Download Appendix 3-4 Structures and Generation of Explosives

Safety Instruction for Hazardous Maerials (Appendix 3-4)
Structures and Generation of Explosives
"Safety Guidance for Chemical Experiments 4th Edition" ed. by The Chemical Society
of Japan, Maruzen (1999)
Bond
O-O
Explosive compounds
Chemical structures
High concentrated
hydrogen peroxide
Organic peroxides
H2O2
R-O-O-R'
O
Ozonides
N-O
Generation reaction
Alcohols + H2O2
Halides + H2O2
Aldehydes + H2O2
Ketones + H2O2
Carboxylic acids + H2O2
Ethers + H2O2
Unsaturated hydrocarbon
+ O3
O
O
Nitric acid esters
C
ONO2
Alcohols + HNO3
Carbohydrates + HNO3
Nitrous acid esters
C
ONO
Alcohols + HNO2
Halides + MNO2
Nitro compounds
C
NO2
Amine salts of nitric acid
N
HNO3
Halides + M'NO2
Hydrocarbons, others +
HNO3
Amines + HNO3
Ammonium nitrate
NH4NO3
NH3 + HNO3
Nitramines
C
N NO2
Dehydration of amino nitrates
Amines + HNO3
Nitroso compounds
C
NO
Ketone oximes
O C
R1
C
NOH
Hydroxyamine
derivatives
R2
Fulminates
M' O N C
N
Phenols + HNO2
OH
Metal nitrates + HNO3
+ Alcohls
X-O
Dichlorine Heptoxide
Cl2O7
Amine salts of perchloric
acid
N
Perchloric acid esters
C OClO3
Perchloryl compounds
C
HClO4
ClO3
Alcohols + HClO4
C
H
+ FClO3
Chloric acid
HClO3
M'ClO3 + Acids
Chlorine dioxide
ClO2
M'ClO2 + Acids
Heavy metal salts of
chloric acid
M'ClO3
Ammonium chlorate
NH4ClO3
KClO3 + Heavy metal salts,
Hg, Ag, Pb
Amine salts of chloric
acid
N HClO3
Chloric acid esters
C OClO2
Chlorous acid
HClO2
Hypochlorous acid
HClO
Chlorine monooxide
Cl2O
Salts of hypochlorous acid
C OCl
Amine salts of boromic
acid
N
Amine salts of iodic acid
M'ClO3 + Amine salts
M'ClO
Hypochlorous acid esters
Ammonium bromate
M'ClO3 + NH3 or
Ammonium salts
HBrO3
NH4BrO3
HIO3
N
Ammonium iodate
NH4IO3
Permanganic acid
HMnO4
M'MnO4 + H2SO4
Manganese(VII) oxide
(Dimanganese heptoxide)
Mn2O7
M'MnO4 + H2SO4
Ammonium Permanganate
NH4MnO4
M'MnO4 + Ammonium salts
Amine salts of
permanganic acid
Ammonium dichromate
Amine salts of dichromic
acid
N
HMnO4
(NH4)2Cr2O7
N
2
H2Cr2O7
M'2Cr2O7 + Ammonium salts
N-N
Amine salts of nitrous
acid
Amines + HNO2
N HNO2
Ammonium nitrite
M'NO2 + NH4X
NH4NO2
Nitrosoamines
C
N NO
C
N
+ HNO2
H
C
Diazonium salts
Diazo oxides
+
N
N
Amines + HNO2 + HX
X–
N2
C
C
O
H2N
C
C
OH
+ HNO2 + HX
Hydrazine derivatives
N
Hydrogen azide
HN3
Heavy metal azides
M'N3
N
Metal azides + acids
NaNH3
+
N2O
N2H4
+
NaNO2
+
RONO
NaN3 + Heavy meal salts
Halogen azides
Organic azides
XN3
C N3
NaN3 + Halogen or
hypohalogenous acid salts
Halides + NaN3
Isotetracene derivatives
Nitrogen long chain
compounds
N-M
Nirides
M'3N
Imides
M'2NH
Amides
M'NH2
MX + nNH3
Amine metal complexes
N-X
Nitrogen halides
NX3
X2 or M'XO + NH3
or Ammonium salts
Nitrogen sulfide
N4S4
SCl2 or S2Cl2 + NH3
C-C
Acetylene
HC CH
Heavy metal acetylide
M'C CM'
Acetylene halides
X C C X
CaC2 + H2O
Heavy metal salts + C2H2
Polyacetylenes, acetylene
derivatives etc. and their
halogen or heavy metal
derivatives
Heavy metal salts of
oxalic acid
COOH
COOM'
COOH
CH2
Ethylene oxide
CH2
Compounds with a N-O bond:
Nitric acid esters
COOM'
O
Compounds with a N-N bond:
C ONO2
Nitro compounds
C NO2
Nitramines
C N NO2
Diazo compounds
N
N C
Hydrogen azide
HN3
Metal azides
M'N3
Compounds with an O-O bond:
Organic peroxides
Amine salts of nitric acid
+ Heavy metal salts
N HNO3
Ozonides
O O
O O
O
Nitrous acid esters
C
Nitroso compounds
C NO
Nitrosoamines
C N NO
Amine salts of nitrous acid
N HNO2
ONO
Compounds with an O-halogen bond:
Amine salts and esters of chloric acid:
HClO3, perchloric acid: HClO4, etc.
Others:
Acetylenes and their heavy metal salts
and halogen derivatives
Heavy metal salts of oxalic acid etc.