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2C Spring 03 Chemistry 2C Worksheet Chapter #27 Terminology, Structure, and Nomenclature Circle the Single Best Answer. 1. All of the following are saturated straight-chain hydrocarbons except A) C3H8 B) C4H8 C) C4H10 D) C6H14 E) C5H12 2. Which of the following could be a cycloalkane? A) C6H12 B) C3H8 C) C4H10 D) C5H12 E) C6H14 3. For (CH3)2CHCH(CH3)CH2CH(CH2CH3)CH2CH2CH3, the longest unbranched chain of carbon atoms is A) 6 B) 7 C) 8 D) 9 E) 12 4. Which of the following could be an alkyne? A) C2H4 B) C4H8 C) C2H6 D) C4H6 E) C3H6 5. The compound (CH3)2CHCH(CH3)CH2CH(CH2CH3)CH2CH2CH3 is named as A) a decane. B) a nonane. C) an octane. SAME QUESTION AS #3 and #7 D) E) a hexane. a heptane. 6. The compound (CH3)3CCH2CH(CH3)2 is A) named as a hexane but is an isomer of octane. B) named as a pentane but is an isomer of heptane. C) named as a pentane but is an isomer of octane. D) named as a pentane but is an isomer of hexane. E) named as a butane but is an isomer of octane. 7. Name the compound (CH3)2CHCH(CH3)CH2CH(CH2CH3)CH2CH2CH3. A) 2,3-dimethyl-5-propylheptane B) 5-ethyl-2,3-dimethyloctane C) 4-ethyl-6,7-dimethyloctane D) 6,7-dimethyl-4-ethyloctane E) 2-methyl-3-methyl-5-ethyloctane 8. Name the compound (CH3)2CHCH(Cl)C(CH3)3. A) 3-chloro-2,4,4-trimethylpentane B) chloro-t-butyl-isopropylmethane C) 3-chloro-2,2,4-trimethylpentane D) 4-chlorooctane E) 2-chloro-1,1,1,4-tetramethylbutane 9. Name the compound C(CH3)4. A) 2,2-dimethylpropane B) isopropylmethane C) 2-methylbutane D) isobutylmethane E) pentane 10. Name the following compound. A) B) C) D) E) 4-ethyl-2,2,5-trimethylhexane 3-ethyl-2,5,5-trimethylhexane undecane 1,1,1,4-tetramethyl-3-ethylpentane 1-tert-butyl-4-ethyl-5-methylbutane 11. Name the following compound. A) 1-iodo-2-methylbenzene B) 2-iodo-1-methylbenzene C) m-iodobenzene D) E) m-toluene 2-iodo-3-methylbenzene 12. Name the compound H2C=C(Cl)CH2CH2CH3. A) 2-chloro-2-pentene B) 2-chloropentene C) 4-chloro-4-pentene D) chloropentene E) 2-chloro-1-pentene 13. Name the following compound. A) 3,5-dinitrobenzene B) 1,3,5-trinitrobenzene C) di-m-nitrobenzene D) 2,4,6-trinitrobenzene E) trinitrobenzene 14. Name the compound CH3COO(CH2)7CH3. A) methyl octanoate B) octyl acetate C) heptyl acetate D) 2-decanone E) decanoic acid 15. Which of the following is a tertiary alcohol? A) CH(CH3)2OH B) CH3(CH2)3OH C) CH3CH2OH D) C(CH3)3OH E) C6H5CH2OH 16. The compound CH3CH2OCH2CH3 is A) a ketone. B) an ester. C) an ether. D) an alcohol. E) an aldehyde. 17. The hydroxyl group occurs in A) aldehydes and alcohols. B) ketones and carboxylic acids. C) alcohols, phenols, and carboxylic acids. D) E) alcohols only. phenols and ketones. 18. The systematic name of CH3CH2CH(CHO)CH3 is A) 2-methylbutanal. B) 3-methylbutanal. C) 2-pentanone. D) 2-pentanal. E) 2-ethylpropanal. 19. How many isomers are there with the formula C6H14. A) 1 B) 2 C) 3 D) 4 E) 5 20. The compound 1-chloro-1-pentene A) has 3 structural isomers. B) is an alkyne. C) has the formula C5H11Cl. D) can exist as cis and trans isomers. E) cannot exist as cis and trans isomers. 21. Name the following compound. A) trans-2-pentene B) ethylmethylethene C) trans-1-ethyl-1-propene D) cis-2-pentene E) trans-1-methyl-1-butene 22. Which of the following alkenes shows cis-trans isomerism? A) CH2CH(CH2CH3) B) (CH3)2CCH(CH2CH3) C) CH(Cl)C(CH2CH3)2 D) CCl2CH(CH2CH3) E) CH(Cl)CHCH(CH2CH3)2