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Vinnytsia National Pirogov Memorial Medical University Biological and General Chemistry Department Medical chemistry course CHEMISTRY DICTIONARY Vinnytsia 2010 1 Recommended by CMC of Vinnytsia National Medical University (protocol № 5 from 2.03.2011) Authors: Assistant Professor Smirnova O.V. Assistant Professor Chervyak M.M. Assist. Shunkov V.S. Reviewer: Azarov O.S.- Candidate of chemistry science, assistant professor Department of Biological and General Chemistry VNMU Marchak T.V.- Candidate of chemistry science, assistant professor Department of Physiological Agriculture and Live Stock Breeding and Chemistry VNAU Shitova T.V. – Senior-lecturer Department of Russian and Ukrainian languages Head of English language courses VNMU Printing group VNMU: Text editor – Shunkov V.S. Computer editor – Shunkov V.S. Secretary Koroleva N.D. 2 CHEMISTRY DICTIONARY Alkanes Name Methane Ethane Formula CH4 CH3 CH3 Propane Butane Name Methyl Ethyl Propyl CH3 CH3 CH2 CH2 CH3 CH2 CH3 CH CH3 CH3 CH2 CH3 CH2 CH2 CH3 Isopropyl CH3 Butyl CH3 Secondary butyl CH3 Isobutyl Isobutane (2 – Methyl – propane) Radicals Formula CH CH2 CH2 CH CH CH3 CH2 CH3 CH3 CH3 CH2 CH2 CH3 CH3 CH3 Tertiary butyl C CH3 CH3 Pentane CH3 CH2 CH2 CH2 CH3 Pentyl CH3 CH2 Secondary pentyl CH3 CH2 Isopentyl Isopentane (2 – Methylbutane) CH3 CH2 CH CH3 CH2 CH2 CH2 Tertiarypentyl CH2 CH CH CH2 CH3 CH2 C CH3 CH3 2,2 – dimethyl – propane CH3 C CH3 CH3 Halogenoalkanes Chloromethane CH3Cl Trichloromethane (chloroform) CHCl3 C Cl4 Carbon tetrachloride 3 CH3 CH3 CH3 CH3 CH2 CH3 CH I 3 Triiodide (iodoform) CH3 Chloroethane CH3 Chloropropane CH2 CH3 2 – Chloropropane CH2 Cl CH2 CH Cl CH3 Cl CH3 Chlorobutane CH2 CH3 2 – Chlorobutane CH2 CH2 CH2 CH Cl Alkenes Ethene H2C Propene H2C CH Butene –1 H2C CH Butene – 2 H3C CH2 CH2 CH3 CH CH CH3 Pentene – 1 H2C CH Pentene – 2 H3C CH2 CH CH2 Arenes (Benzene and its derivatives) Benzene Phenyl CH3 Toluene CH2 Benzyl 4 CH3 CH2 CH3 CH CH3 CH3 Cl CH3 Xylene: o – xylene (o – dimethylbenzene) CH3 CH3 m – xylene (m – dimethylbenzene) CH3 CH3 p – xylene (p – dimethylbenzene) CH3 C2H5 Ethylbenzene H3C CH CH3 Іsopropylbenzene (cumene) CH CH2 Sterol (vinyl benzene) CH2 OH Benzyl alcohol C Benzaldehyde C Benzoic acid 5 O H O OH O C OH Paraoxybenzoic acid OH C O OH Para–aminobenzoic acid NH2 NH2 Aniline (aminobenzene) NH2 Para–Methylaniline CH3 CH2 NH2 Benzylamine O C Salicylic acid OH O C Acetylsalicylic acid OH OH O C O OH Phenol OH OH Ortho–dioxybenzene (pirokatekhin ) 6 CH3 OH Meta–dioxybenzene (resorcin) OH OH Para–dioxybenzene (hydroquinone) OH OH Cresol: ortho – cresol (ortho – methylphenol) CH3 OH meta – cresol (meta – methylphenol) CH3 OH para – cresol (para – methylphenol ) CH3 OH Para – nitrophenol NO2 Alcohols (R–О– alkoxy group) Methanol Methoxy Ethanol CH3 CH2 OH Ethoxy CH3 CH2 O CH3 CH3 CH3 Propanol O CH2 CH3 Isopropanol OH CH OH 7 CH2 OH CH3 CH3 Butanol Secondary butanol CH2 CH2 CH2 H3C CH2 CH HO CH2 OH CH CH3 Isobutanol OH CH3 CH3 OH CH3 Tributanol C CH3 CH3 OH Cyclohexanol Vinyl alcohol H2C CH OH Polyatomic alcohols CH2 Ethylene glycol (ethandiol) OH OH CH2 CH CH2 Glycerol (propantriol) Xylitol Sorbitol CH2 CH2 OH CH OH CH OH CH CH2 OH OH OH OH OH CH2 CH CH CH CH CH2 OH OH OH OH OH OH Ester (ethers) Dimethyl ether CH3 O CH3 Diethyl ether (medical ether) C2H5 O C2H5 Phenyl ethyl ether C6H5 O C2H5 Amines Metylamine CH3 Ethylamine CH3 Propylamine CH3 8 NH2 CH2 CH2 NH2 CH2 NH2 CH3 Іsоpropylamine (2 – аminоpropane) CH CH3 NH2 Butylamine CH3 CH2 H3C Secondary – butylamine CH2 CH2 CH2 CH NH2 CH3 NH2 Primary amine (metylamine) CH3 Secondary –amine (dimetylamine) NH2 CH3 NH CH3 CH3 N CH3 Tertiary amine (trimetylamine) CH3 CH3 CH3 Quaternary basis N CH3 CH3 Biogenic amines CH2 Calamine (ethanolamine) N Histamine NH2 CH2 OH CH2 CH2 NH2 N H CH2 Tryptamine CH2 NH2 N H HO CH2 Serotonin OH CH2 NH2 N H OH Norepinephrine HO CH CH2 OH OH NH2 Adrenaline HO CH 9 CH2 NH CH3 CH3 N CH3 Choline CH2 CH2 OH CH3 CH3 Acetylcholine CH3 N CH3 CH2 Putrescine CH2 NH2 CH2 CH2 Cadaverine CH2 CH2 O CH2 C NH2 CH2 CH2 CH2 NH2 Thiols (mercaptans) Methanethiol (mercaptomethane) CH3 Еthanethiol CH3 CH3 Dimethyl sulfide SH CH2 CH2 CH3 Іsopropanethiol SH CH2 CH SH S CH3 SH CH3 CH3 SH Thiophenol Aldehydes Methanal (formaldehyde, formic) H C Ethanal (acetaldehyde, acetic) H3C C Trichloracetic aldehyde Cl3 C C Propanal (propionic) CH3 Butanal (oil) CH3 Ketones 10 CH3 CH2 NH2 Propanethiol O CH2 CH2 O H O H O H C CH2 O H C O H CH3 C CH3 CH3 O C C2H5 C6H5 O C C2H5 Acetone (dimethylketone) Methylethylketone Phenylethylketone (propiophenone) O Carbonic acid Formate (methanoic, formic) Acetate (ethanoic, acetic) Propionate (propanoic) Butyrate (butanoic, oil) H C H3C Oxalate (sorrel) Succinate (amber, butanedioic acid) Glucarate (glutaric) OH O C OH O CH3 CH2 C OH O CH3 CH2 CH2 C OH Dicarboxylic acids O Malonate (malonic) O HO O C C O C OH CH3 O C OH HO O O C CH2 CH2 C HO OH O O C CH2 CH2 CH2 C HO OH Oxyacids Lactate (milk, 2 – oxypropane) CH3 CH C OH β – Oxybutyrate (β – hydroxybutyric, 3 – oxobutanoate) CH3 O Malate (apple, 2 – oxybutanedioic) HO 11 CH CH2 O OH C OH C CH2 CH OH C O OH O OH OH O Citrate (lemon acid) C HO CH2 C CH2 O C O Tartare (wine acid) C HO C OH CH CH OH OH O OH O C OH Oxoacids CH3 Pyruvate (PA, pyruvic, 2 – oxopropane) C O C OH O CH3 Acetoacetate (3 – oxobutanoate) O Oxaloacetate (2 – oxobutandioic) α – Ketoglutarate (α – ketoglutaric, 2 – oxopentadioic) HO O CH2 C O C CH2 C C O C C HO C CH2 CH2 O OH O OH C O Unsaturated carboxylic acid Acrylate (acrylic, 2 – propenoic) CH2 Crotonic (2 – butenoic) CH3 C CH CH O OH O C OH CH Anhydrides Formic Acetic H C H C H3C C H3C C O O O O O O Halogenanhydrides Methyl chloride H 12 C O Cl O OH Acetyl chloride H3C C Benzoyl chloride C6H5 C O Cl O Cl Amides, nitriles O Acetamide H3C C Benzamide C6H5 C NH2 O NH2 Acetonitrile H3C C N Benzоnitrile C6H5 C N Esther O Methyl formate (methyl methanoate) H C Ethyl formate H C Methyl acetate H3C C Ethyl acetate H3C C Methyl benzoate C6H5 13 O CH3 CH2 C O C2H5 O O O CH3 O O C2H5 O CH3 Lipids Higher fatty acids Palmitic C15H31COOH Stearic С17H35COOH Oleic C17H33COOH Linoleic C17H31COOH C OH H3C O C OH H3C H3C O C C OH O OH H3C O C Linolenic C17H29COOH OH CH3 C Arachidonic C19H31COOH Oleic C17H33COOH O O OH CH3 H3C C Triacylglycerides (tristearine) 14 H2C O C HC O C H2C O C O C17H35 O C17H35 O C17H35 O OH H2C Phosphatidic acid Phosphoglyceride (phosphatidylcholine) O O C C17H35 O HC O C H2C O PH H2C O C HC O C H2C O P C17H33 O OH O C17H35 O C17H33 O OH O H2C CH2 CH3 CH3 CH3 N Amino acids Monoaminomonocarboxylic acid CH2 Glycine (Gly) O C OH NH2 CH3 Alanine (Ala) O C CH OH NH2 CH3 * Valine (Val) Leucine* (Leu) CH3 CH CH CH3 NH2 CH CH2 CH3 Isoleucine* (ile) CH3 CH2 Monoaminodicarboxylic acid 15 C CH O OH C NH2 CH CH CH3 NH2 C O OH O OH O Aspartic (Asp) (aspartate) HO O Glutamic acid (Glu) C CH2 C H2N O Glutamine (Gln) O C OH CH2 CH C NH2 O Asparagine (Asn) CH NH2 C HO CH2 CH CH2 CH2 OH O C OH NH2 C H2N CH2 O C CH O NH2 OH Diaminomonocarboxylic acid H2N Lysine*(Lys) CH2 CH2 CH2 CH2 CH C NH2 Arginine (Arg) NH2 C NH CH2 CH2 CH2 CH C NH2 NH Oxyamino acid * Serine (Ser) CH2 CH OH NH2 H3C Threonine (Thr) O C CH CH OH NH2 OH O C OH Sulfur-containing amino acids Cysteine (Cys) Methionine*(Met) H3C S CH2 CH SH NH2 CH2 O C CH2 OH CH C NH2 Aromatic amino acids CH2 * Phenylalanine (Phe) CH NH2 16 C O OH O OH O OH O OH Tyrosine (Tyr) CH2 HO CH C O OH NH2 Heterocyclic amino acids CH2 Tryptophan*(Trp) Histidine (His) C CH2 CH O C OH NH2 N H Proline (Pro) OH NH2 N H N CH O N H O C OH Carbohydrates Monosaccharides CH2OH H Glucose O H OH H H OH OH H OH CH2OH O H OH H H OH OH H Galactose H OH CH2OH O H H H OH OH OH OH Mannose HO CH2 H O H Fructose H OH OH H OH 17 H2C H OH HO CH2 H Ribose OH O H H H HO CH2 OH OH H Deoxyribose OH O H H H HO CH2 OH H H OH Xylose H O OH H H CH2O H H OH Glucose - 6 phosphate OH PO3H2 O OH H H OH H OH CH2OH O H H H H OH OH OH H NH2 Glucosamine Disaccharides CH2OH H Sucrose H OH O O H OH H OH HO CH2 OH CH2OH OH Lactose H OH H2C O H H H H OH CH2OH O H O H H OH O 18 OH H H OH H H H OH H OH CH2OH H Maltose H OH CH2OH O H H H Cellobiose O H OH CH2OH O H H OH OH H OH CH2OH O H H OH H O H H OH Nitrogenous base Pyrimidine line O NH Uracil N H O O H3C Thymine NH O N H NH2 N Cytosine N H O Purine line NH2 N Adenine N N O N H HN Guanine H2N 19 OH H H OH H H O OH H H OH N N N H OH