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Name: ______ANSWER KEY!_________________#: ____ Class: ______ Date: ____________________ Exam #5 Review SHOW ALL WORK ON A SEPARATE PIECE OF PAPER!! Determine the Molar Mass of the following compounds. 1. (NH4)3PO4 N: 3 x 14.01 = 42.03 H: 12 x 1.008 = 12.096 P: 1 x 30.97 = 30.97 ADD ALL THE MASSES TOGETHER! O: 4 x 16.00 = 64.00 149.096 g 2. O2Cl4 O: 2 x 16.00 = 32.00 Cl: 4 x 35.45 = 141.80 ADD ALL THE MASSES TOGETHER! 173.80 g 3. CuClO3 Cu: 1 x 63.55 = 63.55 Cl: 1 x 35.45 = 35.45 O: 3 x 16.00 = 48.00 ADD ALL THE MASSES TOGETHER! 147.00 g 4. Mg(OH)2 Mg: 1 x 24.30 = 24.30 O: 2 x 16.00 = 32.00 H: 2 x 1.008 = 2.016 58.316 g ADD ALL THE MASSES TOGETHER! Determine % composition of the following elements. First, find the total molar mass (g) of the compound. Then use the formula! % comp = total mass of ELEMENT __ x 100 MOLAR MASS OF COMPOUND 5. What % of chlorine is found in O2Cl4? O2Cl4 O: 2 x 16.00 = 32.00 Cl: 4 x 35.45 = 141.80 Total Molar Mass = 173.80 g 141.80 X 100 = 81.59 % 173.80 Divide & multiple by 100 to get a percent! 6. What % of chlorine is found in CuClO3? CuClO3 Cu: 1 x 63.55 = 63.55 Cl: 1 x 35.45 = 35.45 O: 3 x 16.00 = 48.00 35.45 X 100 = 24.12 % 147.00 Divide & multiple by 100 to get a percent! Total Molar Mass = 147.00 g 7. What % of oxygen is found in Mg(OH)2? Mg(OH)2 Mg: 1 x 24.30 = 24.30 O: 2 x 16.00 = 32.00 32.00 X 100 = 54.87 % 58.316 H: 2 x 1.008 = 2.016 Divide & multiple by 100 to get a percent! Total Molar Mass = 58.316 g Solve the following to find the empirical formula. 8. What is the empirical formula for a compound that consists of 74.47% C, 8.75% H and 17.36% N? a. Change percent to mass (assume 100 g) 74.47% C = 74.47 g C 8.75% H = 8.75 g H 17.36% N = 17.36 g N b. Mass to Moles (Divide the masses by their mass on the periodic table! This will equal MOLs) 74.47 g C 1 mol C = 6.20 mol C 12.01 g C 8.75 g H 1 mol H = 8.68 mol H 1.008 g H 17.36 g N 1 mol N = 1.24 mol N 14.01 g N c. Divide by Small (Divide by the smallest mol value) C: 6.2 mol / 1.24 = 5 H: 8.68 mol / 1.24 = 7 N: 1.24 mol / 1.24 = 1 d. Times till whole! Multiply until you get a whole number! (since all are whole numbers, you can skip step 4!) Final Answer/Empirical Formula: C5H7N 9. For these below, just reduce! a. C6H12O6 (Divide by 6) b. N3Br27 (Divide by 3) CH2O NBr9 c. O15F24 (Divide by 3) O5F8 Mole Conversions 10. 1 mol is equal to molar mass. These units are in grams (g). 11. 1 mol is equal to 6.02 x 1023 particles. This number is known as Avogadro’s Number! 12. What are the 3 types of particles? atoms, ions and molecules 13. How many molecules are found in 2.94 moles of CO2? 2.94 mol of CO2 6.02 x 10 23 1 mol CO2 molecules of CO2 CONVERSION FACTORS 1 mol = 6.02 x 10 23 molecules 1 mol = molar mass (g) = 1.77 x 1024 molecules of CO2 14. How many moles are found in 79.2 grams of Fe? 79.2 g of Fe 1 mol Fe = 1.42 mol Fe 55.85 g Fe 15. What is the mass (grams) of 4.16 moles of Ca3(PO4)2? 4.16 mol of Ca3(PO4)2 310.18 g Ca3(PO4)2 Molar Mass of Ca3(PO4)2 Ca: 3 x 40.08 = 120.24 P: 2 x 30.97 = 61.94 O: 8 x 16.00 = 128.00 310.18 g = 1290.35 g Ca3(PO4)2 1 mol Ca3(PO4)2 16. How many moles contain 5.92 x 1024 atoms of P? 5.92 x 1024 atoms of P 1 mol of P Make sure to cancel out your units! = 9.83 mol of P 6.02 x 1023 atoms of P Molar Mass of NaNO3 17. How many molecules are in 74.8 grams of NaNO3? 74.8 g of NaNO3 1 mol of NaNO3 85.00 g NaNO3 6.02 x 1023 molecules of NaNO3 1 mol of NaCl 23 6.02 x 10 molecules of NaCl = 5.30 x 1023 molecules NaNO3 1 mol of NaNO3 18. What is the mass (grams) of 3.71 x 1025 molecules of NaCl? 3.71 x 1025 molecules of NaCl Na: 1 x 22.99 = 22.99 N: 1 x 14.01 = 14.01 O: 3 x 16.00 = 48.00 85.00 g 58.44 g NaCl 1 mol of NaCl Molar Mass of NaCl Na: 1 x 22.99 = 22.99 Cl: 1 x 35.45 = 35.45 58.44 g = 3601.53 g NaCl