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Modern Periodic Table Chapter 11 Periodic Trends Periods • Horizontal Rows • Based on Atomic Number for order • Based on Electron Configuration for arrangement Groups and/or Families p.68,69 • Vertical Column(s) • Elements in groups/families g p have similar (not identical) properties Patterns Repeat in a group/family because Electron Configurations repeat. • Focus for this relationship is the valance electrons • Valance = Outermost s & p electrons • O: 1s22s22px22py12pz1 • Ga: 1s22s22p63s23p64s23d104px1 • K: 1s22s22p63s23p64s1 1 Metals vs. Nonmetals Periodic Law: • When elements are arranged g atomic in order of increasing number, their physical & chemical properties show a repeating (periodic) pattern Semimetals or Metalloids 1 -Solids - dull 2 -Poor conductors of heat & electricity 3 -most are Gases @ room temp. (low m.p. & b.p.) 4 & 5 -Solids are brittle 6 -Form Form negative ions Periodic Trends A. Atomic Radius Increeases in Size • B, Si, Ge, As, Sb, Te, Po, At • Properties: ( ) Luster (metallic) Brittle (nonmetallic) Semiconductors of heat & electricity (intermediate) 1 -Luster 2 -Good conductors of heat & electricity 3 -Solids at room temp. p (High melting & boiling points) 4 -Malleable 5 -Ductile 6 -Form positive ions Decreases in Size A. Atomic Radius • Within a period the number of protons increase (nucleus gets larger) have a greater pull on the outer electrons • The result is a tighter/closer hold on outer electrons 2 B. Ionization Energy • Energy required to remove an electron from an atom (measure in Joules (J) or kilojoules (Kj) B. Ionization Energy C. Electron Affinites Increases C. Electron Affinities Decreaases • Measures an atom’s attraction for an electron Decreaases • Atoms w/ filled or 1/2 filled sublevels are slightly more stable (less reactive) than atoms with other arrangements. • Octet rule: An atom with 8 electrons in its valence shell (s & p’s) is the MOST chemically stable Increases 3 C. Electron Affinities • Nonmetals (exception Noble gases) More likely the atom will gain an electron • Metals l – Less likely lik l to gain i an electron. 4