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Dougherty Valley HS Chemistry Acid Base Practice Problems I Name: Date: Period: – 1. Consider the reaction HCO3 (aq) + H2O (l) H2CO3 (aq) + OH– (aq) What are the Brønsted-Lowry acids in the reaction? – + 2. Consider the reaction H2SO4 (aq) + NH3 (aq) HSO4 (aq) + NH4 (aq) What are the conjugate acid-base pairs? + 3. Give the conjugate base for each of the following acids: HCN, HNO 2, NH4 , HF, HC2H3O2 – – –2 – 4. Give the conjugate acid for each of the following bases: Br , NH3, ClO , CO3 , NO2 + 5. What is the [H ] for the following solutions? –4 a. 1.25 M HCl, b. beer, pH=4.2, c. 0.250 M H2SO4, d. 5.3 x 10 M NaOH 6. What is the pH of the following solutions? Indicate whether the solution is acidic, basic, or neutral. + –5 –4 a. 0.025 M HNO3, b. coffee, [H ]=1.4 x 10 M, c. pOH=6.19, d. 5.35 x 10 M NaOH 7. If 0.10 M solutions of the following are prepared, which has the lowest pH? HCN, NaOH, HI, NaCl, KF 8. Write the equilibrium expression for the following weak acids: HCN, HNO 2, NH4+, HF, HC2H3O2 – – – – 9. Write the equilibrium expression for the following weak bases: F , NH3, ClO , C2H3O2 , NO2 + 10. Calculate the [H ], the pH, and the percent ionization for a 0.100 M solution of hydrocyanic acid, HCN –10 (Ka=4.9 x 10 ). + 11. Calculate the [H ], the pH, and the percent ionization for a 0.150 M solution of formic acid, HCOOH –4 (Ka=1.7 x 10 ). + 12. Calculate the [H ], the pH, and the percent ionization for a 0.150 M solution of hypochlorous acid, HClO –8 (Ka=3.0 x 10 ). 13. A 0.125 M HNO2 solution is 5.98% ionized at 25°C. What is Ka for HNO2 at this temperature? 14. A 0.250 M ascorbic acid solution is 1.79% ionized at 25°C. What is Ka for ascorbic acid at this temperature? -- 15. If the pH=2.5 for a 0.25 M solution of a weak acid, what is Ka for the acid? General Formula: HA A + H 16. If the pH=5.35 for a 0.15 M solution of a weak acid, what is K a for the acid? –4 17. Calculate the pH of a 0.50 M HNO2 (Ka=4.5 x 10 ) solution. –5 18. Calculate the pH of a 0.25 M NH3 (Kb=1.8 x 10 ) solution. –4 19. Calculate Kb for the conjugate base of nitrous acid, HNO2 (Ka=4.5 x 10 ). –5 20. Calculate Ka for the conjugate acid of ammonia, NH3 (Kb=1.8 x 10 ). 21. Would the following salt solutions be acidic, basic, or neutral? NaCN, AlCl 3, NH4Cl, LiF, KNO3, FeCl3, NaNO2, Ca(C2H3O2)2, Ba(ClO4)2, Li2CO3 3– 2+ 2– 22. Indicate the Lewis acid and Lewis base in each of the following: [Fe(CN) 6] , [Ni(NH3)6] , CdBr4 , + + + + NH3 + H NH4 , H2O + H H3O +