Download ORGANIC REAGENTS

ORGANIC REAGENTS
S.No. Reagent
1
PCl3, PBr3, PI3
2
SoCl2, PCl5
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
Function
Alcohols into Alkyl halides
Alcohols into Alkyl chlorides &
Carboxylic acids into Acid Chlorides
HCl/ZnCl2,HBr,HI
Alcohols into alkyl halides
Cl2/Fe or FeCl3
Cl group substituting on Benzene
0
NaNO2 /HCl 0-5 C
Diazotisation
CuCl,CuBr,CuCN,KI,H2O, Diazonium Cholride into Chlor Benzene,
H3PO2
Bromo Benzene, Benzo nitrile, Iodo
Benzene , Phenol,Benzene respectively
HBF4 or NaBF4
Diazonium Chloride into Floro Benzene
AgF or Hg2F2 or SbF3 or
Alkyl halides into alkyl florides
CoF2
Na / dry ether
Alkyl halides into alkanes
NaOH 623/443/368K
Chloro benzene to phenol
Br2 /FeBr3
Bromination of Benzene
Cl2 /FeCl3
Chlorination of Benzene
CH3Cl /AlCl3
alkylation of benzene and its derivatives
CH-CO-Cl /AlCl3
Acylation on benzene
H2SO4 /HNO3
Nitration of benzene
(CHCO)2O /AlCl3
O – Acylation of Phenol
H2SO4
Sulphonation on Benzene
H2O/ H 2SO4
alkenes into alcohols
Aq KOH
Alkyl halide into alcohol
BH3 /H2O 2 /OH
Alkenes into alcohols (Anti
Markownikoff product)
NaBH4/ LiAlH4(LAH)
Aldehydes, ketones, acids into alcohols,
Nito & Cynides , Isocyanides into amines
H2/ Ni or H2/Pd
reduction of aldehydes, ketones and
cynides
+
RMgX/H3O
Aldehydes, ketones into alcohls
+
O2/H
Cumene to phenol
Na
Alcohol or phenol into Sodium
alkoxide/Phenoxide
(CHCO)2O/ CH-CO-Cl
O acylation on phenol or N acylation on
Aneline or amine
Conc.H 2SO4/443K
Conversion of primary alcohols into
Alkenes
Conc.H 2SO4/410K
Conversion of alcohols into Ethers
85% H3PO4 / 440K
Secondary alcohol into alkene
20% H3PO4/358K
Tertiary alcohol into alkene
Alcoholic KOH
Alkyl halide into alkene
ORGANIC REAGENTS
30
31
32
33
34
35
36
37
38
39
40
CrO3/KMnO4 or K2Cr2O 7
in acidic medium
Cu /573k
41
42
43
44
45
46
47
48
49
50
51
Dil. HNO3
Conc.HNO3
Br2 /H2O
Br2 /Cs2
NaOH /CO2
CHCl3 /NaOH
Zn dust
Na2Cr2O7 /H2SO4 or air
Zn/Cr2O 3 200to 300 atm
573 – 673K
Invertase
Zymase
HI
PCC
Pd /BaSO4,H2
SnCl2/HCl/H3O+
AlH(i-Bu)2/H2O
DIBAL-H/H2O
CrO2Cl2/H2O
CrO3 /(CH 3CO)2O
Cl2/hv
52
53
54
55
56
57
58
59
CO, HCl anhydrous AlCl3
(CH3)2Cd
RMgX/H3O +
HCN
NaHSO3
H2NOH
H2N-NH2
H2N-NH-Ph
60
2,4DNP
61
62
H2N-NH-CO-CH3
ROH/HCl
63
HO-CH2-CH2-OH/HCl
oxidation of alcohols into acids
dehydrogenation of alcohols gives 10
alcohols into aldehydes and 20 alcohols
into ketones & 30 alcohos into alkenes
Mono nitration of Phenol
tri nitration of phenol
tri bromination of phenol
mono bromination of phenol
Phenol to salicilic acid
Phenol to salcilaldehyde
Phenol to Benzene
Phenol to Benzo quinone
CO & H into methanol
Sucrose into Glucose or Fructose
Glucose or Fructose into ethanol
Ether into alcohol & alkyl halide
alcohol to aldehyde
acid chloride into aldehyde
Cyanides into aldehydes
Cyanides into aldehydes
Esters into aldehydes
Toluene to aldehyde
Toluene into Benzaldehyde
Chlorination on alkyl group of Benzene or
alkane
Benzene to Benzaldehyde
acid chloride into ketones
Cyanides into ketones
Carbonyl compound into cyanohydrin
addition to aldehyde and ketone
carbonyl compound into oxime
carbonyl compound into hydrazone
carbonyl compound into Phenyl
hydrazone
carbonyl compound into 2,4 dinitro
phynyl hydrazone
carbonyl compound into semi carbazide
Aldehydes & ketones into hemiacetal and
acetal
Aldehyde or ketone into ethelene glycol
ORGANIC REAGENTS
64
65
66
67
68
69
70
71
72
73
Zn-Hg/HCl
H2N-NH2 /KOH
KMnO 4/OH-/ K2Cr2O7
/H2SO4 or HNO3
(Ag(NH 3)2)NO3+NaOH
Cu(OH)2
NaOH+I2
NaOH or Ba(OH)2
Conc KOH or NaOH
KMnO 4 /KOH
H2O/H +
74
NaOH
75
76
Na2CO3 or NaHCO3
P4O 10 or P2O5
77
78
79
80
81
ROH/conc H2SO 4
PCl3, SoCl2, PCl5
NH3 heating
NaOH/CaO
LiAlH4
82
83
Cl2 /red.P4
Sn /HCl or Fe /HCl, H2/Pd
84
85
86
87
NH3
H2/ Ni or H2/Pd LiAlH4
KOH/R-X
NaOH /Br2
88
89
90
91
92
93
KOH,CHCl3
NaNO2/HCl
NaNO2/HCl 0 – 50C
C6H5SO 2Cl
Br2/H2O
Br2/ CH-CO-Cl
/(CHCO)2O
ketone
carbonyl compound into alkane
carbonyl compound into alkane
Ketones into mixture of carboxylic acids
on prolonged oxidation
Tollen’s test
Fehiling’s test
Iodoform
aldal condensation
Cannizaro’s reaction
Toluene/alkyl Benzene into Benzoic Acid
Cyanides into carboxylic acids, amides
into carboxylic acids, esters into
carboxylic acis and alcohols, acid
chlorides or anhydrides into carboxylic
acids
Saponificaiton of ester, acid into salt of
acid
Carboxylic acid test
Dehydration of acids into anhydride,
amides into nitriles
Caroxylic acids into esters
Carboxylic acids into acid chlorides
Carboxylic acids into amides
Decarboxylation (acids into alkanes)
Carboxylic acids into alcohols, amides
into amines
HVZ reaction
Reduction of nitro compounds into
amines
Alkyl halides into amines
Amides into cyanindes
Phthalamide into amine
Hoffman bromamide, amide into amine
with one ‘C’ less
Amines into Carbyl amines
10 aliphatic amines into alcohols
Aniline into diazonium chloride
Distinguishing 10,20 & 30 amines
Aneline into tri bromo aniline
Aniline into Bromo Aniline
ORGANIC REAGENTS
94
95
96
HNO3/ CH-CO-Cl
/(CHCO)2O
H2SO4
CuCl,CuBr,CuCN,KI,H2O,
H3PO2 or CH 3-CH2-OH
Nitro aniline
Sulphonation on aniline
Diazonium Cholride into Chlor Benzene,
Bromo Benzene, Benzo nitrile, Iodo
Benzene , Phenol,Benzene respectively
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