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Dr Ali Jawarneh Department of Mechanical Engineering Hashemite University 1 Objectives • Introduce the concept of energy and define its various forms. • Discuss the nature of internal energy. gy • Discuss the three mechanisms of heat transfer: conduction, convection, and radiation. • Define the concept of work, including electrical work and several forms of mechanical work. • Introduce the first law of thermodynamics, energy balances, and mechanisms of energy transfer to or from a system system. • Define energy conversion efficiencies. • Discuss the implications of energy conversion on the environment. 2 3 2–1 INTRODUCTION • The conservation of energy principle, principle or Energy cannot be created or destroyed during a process; it can only change from one form to another. - The only energy interaction involved is the electrical energy crossing the system boundary and entering the room. The conservation of energy gy requires q the energy gy content of the room to increase by an amount equal to the amount of the electrical energy drawn by the refrigerator refrigerator.The The refrigerator or its motor does not store this energy Therefore, this energy must now be in the room air, and it will manifest itself as a rise in the air temperature. 4 2–2 FORMS OF ENERGY • Energy can exist in numerous forms such as thermal, mechanical, kinetic, potential, electric, magnetic, chemical, and nuclear, and their sum constitutes the total energy E of a system. • The total energy of a system on a unit mass basis is denoted by e and is expressed as E e= (kJ/kg) m (2-1) 5 • The total energy has two forms : (1) The Th macroscopic i forms f off energy are those th a system possesses as a whole with respect to some outside reference frame frame, such as kinetic and potential energies. (2) The microscopic forms of energy are those related to the molecular structure of a system and the degree of the molecular activity, and they are independent of outside reference frames. The sum of all the microscopic forms of energy is called the i t internal l energy off a system t andd is i denoted d t d by b U. U 6 • The macroscopic energy of a system is related to motion and the influence of some external effects such as gravity, magnetism, electricity, and surface tension. - The energy that a system possesses as a result of its motion relative to some reference frame is called kinetic energy ((KE). ) When all p parts of a system y move with the same velocity, the kinetic energy is expressed as: V2 KE = m (kJ) 2 (2 2) (2-2) or, on a unit mass basis, V2 ke = (kJ/kg) 2 (2-3) 7 - The energy that a system possesses as a result of its elevation in a gravitational field is called potential energy (PE) PE = m g z (kJ) (2-4) or, on a unit i mass basis, b i pe = g z (kJ/kg) (2-5) - In the absence of the magnetic magnetic, electric, electric and surface tension effects the total energy of a system consists of the kinetic,, potential, p , and internal energies g and is expressed as: V2 + mgz (kJ) (2-6) E = U + KE + PE = U + m or, on a unit mass basis, 2 V2 e = u + ke + pe = u + + gz (kJ/kg) 2 (2-7) 8 • Stationar Stationary ssystem stem is i a system t whose h velocity l it andd elevation of the center of gravity remain constant during a process process. The change in the total energy E of a stationary system is identical to the change in its internal energy U. ΔKE = 0 ΔPE = 0 ΔEsystem = ΔU y 9 Control volumes: • - Volume flow rate V which is the volume of a fluid flowing through a cross section per unit time. • V = Ac Vavg (m3 /s) • - Mass flow rate m : the amount of mass flowing through a cross section per unit time. • m = ρ Ac Vavg (kg/s) (2-8) Ac :cross sectional area of flow Vavg: is the average flow velocity normal to Ac The energy flow rate associated with a fluid • • E=me or (kJ/s or kW) (2-9) E=me 10 Some Physical Insight to Internal Energy 11 • Internal energy may be viewed as the sum of the kinetic and p potential energies g of the molecules. • The kinetic energy of the molecules is called sensible heat. • The internal energy is also associated with various binding forces between the molecules of a substance, between the atoms within a molecule, and between the particles within an atom and its nucleus. nucleus • An atom consists of neutrons and positively charged protons bound together g by y very y strong g nuclear forces in the nucleus,, and negatively charged electrons orbiting around it. • The internal energy associated with the phase of a system is called ll d latent l t t heat. h t • The internal energy associated with the atomic bonds in a molecule is called chemical ((or bond)) energy. gy • The internal energy associated with the bonds within the 12 nucleus of the atom itself is called nuclear energy. The forms of energy (total energy) of a system, can be contained or stored in a system, and thus can be viewed as the static forms of energy. The forms of energy not stored in a system can be viewed as the dynamic forms of energy or as energy interactions interactions. The dynamic forms of energy are recognized at the system boundary as they cross it, and they represent the energy gained or lost by a system during a process. The only two forms of energy interactions associated with a closed system are heat transfer and work work. A control volume can exchange energy via mass transfer, heat transfer and work. we frequently refer to the sensible and latent forms of internal energy as heat, and we talk about heat content of bodies In thermodynamics bodies. thermodynamics, however however, we usually refer to those forms of energy as thermal energy to prevent any 13 confusion with heat transfer. Distinction between the macroscopic kinetic energy of an object as a whole and the microscopic kinetic energies of its molecules that constitute the sensible internal energy gy of the object. j The kinetic energy of an object is an organized form of energy associated with the orderly motion of all molecules i one direction in di i in i a straight i h pathh or around an axis. In contrast, the kinetic energies of the molecules are completely random and highly disorganized. 14 The major application area of thermodynamics is the conversion of disorganized energy (heat) into organized energy (work). The organized energy can be converted to disorganized energy completely, but only a fraction of disorganized energy can be converted to organized energy by specially built devices called heat engines (like car engines and power plants). l t) A similar argument can be given for the macroscopic potential energy of an object as a whole and the microscopic p p potential energies g of the molecules. 15 Mechanical Energy • The h mechanical h i l energy can be b defined d fi d as the h form f off energy that can be converted to mechanical work completely and directly by an ideal mechanical device such as an ideal turbine. P V2 emech = + + gz ρ 2 (2 10) (2-10) P/ρ :the flow energy, gy V2/2 :the kinetic energy, and gz :the potential energy of the fluid • • • P V2 Emech = m emech = m( + + gz) ρ 2 (2-11) 16 • The mechanical energy change of a fluid during incompressible ( ρ = constant) flow becomes P2 − P1 V22 − V12 Δemech = + + g(z 2 − z1 ) (kJ / kg) ρ 2 (2-12) P2 − P1 V22 − V12 Δ Emech = m Δemech = m( + + g(z 2 − z1 )) (kW) ((2-13)) ρ 2 • • • • In the absence of any losses losses, the mechanical energy change represents the mechanical work supplied to the fluid (if Δemech ec > 0 ) or extracted from the fluid (if Δemech < 0 ). 17 o E system= E microscopic{molecules}+ E macroscopic{object as a whole} o E microscopic{molecules}= U = Internal Energy = [sensible(KE)+PE+latent(phase)+chemical+nuclear ibl ( ) l ( h ) h i l l ] gy ((heat)= ) sensible ((KE)+latent(phase) ) (p ) oThermal energy In general, internal energy consists of sensible, latent, chemical, and nuclear energies. However, in the absence of any chemical or nuclear reactions, the chemical and nuclear energies can be disregarded and the internal energy can be considered to consist of only sensible and latent energies that can be transferred to or from a system as heat whenever there is a temperature difference across the system boundary. o E macroscopic{object p { j as a whole}}= [KE+PE+electrical+magnetic+surface tenstion] P/ρ :the flow energy, o Mechanical Energy: 2 • • • P V2 Emech = m emech = m( + + gz) ρ 2 V /2 :the th kinetic ki ti energy, andd gz :the potential energy of the fluid 18 EXAMPLE: Consider a river flowing toward a l k att an average velocity lake l it off 3 m/s / att a rate t off 500 m3/s at a location 90 m above the lake surface. f D Determine t i the th total t t l mechanical h i l energy of the river water per unit mass and the power generation ti potential t ti l off the th entire ti river i att that th t location 19 SOLUTION: 20 2–3 ENERGY TRANSFER BY HEAT • Energy can cross the boundary of a closed system in two distinct forms: heat and work • Heat H t is i defined d fi d as the th form f off energy that is transferred between two systems ( a system (or t andd its it surroundings) di ) by b virtue of a temperature difference • Heat is energy energ in transition. It is recognized i d only l as it crosses the boundary of a system. 21 • A process during which there is no heat transfer is called an adiabatic process. process • There are two ways a process can be adiabatic: Either the system is well insulated so that only a negligible amount of heat can pass through the boundary, or both the system and the surroundings are at the same temperature and therefore there is no driving force (temperature difference) for heat transfer. 22 • heat transfer Q, kJ (1 Btu=1.0551 kJ) • Heat H t transfer t f per unit it mass Q q= m (kJ / kg) (2-14) • • Heat transfer rate Q , kJ/s or kW • • When Q varies with time, the amount of heat transfer d i a process is during i t2 • Q = ∫ Q dt • (kJ) (2 15) (2-15) t1 • When Q remains constant during a process, this • relation l i reduces d to Q = Q Δt (kJ) (2-16) 23 Heat is transferred by three mechanisms: 1- Conduction is the transfer of energy from the more energetic particles of a substance to the adjacent less energetic ones as a result of interaction between particles. 2- Convection is the transfer of energy between a solid surface and the adjacent fluid that is in motion, and involves the combined effects of conduction and fluid motion. i 3- Radiation is the transfer of energy due to the emission of electromagnetic waves (or photons). photons) 24 2–4 ENERGY TRANSFER BY WORK • Work (W), kJ: is i the h energy transfer f associated i d with iha force acting through a distance. • The work done per unit mass of a system is denoted by w and is expressed as: W (kJ / kg) (2-17) w= m • The work• done per unit time is called power and is denoted W kJ/s, or kW. 25 • Heat and work are directional quantities, and thus the complete description of a heat or work interaction requires the specification of both the magnitude and direction. • One way of doing that is to adopt a sign convention. heat transfer to a system and work done by a system are positive iti • Another way is to use the subscripts in and out to indicate direction 26 Heat and work are energy transfer mechanisms between a system and its surroundings, surroundings and there are many similarities between them: 1 Both are recognized at the boundaries of a system as 1. they cross the boundaries. That is, both heat and work are boundaryy pphenomena. 2. Systems possess energy, but not heat or work. 3. Both are associated with a pprocess,, not a state. Unlike properties, heat or work has no meaning at a state. g depend p 4. Both are ppath functions ((i.e.,, their magnitudes on the path followed during a process as well as the end states). 27 • Path functions have inexact differentials designated by the symbol δ . Therefore Therefore, a differential amount of heat or work is represented by δ Q or δ W, respectively, instead of dQ or dW. Simply, W & Q are not properties and systems do not possess W or Q at a state. • Properties are point functions (i.e., they depend on the state t t only, l andd nott on how h a system t reaches h that th t state), t t ) and they have exact differentials designated by the symbol y d. • Example 2 ∫ dV = V -V 2 1 = ΔV 1 2 ∫ δW = W 12 (not ΔW) 1 28 Electrical Work • Electrons l can cross the h system boundary b d to do d electrical l i l work on the system. In an electric field, electrons in a wire move under the effect of electromotive forces, forces doing work. • (2-18) • Electrical p power: We = V I ( W) • In general, both V and I vary with time, and the electrical work (We ) done during a time interval Δ t is expressed as 2 We = ∫ V I dt (kJ) (2-19) 1 • When both V and I remain constant We = V I Δt (kJ) (2-20) (2 20) 29 2–5 MECHANICAL FORMS OF WORK ( ) • Constant force f F W = F s (kJ) (2-21) • The force F is not constant, 2 W = ∫ F ds (kJ) 1 (2-22) Shaft Work Torque q T: T= F r Shaft work: Wsh = 2π n T (kJ) (2-25) n:: revolutions evo ut o s • • Shaft power: Wsh = 2π n T (kW) (2-26) • per unit time. n : the number of revolutions p 30 Spring Work • When h the h length l h off the h spring i changes h by b a differential diff i l amount dx under the influence of a force F, the work done is (2-27) δWspring = F dx • For linear elastic springs, the displacement x is proportional p p to the force applied pp F =kx (2-28) 1 Wspring = k (x22 − x12 ) 2 (KJ) (2-29) • x1 and x2 are the initial and the final displacements of the spring, spring 31 Work Done on Elastic Solid Bars • Solids lid are often f modeled d l d as linear li springs i because b under d the action of a force they contract or elongate, and when the force is lifted, lifted they return to their original lengths, lengths like a spring. This is true as long as the force is in the elastic range, that is, not large enough to cause permanent (plastic) deformations. • normal stress σn = F/A • Work associated with the • expansion or contraction of an elastic solid bar 2 2 1 1 Welastic = ∫ F dx = ∫ σn Adx (KJ) (2-30) A: is the cross-sectional area of the bar. 32 Work Associated with the Stretching of a Liquid Film • surface tension σs (N/m): ( / ) The h pulling lli effect ff on the h liquid li id molecules at an interface caused by the attractive forces of molecules per unit length. length • The force is used to overcome the microscopic forces between molecules at the liquid–air q interfaces is: F = 2b σs • Therefore, the work associated with the stretching of a film is called surface tension work. 2 Wsurface = ∫ σs dA (kJ) (2-31) 1 where dA = 2b dx 33 EXAMPLE: Determine the work required to deflect a linear spring with a spring constant of 70 kN/m by 20 cm from its rest position. ANSWER: 34 EXAMPLE: The engine of a 1500-kg automobile has a power rating of 75 kW. kW Determine the time required to accelerate this car from rest to a speed of 100 km/h at full power on a level road. Is your answer realistic? ANSWER: 35 2–6 THE FIRST LAW OF THERMODYNAMICS • The Th first fi law l off thermodynamics, h d i also l known k as the h conservation of energy principle. • The first law of thermodynamics states that energy can be neither created nor destroyed during a process; it can onlyy change g forms. 36 37 Energy Balance (Total energy entering the system) - (Total energy leaving the system) = (Change in the total energy of the system) Ein − Eout = ΔEsystem ΔEsystem Energy gy Change g of a System, y y Energy change = Energy at final state - Energy at initial state ΔEsystem = Efinal − Einitial = E2 − E1 (2-32) 38 • In the absence of electric, magnetic, and surface tension effects (i.e., (i e for simple compressible systems), systems) the change in the total energy of a system during a process is: ΔE = ΔU + ΔKE + ΔPE (2-33) (2 33) ΔU = m(u2 − u1 ) 1 ΔKE = m(V22 − V12 ) 2 ΔPE = mg(z 2 − z1 ) u1 and u2 : Specific internal energies can be determined directly from the property tables or thermodynamic property relations. • for stationary systems 39 Mechanisms of Energy Transfer, E in and E out • Energy can be b transferred f d to or ffrom a system in i three h forms heat, work, and mass flow. Energy interactions are recognized at the system boundary as they cross it it, and they represent the energy gained or lost by a system during a process. • The only two forms of energy interactions associated with a fixed mass or closed system are heat transfer and work. (1) Heat Transfer, f Q. Q Heat transfer f to a system ((heat gain) i ) increases the energy of the molecules and thus the internal energy of the system, system and heat transfer from a system (heat loss) decreases it since the energy transferred out as heat comes from the energy of the molecules of the system. 40 (2) Work Transfer, W. A rising piston, a rotating shaft, and an electrical wire crossing the system boundaries are all associated with work interactions. - Work transfer to a system y ((i.e.,, work done on a system y ) increases the energy of the system, and work transfer from a system (i.e., work done by the system) decreases it since i the th energy transferred t f d outt as workk comes from f the th energy contained in the system. - Car engines and hydraulic, hydraulic steam, steam or gas turbines produce work while compressors, pumps, and mixers consume work. 41 (3) Mass Flow, m. When mass enters a system, system the energy of the system increases because mass carries energy with it (in fact, mass is energy). gy) Likewise,, when some mass leaves the system, the energy contained within the system decreases because the leaving mass takes out some energy with it. 42 • The energy balance can be written more explicitly as Ein − Eout = (Qin − Qout ) + ( Win − Wout ) + (Emass,in − Emass,out ) = ΔEsystem (2-34) • Energy balance for any system undergoing any kind of process can be expressed more compactly as (2-35) (2 35) Eini − Eout = ΔEsystem (kJ) Net energy transfer Change in internal, kinetic, by heat, work, and mass potential etc.. energies or, in i the th rate t fform, as • • Ein − Eout = dEsystem / dt Rate of net energy transfer by heat, work, and mass (kW) (2-36) Rate of change in internal, kinetic, potential etc.. energies g 43 • For constant rates, the total quantities during a time interval Δt are related to the quantities per unit time as • • Q = Q Δt, W = W Δt, and ΔE = (dE / dt) Δt (kJ) (2-37) • The energy balance (Eq (Eq.2-35) 2 35) can be expressed on a per unit mass basis as ein − eout = Δesystem (kJ / kg) (2 38) (2-38) • For a closed system undergoing a cycle, the initial and final states are identical: ΔEsystem = E2 − E1 = 0 Eini − Eoutt = 0 or Eini = Eoutt • • Wnet,out = Qnet,in or Wnet,out = Qnet,in (2 40) (2-40) 44 EXAMPLE: Water is being heated in a closed pan on top of a range while being stirred by a paddle wheel. wheel During the process, 30 kJ of heat is transferred to the water,, and 5 kJ of heat is lost to the surroundingg air. The paddle-wheel work amounts to 500 N · m. Determine the final energy of the system if its initial energy is 10 kJ. SOLUTION: Ein − Eout = ΔEsystem (kJ) Qin + Wsh, in − Qout = ΔU = U2 − U1 30kJ + 0.5 kJ − 5 kJ = U2 − 10kJ U2 = 35.5 kJ 45 EXAMPLE: The driving force for fluid flow is the pressure difference, difference and a pump operates by raising the pressure of a fluid (by converting the mechanical shaft work to flow energy). gy) A gasoline g pump is measured to consume 5.2 kW of electric power when operating. If the pressure differential between the outlet and inlet of the pump is measured to be 5 kPa and the changes in velocity and elevation are negligible, negligible determine the maximum possible volume flow rate of gasoline. 46 • Solution: • 0.0 ((steady) y) • • • • P V2 Emech = m emech = m( + + gz) ρ 2 • • Ein = Eout Ein − Eout = dEsystem / dt • • • • • Win + m(Pv)1 = m(Pv)2 ⇒ Win = m(P2 − P1 )v = V ΔP • • Win 5.2 V= = = 1.04 m3 / s ΔP 5 47 2–7 ENERGY CONVERSION EFFICIENCIES • Effi Efficiency i i di t how indicates h well ll an energy conversion i or transfer process is accomplished. • Performance or efficiency, efficiency in general, general can be expressed Desired output Performane= Required output (2-41) (2 41) • The efficiency of a water heater: energy delivered to the house by hot water η waterheater = energy supplied to the water heater 48 • The heating value of the fuel (HV): amount of heat released when a unit amount of fuel at room temperature is completely burned and the combustion products are cooled to the room temperature. Q Amount of heat released during combustion η combustion = b ti = HV Heating value of the fuel burned (2-42) 49 Most fuels contain hydrogen, which forms water when burned, and the heating value of a fuel will be different, depending on whether the water in combustion products is in the liquid or vapor form. The heating value is called the lower heating value, or (LHV), when the water leaves as a vapor, and the higher heating value, value or (HHV), (HHV) when the water in the combustion gases is completely condensed and thus the heat of vaporization is also recovered. The difference between these two heating values is equal to the product of the amount of water and the enthalpy of vaporization of water at room temperature temperature. where m is the mass of H2O in the products per unit mass of fuel and h fg is the enthalpy of vaporization of water at the specified temperature. For example, the lower and higher heating values of gasoline are 44,000 kJ/kg and 47,300 kJ/kg, respectively. 50 51 • Power Plant: Q η combustion = HV • η Thermal = Wshaft • Q net shaft work output of the turbine = heat input to the working fluid • η generator = Wnet,electrical • Wnet,shaft electrical power output = mechanicalpower input • η overall = η combustionη thermalη generator = Wnet,electrical • HHV x mnet (2 43) (2-43) 52 • The efficiency Conversion of electrical energy to light energy convertedto light η conversion of electricity to light = electrical energy consumed • The efficiency of a cooking ki appliance li 53 Efficiencies of Mechanical and Electrical Devices • Th The transfer t f off mechanical h i l energy is i usually ll accomplished li h d by a rotating shaft, and thus mechanical work is often referred to as shaft work. • A pump or a fan receives shaft work (usually from an electric motor) and transfers it to the fluid as mechanical energy (less frictional losses). • A turbine converts the mechanical energy of a fluid to shaft h ft work. k • The mechanical efficiency of a device or process is: Emech,loss Mechanical energy output Emech,out (2-44) = = 1− η mech = Mechanical energy input Emech,in Emech,in 54 55 • In fluid systems, we are usually interested in increasing the pressure, pressure velocity, velocity and/or elevation of a fluid. fluid This is done by supplying mechanical energy to the fluid byy a p pump, p, a fan,, or a compressor p ((we will refer to all of them as pumps) g • Or we are interested in the reverse pprocess of extracting mechanical energy from a fluid by a turbine and producing mechanical power in the form of a rotating shaft that h can ddrive i a generator or any other h rotary device. • The Th degree d off perfection f ti off the th conversion i process between the mechanical work supplied or extracted and the mechanical energy of the fluid is expressed by the pump efficiency and turbine efficiency 56 • Pump efficiency • η pump = • Mechanicalenergy increase of the fluid Δ Emech,fluid Wpump,u = • = • Mechanicalenergy input Wshaft, in Wpump (2-45) • Useful pumping power ( Wpump,u ) • • • • Wpump,u = Δ Emech,fluid = Emech,out − Emech, in • Turbine efficiency • Mechanical energy output = η tubine = Mechanical decrease of the fluid • • • W shaft ,out • Δ E mech, fluid • = W turbine • W turbine,e (2-46) • W turbine, e = Δ E mech, fluid = E mech,in − E mech,out which is equivalent to the mechanical power extracted from the fluid by the turbine 57 • Motor efficiency • Mechanicalpower output Wshaft,out η motor = = • Electrical power input Welect, in (2-47) • Generator efficiency • Electrical power output Welect,out η generator = = • Mechanical power input Wshaft h ft, in i (2-48) 58 • A pump is usually packaged together with its motor, and a turbine with its generator. generator Therefore, Therefore we are usually interested in the combined or overall efficiency of pump–motor p p and turbine–generator g combinations: • η pump− motor = η pumpη motor = W pump,u • • = Δ E mech, fluid • W elect,in W elect,in • η turbine− gen = η turbineη generator = W elect,out • W turbine,e (2-49) • = W elect,out • Δ E mech, fluid (2-50) η=0.0% corresponds to the conversion of the entire mechanical or electric energy input to thermal energy, and the device in this case functions like a resistance heater. η=100 %corresponds to the case of perfect conversion with no friction or other irreversibilities, irreversibilities and thus no conversion of mechanical or electric energy to thermal energy. 59 EXAMPLE: An oil pump is drawing 35 kW of electric power while pumping oil with ρ = 860 kg/m3 at a rate of 0.1 m3/s. The inlet and outlet diameters of the p pipe p are 8 cm and 12 cm,, respectively. If the pressure rise of oil in the pump is measured to be 400 kPa and the motor efficiency is 90 percent, determine the mechanical efficiency of the pump, and the overall efficiency. 60 SOLUTION: Assumptions: i (1) ( ) The h flow fl is i steady d andd incompressible. i ibl (2) The elevation difference across the pump is negligible. • • • V22 V12 Δ Emech, fluid = m(emech,out − emech, in ) = m[(Pv)2 + − (Pv)1 − ] 2 2 • V22 − V12 = V [(P2 − P1 ) + ρ ] 2 • V1 = • • • • V V 0.1 V V 0.1 = = = 19.9 m / s and V2 = = = = 8.84 m / s π π A1 π 2 π A 2 D1 (0.08)2 D22 (0.12)2 4 4 4 4 • • Wpump,u = Δ Emech,fluid = 26.3 kW • Wpump,shaft = ηmotor Welectric = (0.9)(35) = 31.5 kW • ηpump = Wpump,u • Wpump,shaft = 26.3 = 0.836 = 83.6% 31.5 η pump−motor = η pumpη motor = 0.836x 0.9 = 0.75 = 75% 61 2–8 ENERGY AND ENVIRONMENT • The h conversion i off energy from f one form f to another h often f affects the environment and the air we breathe in many ways and thus the study of energy is not complete ways, without considering its impact on the environment hydrocarbons (HC), nitrogen oxides (NOx), ) and carbon monoxide (CO) 62 • Fossil fuels such as coal, oil, and natural gas • Pollutants emitted during the combustion of fossil fuels are responsible for smog, acid rain, and global warming and climate change. g • The environmental pollution threat to vegetation, wild life, and human health (i.e Asthma, Cancer), etc…. • Some compounds are added to liquid fuels for various reasons (such as MTBE to raise the octane number of the fuel and also to oxygenate the fuel in winter months to reduce urban smog). • The new cars were required to have catalytic converters in their exhaust systems to reduce HC and CO emissions. • The removal of lead from gasoline to permit the use of catalytic converters led to a significan reduction in toxic 63 lead emissions. • Methyl tert-butyl ether, also known as methyl tertiary butyl y ether and MTBE, is a chemical compound p with molecular formula C5H12O. MTBE is a volatile, flammable and colorless liquid that is immiscible, yet reasonably soluble in water water. • The octane rating is a measure of the autoignition resistance of gasoline or petrol and other fuels used in spark-ignition internal combustion engines. It is a measure of anti-detonation of a gasoline or fuel. • Octane number is the number which gives the percentage, by volume, of iso-octane in a mixture of iso-octane and normal heptane, heptane that would have the same anti anti-knocking knocking capacity as the fuel which is under consideration. For example, p , ggasoline with the same knocking g characteristics as a mixture of 90% iso-octane and 10% heptane would 64 have an octane rating of 90. Ozone and Smog Smog is made up mostly of: 1- Ground-level ozone (O 3) Th harmful The h f l ground-level d l l ozone should not be confused with the useful ozone layer l high hi h in i the th stratosphere t t h that th t protects the earth from the sun’s harmful ultraviolet rays. rays 2- Chemicals, including carbon monoxide (CO) which is a colorless odorless, colorless, odorless poisonous gas gas. 3- Particulate matter such as soot and dust 4- Volatile organic compounds (VOCs) such as benzene benzene, butane, and other hydrocarbons. 65 Acid Rain 9 The sulfur in the fuel reacts with oxygen to form sulfur dioxide (SO2) 9 Volcanic eruptions and hot springs also release sulfur oxides (the cause of the rotten egg smell). smell) 9 The sulfur oxides and nitric oxides react with water vapor and other chemicals high in the atmosphere in the presence of sunlight g to form sulfuric and nitric acids . 9 The acids formed usually dissolve in the suspended water droplets in clouds or fog. These acid-laden droplets, which can be as acidic as lemon juice, are washed from the air on to the soil by rain or snow. This is known as acid rain. 66 The Greenhouse Effect: Global Warming and Climate Change • Glass of the car transmits over 90% of radiation in the visible range and is practically opaque (nontransparent) to radiation in the longer wavelength a elength infrared regions regions. • Therefore, glass allows the solar radiation to enter freely but blocks the infrared radiation emitted by the interior surfaces. This causes a rise in the interior temperature te pe atu e as a result esu t of o the t e thermal t e a energy e e gy buildup bu dup in the car. This heating effect is known as the greenhouse effect, since it is utilized primarily in greenhouses. 67 • The greenhouse effect is also experienced on a larger scale on earth. earth The surface of the earth, earth which warms up during the day as a result of the absorption of solar energy, cools down at night by radiating part of its energy into deep space as infrared radiation. Carbon dioxide (CO2 being the primary component), water t vapor, andd trace t amounts t off some other gases such as methane and nitrogen oxides act like a blanket and keep the earth warm at night by blocking the heat radiated from the earth. Therefore, they are called “greenhouse greenhouse gases” gases . 68 • Excessive amounts of these gases disturb the delicate balance by trapping too much energy, energy which causes the average temperature of the earth to rise and the climate at some localities to change. These undesirable consequences of the greenhouse effect are referred to as global warming or global climate change. change • In I a 1995 report, t the th world’s ld’ leading l di climate li t scientists i ti t concluded that the earth has already warmed about 0.5°C during g the last century, y, and theyy estimate that the earth’s temperature will rise another 2°C by the year 2100. • A rise of this magnitude is feared to cause severe changes in weather patterns with storms and heavy rains and flooding at some parts and drought in others 69 Summary • Forms of energy – Macroscopic = kinetic + potential – Microscopic = Internal energy (sensible + latent + chemical + nuclear) • • • • Energy transfer by heat Energy transfer by work Mechanical forms of work The first law of thermodynamics – Energy balance – Energy change of a system – Mechanisms of energy transfer (heat, work, mass flow) • Energy conversion efficiencies – Efficiencies of mechanical and electrical devices (turbines (turbines, pumps) • Energy and environment – Ozone and smog – Acid rain – The Greenhouse effect: Global warming 70