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Igneous Mineral Associations How we know the mineralogy of the mantle: • Seismic wave velocities indicate rocks are either peridotite or eclogite • Natural samples of the mantle: xenoliths in lava, rocks from tectonically disrupted lithosphere (ophiolites) are mostly peridotite • Mantle rocks must melt to form basaltic magma 3 types of primary basaltic magma • • • At divergent plate margins (mid ocean ridges) – magma rises from asthenosphere decompression melting at low pressure - tholeiitic basaltic magma At hot spot (intra-plate volcanoes) – magma rises from deep mantle - decompression melting at high pressure - alkalic basaltic magma At convergent plate margins (volcanic arcs) – water added to the mantle from the subducted lithosphere causes melting - flux melting - calc-alkaline or high alumina basaltic magma Mineral association 1) Peridotite contains olivine + clinopyroxene + orthopyroxene and it melts partially to form basaltic magma Lherzolite – harzburgite – dunite sequence is formed by magma extraction. Dunite is >90% olivine. Phase diagram for Lherzolite Si [4] => Si [6] After Wyllie, P. J. (1981). Geol. Rundsch. 70, 128-153. Intrusive and extrusive igneous rocks Intrusive (plutonic) igneous rocks form from magma that cools beneath the earth’s surface Extrusive (volcanic) igneous rocks form from magma that cools at the earth’s surface: Lava Pyroclastics Fine grained Volcanic or extrusive rocks Coarse grained Plutonic or intrusive rocks TEXTURE COMPOSITION Mafic rocks: Basalt and gabbro – contain mafic minerals Felsic rocks: Rhyolite and granite – contain feldspar and quartz The common igneous rocks are classified on the basis of: SiO2 and the percentage of mafic minerals, in addition to texture. Most magma entering the Earth’s crust from the mantle is basaltic (about 50% SiO2, high Mg, Fe, Ca, low Na, K) How does intermediate and felsic magma form? Why are there different types of magma ? Experiments on molten rocks showed that there was a sequence in which minerals crystallized from basaltic magma as the magma cooled Minerals such as plagioclase feldspar and olivine also change composition as the magma cools Albite = NaAlSi3O8 Anorthite = CaAl2Si2O8 Magmatic differentiation by fractional crystallization The liquid part of magma changes composition because minerals with high crystallization temperatures settle out or accumulate at magma chamber boundaries. The elements in these solid minerals are removed from the magma, so that it changes composition, usually toward higher SiO2, lower Mg, Fe and Ca, higher Na, K. Other magmatic differentiation processes: -assimilation of crustal rocks – plenty of geochemical evidence for this -magma mixing Magmatic differentiation Dissolved gases also exsolve as the magma solidifies. Elements that are not accommodated in the common rock forming minerals are also concentrated in the last remaining liquid/gas-charged magma. These late-stage magmas form pegmatites. Pegmatites Layered Mafic Intrusions Some Igneous Mineral Associations: 1) Peridotites (mantle rocks) 2) Layered mafic intrusions 3) Pegmatites 4) Kimberlites http://www.mineralsed.ca/i/video/kimberlite-anim.swf 5) Carbonatites Also – the common igneous rocks