Acid [H2SO4] Nitric Acid [HNO3] Acetylene [C2H 2] Copper Tubing [Cu] Mercury [Hg] or its Compounds Silver [Ag] Ammonia-Anhydrous [NH3] Calcium Hypochlorite [Ca(OCl)2] Mercury [Hg] Ammonium Nitrate [NH3NO3] Acids Chlorates [ClO3] Finely Divided Organics Flammable Liquids Metal Powders Nitrates [NO3] Sulfur [S] Other Combustibles Chlorates [ClO3] Ammonia Salts Acids Carbon [C] Finely Divided Organics Metal Powders Sulfur [S] Other Combustibles Chromic Acid [CrCO3] Acetic Acid [H3C-COOH] Alcohols [R-OH] Glycerine [C3H5(OH)3] Naphtahlene [C10H8] Other Flammable Liquids n:\admin\publicat\net\csu4.pm6 Perchloric Acid [HClO4] Peroxides [O2] Permanganates [MnO4] Rev. 8/1/96 a o Do Not Contact: Cyanide [CN] Hydrogen Peroxide [H2O2] With Any of the Following: Acids Aniline [C6H 8-NH2] Chromium [Cr] Copper [Cu] Iron [Fe] Nitromethane [CH3NO2] Hydrogen Sulfide [H2S] Nitric Acid [HNO3] Oxidizing Gases Hydrocarbons Bromic Acid [HBrO3] Sodium Peroxide [Na2O2] Mercury [Hg] Flammable Liquids Most Metals and Their Salts Acetylene [C2H2] Hydrogen Sulfide [H 2S] Flammable Gases and Liquids Substances Readily Nitrated Nitric Acid [HNO3] Acetic Acid [H3C-COOH] Carbon [C] Chromic Acid [CrCO3] Perchloric Acid [HClO4] Acetic Anhydride Alcohols [R-OH] Paper Wood Other Organic Materials Potassium Permanganate [KMnO4] Benzaldehyde [C7H10O] Ethylene Glycol [HOCH2CH2OH] Glycerine [C3H5(OH)3] Sulfuric Acid [H2SO4] Sodium Peroxide [Na2O2] Oxidizable Substances: Carbon Disulfide [CS2] Ethylene Glycol [HOCH2CH2OH] Glacial Acetic Acid [CH3COOH] Glycerine [C3H5(OH)3] Methanol [H3COH] Sulfuric Acid [H2SO4] Chlorates [ClO3] Perchlorates [ClO4] Permanganates [MnO4] Water [H2O] n:\admin\publicat\net\csu4.pm6 Rev. 8/1/96