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Photonic Band Gap Materials: The “Semiconductors” of the future? C. M. Soukoulis Ames Lab. and Physics Dept. Iowa State University. and Research Center of Crete, FORTH - Heraklion, Crete Collaborators Ames Laboratory, Iowa State University – Mike Sigalas (Agilent) – Gary Tuttle, W. Leung – Ekmel Ozbay (Turkey) – Rana Biswas – Mario Agio (Pavia), P. Markos (Slovakia) – E. Lidorikis (MIT), S. Foteinopoulou – C.T. Chan (Hong-Kong) – K.M. Ho Research Center of Crete – E. N. Economou – G. Kiriakidis, N. Katsarakis, M. Kafesaki – PCIC Computational Methods Plane wave expansion method (PWE) C.T. Chan, K.M. Ho, E. Lidorikis, S. Foteinopoulou Transfer matrix method (TMM) M. Sigalas, I. El-Kady, P. Markos, S. Foteinopoulou Finite-difference-time-domain-method (FDTD) M. Agio, M. Kafesaki, E. Lidorikis, S. Foteinopoulou [email protected] [email protected] http://cmpweb.ameslab.gov/personnel/soukoulis PHOTONIC BAND GAP STRUCTURES: THE “SEMICONDUCTORS” OF THE FUTURE? Semiconductors PBG Crystals Periodic crystal potential Periodic variation of dielectric constant Atomic length scales Length scale ~ Crystal structure given by nature Man-made structures Control electron flow Control e.m. wave propagation 1950’s electronic revolution 1990’s optical fibers, lasers, PBGs --> photonics era Fermi’s Golden Rule: hv 1 / 2 | V | (E ) 2 Density of final states Applications: Microwaves Dielectric Photonic Crystal Efficient planar antennas Applications: Optical range Suppression of spontaneous emission Low-threshold lasers, single-mode LEDs, mirrors, optical filters visible Infra-red mm wave APPLICATIONS OF PBG MATERIALS: Frequency-selective, loss-less reflection Filters, switches, optical amplifiers Areas impacted: Automotive electronics - e.g., collision-avoidance radar (60-77 GHz) Electron cyclotron resonance heating for fusion plasma, diagnostic tool (60-200 GHz) Medical and biological application - e.g., microwave resonance therapy (40-80 GHz), imaging Wide bandwidth communication (60, 94 GHz) mm waveguides Fast electronics - interchip communication Remote sensing - e.g., monitoring atmospheric radiation; observational astronomy Lasers and optical devices - improved performance in efficiency and reduction of background noise Photocatalysis Outline Progress in fabricating 3D photonic crystals Layer-by-Layer structure (ISU) 3-cylinder structure (LIGA) Inverse opals and ordered silica matrices (many groups) Metallic photonic crystals Metallic and dielectric bends Photonic Crystal Waveguides and Bends (2D slabs or 3D PCs) Studies of the losses and effects of disorder Progress in 3d Photonic crystal frequency 10 Frequency (GHz) 10 10 7 Inverse structures 6 Kyoto 5 Kyoto 10 10 10 10 10 ultarviolet visible light fiber optics Sandia C O laser Sandia 2 4 infrared Liga 3 Germany mm waves Ames atmosphere windows 60 and 95 GHz Ames 2 1 Bellcore Ames Wireless Communications 0 1990 1992 1994 1996 1998 2000 2002 Three - cylinder Structure or Yablonovite E. Yablonovitch Diamond like symmetry. PRL 65, 3152 (1990) and Euro. Phys. Lett. 16, 563 (1991) 3-cylinder structure E. Yablonovitch et. al. PRL 67, 3380 (1991) Fabrication of 3-cylinder structure by LIGA technique ISU, FORTH and Mainz Appl. Phys. Lett. 71, 1441 (1997) experiment v=2.4 THz Appl. Phys. Lett. 71, 1441 (1997) Diamond lattice gives the largest photonic band gap Ho, Chan and Soukoulis, PRL 65, 3152 (1990) Diamond lattice Ho, Chan and Soukoulis, PRL 65, 3152 (1990) Photonic band gap formation A synergetic interplay between microscopic (Mie) and macroscopic (Bragg) resonances. d eo r ei Bragg scattering: 2d = m w /c = m / d, m=1,2,… Mie resonance: 2r/i = (m+1)/2, m=0,1,2,… i 2c / w ei w / c / 2r e i Maximum reflection (m=0): Gap appears when: / d / 2r ei 2r / d 1/ ei (filling ratio) Experimental band structure of a fcc lattice of air spheres Gap Fcc Airball(86%) n=3.5 Yablonovitch & Gmitter, PRL 63, 1950 (1989) FCC lattice has only a pseudogap Ho, Chan and Soukoulis, PRL 65, 3152 (1990) Density of States for a fcc structure of air spheres figure Ho, Chan and Soukoulis, PRL 65, 3152 (1990) Sozuer, Haus and Inguva, PRB 45, 13962 (1992) √ Busch and John, PRE 58, 3896 (1998) Band structure for a close-packed fcc lattice of air spheres in silicon Busch and John, PRE 58, 3896 (1998) DOS for a close-packed fcc lattice of air spheres in silicon Busch and John, PRE 58, 3896 (1998) Air Spheres (e=1) in Dielectric (e=10) fcc arrangement with Air filling ratio ~ 74% supercell: 333, k-point sampling: 888, total grids: 727272 Disorder In Position <rms>: Average rms error in the dielectric constant Dd: D(D/R) at half peak d0: D/R at peak value DOS <rms> Dd/d0 0.30 0.015 0.85 0.040 1.60 0.085 2.40 0.135 0 Lidorikis, Soukoulis 0.1 0.2 0.3 wa/2c 0.4 0.5 Air Spheres (e=1) in Dielectric (e=10) fcc arrangement with Air filling ratio ~ 74% supercell: 333, k-point sampling: 888, total grids: 727272 Disorder In Radius <rms>: Average rms error in dielectric const. Dv: D(V/V0) DOS <rms> Dv 0.34 0.1 0.67 0.2 1.00 0.3 1.30 0.4 Lidorikis, Soukoulis 0 0.1 0.2 0.3 wa/2c 0.4 0.5 Carbon structures with 3d periodicity at optical wavelengths A. Zakhidov et. al. Science, 282, 897(1998) On-chip natural asembly of silicon photonic bandgap structures Y. A. Vlasov et. al. Nature, 414, 289 (2001) Inversed opals infiltrated by liquid crystals K. Busch and S. John, PRL 83, 967 (1999) Silicon inverted opals A. Blanco et. al. Nature 405, 437 (2002) Fabrication of photonic crystals by holographic lithography M.Campell et. al. Nature, 404, 53 (2000) An easy-to-build structure with a full photonic band gap Iowa State layer-by-layer structure: Science News 144, 199 (1993); Solid State Comm. 89, 413 (1994) Phys. Rev. B 50, 1945 (1994) Iowa State University’s layer-by-layer structure Diameter of Rods ? Spacing of Rods Midgap Frequency Corresponding Wavelenth at Midgap 0.32 cm 1.120 cm 13 GHz 23 mm 0.20 cm 0.711 cm 20 GHz 15 mm √ 0.08 cm 0.284 cm 50 GHz 6 mm √ 340 micron 1275 micron 100 GHz 3 mm √ 100 micron 350 micron 450 GHz 0.66 mm √ 1.33 micron 4.74 30 THz 10 micron 0.20 micron 0.711 2 x 1014 Hz 1.5 micron !!! 667 Å 2370 Å 6 x 1014 Hz 5000 Å √ !! ?? Science News 144, 199 (1993); Solid State Comm. 89, 413 (1994) Phys. Rev. B 50, 1945 (1994) Iowa State University’s layer-by-layer structure Iowa State University Ames Laboratory Sandia National Laboratory. Electro magnetic waves are incident on the side surface 5 0 Transmission (dB) -5 -10 -15 -20 -25 -30 -35 -40 -45 10 11 12 13 Frequency (GHz) 14 15 Theory and experiment is in excellent agreement Frequency (GHz) 20 15 10 5 0 K L K X' An average attenuation of 16 dB per unit cell is obtained 0 0 -20 -20 -40 -40 Experim ent -60 -60 Noise level -80 -80 Theory -100 0 1 2 3 4 Number of unit cells 5 -100 Transmission (dB) Theoretical (dashed line) and experimental (solid line) transmission characteristics of the defect structure 0 -10 -20 -30 -40 -50 -60 10 12 14 16 Frequency (GHz) 18 The ISU layer by layer structure fabricated at Kyoto Univ. S. Noda et. al. Science, 289, 604 (2000) S. Noda et. al. Science, 289, 604 (2000) S. Y. Lin et. al. Nature, 394, 251 (1998) R. Biswas, ISU Propagation along 90 bends in 3d dielectric structures S. Noda, Kyoto Univ. M. Sigalas et. al. Microwave Opt. Techn. Lett. 23, 56 (1999) Metallic Structure Metallic Structure y x Propagation along 90 bends in 3d metallic structures Transmission along the bend is more than 95% !! M. Sigalas et. al. Phys. Rev. B 60, 4426 (1999) Agio and Soukoulis, PRE, 64, 055603R (2001) Waveguide modes for widths of W1 and W3 Regural waveguides cannot bend light for sharp angles Sharp bends in photonic Crystals !!! Guided bends in Photonic Crystals: - Study of 60o bends in W3 and W5 --Best the smoothest one in collaboration with PCIC groups W3 taper+slit double bends Field profile for a/0.24 Modal analysis for slit2 Studies of the out of plane losses Photonic Crystal Slabs Kafesaki, Agio, Soukoulis, JOSA B (2002) Comparison of 2D and 3D results 3D 2D 3D results can be derived by an effective 2D system with a slightly different f and an imaginary e 2D and 3D gaps almost coincide in position and width. Y-Splitters Summary and Conclusions The layer-by-layer structure has been fabricated at telecom frequencies Inverse closed packed structures with high index materials (TiO2, Si, Ge) Doping of PBGs with active atoms and molecules will lead to new frontiers in microlasers, low threshold switches, random lasers Metallic PBGs. Connectivity is very important Photonic Crystal Waveguides and Bends (3d structures or dielectric slabs) Tunable PBGs Detailed studies of disorder are very important Summary: The “photon band structure” problem is solved Photonic gaps EXIST in diamond like structures Structure is optimized to give largest gap Localization of light in imminent Experimental Challenge Fabricate these new dielectric structures at optical wavelengths, then Applications of photonic gaps in physics and engineering may become possible.