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Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Abstract Volume The Romanian Geological Society a possible link to the future Prof.univ.dr. Nicolae Anastasiu ass.Member of the Romanian Academy- RGS president At the beginning of a millenium where science progresses crossed several borders, and where man is already exploring for some time the space and the oceans depth, when the states controlling the high technique take samples from the moon space, a glance to a distant past brings us into the world of those who searched and discovered, systematically, materials that we are calling today raw materials: iron, aluminum, coal, lead, silica, oil, gold …and many others. Over the last two hundred years, the geologists stood behind these discoveries, those men who, by their love and understanding for nature, drew up hypothesis and issued concepts regarding the evolution and structure of the earth crust-this fragile cover which protects the earth coat and accumulates, for billions and hundreds of millions of years, mineral riches conserved and kept hidden. We should not forget that, for the last centuries and, moreover, nowadays, we were given the access thanks to the effort made in order to know and understand the mineral, vegetal and animal world, the processes which generated over long periods of time, permanent interactions between the lithosphere, the atmosphere, the hydrosphere and the biosphere and the formation of resources with an extremely variety of properties. From the beginning, the Geology gathered a community of specialists with complex background, trained for approaching, by physical, physical-chemical, optical, radiometric and geo-physical continuously improved methods, the concentration places of the energetic and mineral substances, geological bodies shape where they are localized, the depth at which they are found, and, but not last, the economic reserves and their qualities. If we do not neglect all these aspects-which define only a fragment of what Geology and the geological activities mean- then we do realize a part of the importance or of the role played by this field of the geological sciences foe the human society and its evolution, as well as the role which was and is still played by this science in the human civilization history. The observation facts that allowed it to define itself and to impose itself or to clearly create its own investigation methods and instruments gathered slowly, with big efforts and, many times, with many disputes…always specific to a scientific community in progress. The institutions which were and are in charge of the GEOLOGY, in the strict sense of the word, appeared late, but they developed fast. I would dare to compare this system with the computers universe…The traditional countries established, in the high education first, Geology Departments at the beginning and at the middle of the XIXth century (….) and much more later they established governmental institutions licensed to manage “the geologic fund”. Whether they were called Research Institutes, Geological Survey or Agencies for the regulation and the evolution of the resources and reserves potential, once they appeared, they diversified a lot its specialization, they created its specialists and they developed. Nowadays they exist in all developed countries, European or non-European, not from a moral obligation to those who created them, but from an important necessity: that of a interdisciplinary integration which is the base for the globalization profits and strategies. In March 1930, prof.L. Mrazec also proposes the establishment of a geological Society “established on the demand of and for the geologists and the geology friends from the country, disregarding the 1 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai place where they develop their activity”; in this way, it was established a non-governmental institution, with its own rules and generous projects, opened to the civil society and to those spirits which have something to say about “the formation and evolution of the earth crust, about its riches, about the phenomena which keep it alive- the earthquakes and the volcanism evolution-, about the oil and salt origin…” Looking further, we foresee new zones and new priorities where the geological knowledge is a must. In this way, the globalization imposes us a fast adaptation to the new rules required by the environmental protection, the lasting development, the soils fertilization, the fight with the natural disasters, the water need in the desert zones and not only, the climate predilections…Starting with the hammer and the microscope, the utility airplanes (for gravimetry, radiometry, magnetometry ), the electronic wells and performance computers gather information necessary for the statistics and the strategic decisions: data banks are a reality, and the geological drawers must be full. Today’s Romanian Geological Society-by charter, a non-profit and non-governmental organization – with its septuagenarian tradition and with the chance of having had as members and leaders important personalities, looks further remembering that: ”the spirit of free scientific thinking and harmony always dominated inside the Society… This spirit can grow only in the framework of a free education, namely in the framework of that atmosphere which guarantees the liberty of searching, thinking and scientifically speaking, leaving free initiative to the researcher. These are the essential conditions for following undisturbed to find the truth which is the thinking and research supreme scope”. (said L.Mrazec in 1934) May be it is high time to intuit what RGS desires to become: - a place for as many as possible; an institution opened to the civil society which it can inform about the life of the Planet; an active association, where the geologists and the geologist students can debate, in a regular way, their problems and where they have the opportunity to become famous; a professional society which can keep in touch with many profile societies from the country and abroad (AAPG, for example) and which would be represented by its most important members at the national and international scientific events; a “club” for pupils and students where they can find information about the jobs and the professional orientations; a window towards geological sites from other continents; a space where it can be found motivations or where one can rediscover the campaigns world.. All these facts can be a message and a few clues we are bearing in our minds; it can be others, too, but no matter how many of them are added, we need as many as possible, so that our experiences, our passions and our knowledge-all gathered together- would gain strength and would enforce the prestige and the life of the Society whose members we are. On their behalf, we send our greeting to the partners interested in cooperating with us, and we wish luck to the RAPG scientific session. Societatea Geologică – nevoia de comunicare Prof.univ. dr. Nicolae Anastasiu m.c. al Academiei Române – preşedinte SGR La începutul unui mileniu în care progresele ştiinţei au trecut numeroase frontiere, iar omul explorează de mult spaţiile extraterestre şi fundurile oceanelor, când statele care controlează tehnica de vârf exploatează probe din spaţiul lunar, o privire într-un trecut îndepărtat ne fixează în lumea celor ce au căutat şi au descoperit, metodic, substanţe utile pe care astăzi le denumim materii prime: fier, aluminiu, cărbune, cupru, silice, petrol, aur...şi câte altele.În spatele lor, în ultimii două sute de ani, au stat geologii, cei care, iubind şi înţelegând natura , au elaborat ipoteze şi au emis concepte despre structura şi evoluţia scoarţei terestre – acest fragil înveliş ce protejează mantaua pământului şi acumulează, de miliarde şi sute de milioane de ani, bogăţii minerale pe care le conservă şi le ţine ascunse. Nu ar trebui să uităm că în ultimele secole şi, cu atât mai mult, astăzi, accesul la ele a fost şi este posibil graţie unui efort de cunoaştere şi 2 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai înţelegere a lumii minerale, vegetale şi animale, a proceselor care au generat, în lungi perioade de timp, interacţiuni permanente între litosferă, atmosferă, hidrosferă şi biosferă şi au generat resurse purtătoare de proprietăţi de o extremă diversitate. De la început, Geologia a grupat o comunitate de specialişti cu formaţie complexă, pregătiţi pentru a aborda, prin metode mereu avansate - fizice, fizico-chimice, optice, radiometrice, geofizice - locurile de concentrare a substanţelor minerale şi energetice, forma corpurilor geologice în care sunt localizate, adâncimea la care se găsesc şi, nu în ultimul rând, rezervele economice şi calităţile lor. Dacă nu neglijăm toate aceste aspecte – care definesc, însă, doar un mic segment din ce înseamnă Geologia şi activităţile geologice – atunci realizăm o parte din importanţa sau rolul pe care acest domeniu al ştiinţelor geonomice îl are pentru societatea omenească şi pentru dezvoltarea sa , precum şi din rolul pe care această ştiinţă l-a jucat şi îl joacă în istoria civilzaţiei pământene. Faptele de observaţie care i-au permis să se autodefinească şi să se autoimpună sau să-şi creeze, în mod evident, propriile metode şi instrumente de investigaţie s-au adunat încet, cu mari eforturi şi, nu de puţine ori, cu multe dispute...mereu proprii unei comunităţi ştiinţifice în progres. Instituţiile care s-au ocupat şi se ocupă de GEOLOGIE, în sens strict, au apărut târziu, dar s-au dezvoltat rapid. Aş compara sistemul cu universul computerelor....Ţările cu tradiţie au fiinţat, iniţial în învăţământul superior, Catedre de Geologie la începutul şi mijlocul secolului XIX (....) şi mult mai târziu instituţii guvernamentale acreditate să administreze „fondul geologic”,. Fie că s-au numit Institute de cercetări, Geological Survey, sau Agenţii de reglementare şi evaluare a potenţialului de resurse şi rezerve, odată apărute, ele şi-au diversificat mult specializările , şi-au creat specialişti şi s-au dezvoltat. Astăzi ele există în toate ţările dezvoltate, europene şi extraeuropene, nu dintr-o obligaţie morală pentru cei ce le-au creat, ci dintr-o necesitate stringentă: aceea a unei integrări interdisciplinare ce fundamentează strategiile şi beneficiile globalizării. Lumea ştie peste tot de ele, iar cei dintre noi care au pus bazele instituţiilor fundamentale din învăţământ, cercetare şi industrie au făcut eforturi mari să ne facă cunoscuţi. În martie 1930, prof. L. Mrazec a propuns constituirea unei Societăţi Geologice “înfiinţată la cererea şi pentru geologii şi prietenii geologiei din ţară, indiferent de locul în care îşi desfăşoară activitatea” ; se statua, astfel, apariţia unei instituţii neguvernamentale, cu reguli proprii şi proiecte generoase, deschisă spre societatea civilă şi spre acele spirite care aveau ceva de spus despre „formarea şi evoluţia scoarţei terestre, despre bogăţiile ei, despre fenomenele care o ţin în viaţă – cutremurele şi vulcanismul- , despre originea petrolului şi a sării... Privind înainte , întrezărim noi zone şi noi priorităţi în care aplicarea cunoştinţelor geologice este iminentă. Astfel, globalizarea ne impune o adaptare rapidă la noile reguli cerute de protecţia mediului, de dezvoltarea durabilă, de fertilizarea solurilor, de lupta cu hazardele naturale, de nevoia de apă în zonele deşertice şi nu numai, de predicţiile climatice…Pornind de la ciocan şi microscop, avioanele utilitare (pentru gravimetrie, radiometrioe, magnetometrie) sondele electronice şi computerele performante culeg informaţii utile pentru statistici şi decizii strategice: băncile de date sunt o realitate, iar sertarele geologice se cer pline. Societatea Geologică a României de astăzi - prin statut, o organizaţie neguvernamentală şi non-profit – cu tradiţia sa septuagenară şi cu şansa de a fi avut ca membri şi conducători personalităţi marcante – după L. Mrazec, pe Ion Simionescu, Gh. Macovei, I.Popescu-Voiteşti, D.M.Preda, Al.Codarcea, George Murgeanu, Dan Rădulescu, Mircea Săndulescu - , priveşte înainte aducându-şi aminte că : „spiritul de cugetare ştiinţifică liberă şi de armonie a dominat întotdeauna în sânul Societăţii..Acest spirit nu se poate desvolta decât în cadrul libertăţii învăţământului , şi anume în acea atmosferă ce garantează libertatea de a cerceta, de a gândi şi de a grăi ştiinţificeşte, lăsând iniţiativă liberă cercetătorului ( L.Mrazec, 1934). In noua sa formă organizatorică SGR grupează geologi din numeroase domenii - mineralogie, petrologie, metalogenie, geochimie,paleontologie, stratigrafie, sedimentologie, geologie marină, geologie structurală, geologie economică, geologie ambientală - dispuşi să comunice şi să interacţioneze în proiecte generoase ştiinţific şi profitabile economic. Colocviile lunare care s-au derulat în primul semestru al anului 2002 au umplut amfiteatrul de la Universitate şi au prefigurat certitudinea că o motivaţie pentru dialog interdisciplinar exista şi o punte între generaţii, se schiţează. Organizarea Sesiunii ştiinţifice GEO 2002 ne-a apărut ca o provocare, iar cele 60 de lucrări a căror rezumate le grupăm în acest volum sunt expresia nevoii de comunicare. Autorii lor, în mare măsură membrii ai Societăţii Geologice a României, sunt cercetători cu experienţă, profesori de prestigiu şi, alături de ei, studenţi şi geologi de la diverse companii. Poate este momentul să intuim ceea ce SGR poate şi doreşte să devină: un loc pentru cât mai mulţi; 3 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai o instituţie deschisă spre societatea civilă, pe care să o informeze despre viaţa Planetei; o asociaţie activă, în care geologii şi studenţii din aria geologiei să-şi poată dezbate, regulat, problemele de care se ocupă şi în care să se facă cunoscuţi; o societate profesională, care să ţină legătura cu multe alte societăţi de profil din ţară şi din străinătate (AAPG-ul ,de exemplu) şi care să fie prezentă la reuninunile ştiinţifice naţionale şi internaţionale, prin membrii săi de elită; un “club” pentru elevi şi studenţi în care să poată găsi informaţii despre job-uri şi orientări profesionale; o fereastră spre sit-uri geologice din alte continente, un spaţiu, în care să se găsească motivaţii sau să se redescopere lumea campaniilor de teren.. Pot constitui toate acestea un mesaj şi câteva repere pe care le purtăm în gând; pot fi şi altele, dar oricâte s-ar adăuga, este nevoie de cât mai mulţi, pentru ca experienţele, pasiunile şi cunoştinţele noastre – puse alături – să capete forţă şi să întărească prestigiul şi viaţa Societăţii ai cărei membri suntem . mai 2002 DIAGENETICAL EFFECTS ON THE NEOCOMIAN LIMESTONES FROM THE CENTRAL AREA OF MOESIAN PLATFORM – RELATIONS TO THE HYDROCARBONS DYNAMICS Nicolae ANASTASIU, Relu-Dumitru ROBAN Universitatea Bucureşti, [email protected] Cuvinte cheie: Moesian Platform, Neocomian, diagenesis, dolomitisation, stylolite, hydrocarbon reservoir A sedimentological analysis has been performed in order to point out the postdepositional (diagenetic) evolution of the reservoir architectures component of Videle, Blejesti, Serdanu and Ungureni structures. For this several methods – i.e. grain- size & shape analyses, microstructures examination, cathodoluminiscence and U.V. fluorescence studies - have been applied. Specific postdepositional processes – physical, chemical and biochemical in character – that acted differently - spatially and temporally - have been identified, as follows: differential compaction and illuviation of matrix, sindepositional bioturbations, micritizations, vadose- and submarine cementations, polymorphic transformations, recrystallizations (by aggradation), authigeneses of calcite, dolomite and pyrite, pressure solutions, and joints/ fractures. Recrystallizations (by aggradation), are the most frequently, selective, and affect the matrix, peloides, intraclasts and bioclasts . The process is never complete, not symmetrical. Microstylolites are effect of pressure solution, and cover the boundaries between the litons. Sometimes it cut pelloides , and that is a prove for water roll in the process. Dolomitization it was a recurrent processes, in telogenesis, and mesogenesis stages. We can see a cover effect. The effective and total porosity of the studied reservoirs is directly subject to this processes, that specifically controlled modifications of "grain- support" and pore space as well, within three diagenetic stages: incipient burial (eogenesis), uplifting (telogenesis) and, respectively, progressive burial (mesogenesis). 4 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The hydrocarbons dynamic – either from source to reservoir bodies or inside reservoirs – could be considered as a complex process, mainly controlled by pore space configuration and by the relationship between the time of hydrocarbon maturation and the evolution of each process modifying pore space. The prediction of hydrocarbons in dolomitic reservoirs – which hosted a large void, should be connected with depositional model. Intercrystalline pores, and dissolution voids are the most frequent in the reservoirs. EVOLUTION OF ORGANIC MATTER IN PALEOZOIC FORMATIONS LYING TO THE EAST OF BUCHAREST MERIDIAN Stefania ARSENE, Nina BARBULICEANU C.C.P.E.G. Toamnei Ave.,nr.103, sect.2,Bucharest, e-mail: [email protected] ; [email protected] To the east of Bucharest meridian, the Paleozoic penetrated by the drillings carried out in the area consists of sedimentary series that have been divided in three major Formations: Tandarei, Calarasi and Vlasin. Throughout these formations, pelitic sequences have been identified, where in both the organic matter content and the chemical composition classify them within the category of hydrocarbon source rocks. The laboratory analyses performed on the organic matter taken out from these formations made it possible to remark on the type of initial organic matter, transformation degree and its actual state. The available data suggest that the organic matter deposited in Tandarei and Calarasi Formations is of a marine origin and gave rise to kerogen type II and the one deposited in Vlasin Formation has a highly terrestrial input resulting in the formation of mixed kerogen. These formations are actually at the end of the oil window. The genetic relationship between these source rocks and the oils occuring within the relevant area's accumulations could not be established mainly due to the advanced oil degradation level. DIAGENETIC EVOLUTION OF THE CARBONATE DEPOSITS NEAR THE JURASSIC-CRETACEOUS BOUNDARY FROM LESPEZI QUARRY Victor BARBU University of Bucharest, Faculty of Geology and Geophysics, Department of Geology & Paleontology 1 Nicolae Balcescu Ave, sect. 1, RO-70111 Bucharest, ROMANIA e-mail: [email protected] Keywords: limestone, diagenesis, staining, cathodoluminescence, Jurassic/Cretaceous boundary, Lespezi quarry. Lespezi quarry was selected for studying diagenetic evolution of the carbonate deposits near the Jurassic-Cretaceous boundary from the Southern Carpathians. This quarry localized in the southern part of the Bucegi Mts. represent a key outcrop for understanding geological evolution of the narrow carbonate platforms attached to the extensional continental margins during the Upper Jurassic. 5 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Several specific techniques for analyses of the diagenetic features have been applied in the laboratory: staining with Alizarin Red and K Ferricyanide for carbonate mineral identification (Dickson, 1966), optical petrography and cathodoluminescence for deciphering the growth zones of the cements inside the pores. These analyses helped to establishing the diagenetic environments, fluid flows and temporal evolution of these carbonate deposits. Based on these analyses it was for the first time recorded a subaerian exposure surface and several phases of drowning within the post-depositional evolution of this small carbonate platform. SEDIMENTOLOGICAL ANALYSIS OF THE NEOCOMIAN LIMESTONES FROM LESPEZI QUARRY (SOUTHERN BUCEGI MOUNTAINS) Victor BARBU1, Cristina E. PANAIOTU2, Cristian PANAIOTU2, 1 University of Bucharest, Faculty of Geology and Geophysics, e-mail: [email protected] 2 University of Bucharest, Paleomagnetism Laboratory, e-mail: [email protected] Keywords: calcimetry, rock-magnetism, Neocomian limestone, Lespezi quarry, Bucegi Mountains. Sedimentologic and rock-magnetic investigations have been done on 12 samples collected from Neocomian limestones in Lespezi quarry (southern part of the Bucegi Mts.). Sampling was systematically done from each bed for a total thickness of 3 m. Sedimentary structures and lithology changes were registered on a detailed log in the field. In the laboratory, we applied several specific techniques: optical petrography, calcimetry, rockmagnetic proprieties (κn – magnetic susceptibility, ARM – anhisteric remanent magnetization, IRM – isothermal remanent magnetization) to identify the variability of siliciclastic input versus carbonate accumulation. Total carbonate content (calcimetry) is an estimation of the planktonic productivity, while magnetic susceptibility may give information about fine grained clastic input and/or syndepositional bacterial activity. From these parameters which correlate very well each other, high resolution pattern of sedimentation can be identified and correlated with variation in climate and depositional environment. These deposits represent the cap of the Upper Jurassic tectonically drowned carbonate platform accumulated in a deep-water basin evolving in extensional regime. CONDIŢII DE FORMARE ŞI EXPLOATARE A ACUMULĂRILOR DE HIDROCARBURI PE STRUCTURA SÂNIOB, BAZINUL PANONIAN Mihai Valentin BATISTATU 6 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Universitatea Petrol-Gaze Ploieşti, Facultatea de Foraj, Catedra Geologie-Geofizică, B-dul Bucureşti nr. 39, Ploieşti, e-mail: [email protected]şti.ro Key words: well logs, model, acumulations, depositional enviroment. The upper Miocene of the Chişlaz – Sâniob zone is caracterized by the existence of some hydrocarbons bearing zone. The present paper tries to provide a model for these acumulations, to explain the existence of different zones with different productivity by means of depositional enviroment. These considerations are based mainly on the well logs production data corelated with geological features of the area. CONSIDERATIONS ON THE SPREAD OF PROBOSCIDIAN FOSSILS IN PRAHOVA COUNTY AND NEARBY AREA Victor BACARAN, Dumitru FRUNZESCU 283, Bvd. Republicii, bl. 3 B1, ap. 9, Ploiesti, 2000, Prahova University of Petroleum-Gas of Ploiesti, Faculty of Drilling, Geology-Geophysics Section 39, Bvd. Bucuresti, 2000, Ploiesti, Prahova e-mail: [email protected] Key words: proboscidian fossils, Prahova County, biometric measurements, distribution. The paper presents several fossil proboscidian fragments which have been recently found in Prahova County. Taking into account the biometric measurements, a species diagnosis was made and several considerations on the distribution of proboscidian fossil forms were made. STAGES OF THE GERMINATION PROCESS OF FOSSIL FUNGI SPORES. A CASE-HISTORY ON DOFTANA MOLASSE MIOCENE FROM DRAJNA SYNCLINE Victor BACARAN, Dumitru FRUNZESCU 283, Bvd. Republicii, bl. 3 B1, ap. 9, Ploiesti, 2000, Prahova University of Petroleum-Gas of Ploiesti, Faculty of Drilling, Geology-Geophysics Section 39, Bvd. Bucuresti, 2000, Ploiesti, Prahova e-mail: [email protected] Key words: Miocene, Doftana Molasse, fungi spores germination, conservation. The study of palinomorphes distribution from Doftana Molasse Miocene offers examples of fungi spores, which are found in different germination stages: from primordial stages of germination hifes to the stage of spores which are released by hifes. The different germination stages are constituted in premises of different degrees of conservation of fossil material. REACŢII METASOMATICE ŞI GENEZA SKARNELOR DIN VALEA LUI STAN (M-ţii Făgăraş) Alecsandru BĂRBULESCU, Dragoş POPESCU, Liliana POPA (anul III) Îndrumători: Lect. Dr. Ing.Gelu COSTIN, Asist. Peter LUFFI Lucrarea descrie pentru prima dată o ocurenţă de skarne asociate metamorfismului regional din versantul sudic al Munţilor Făgăraş (Valea lui Stan). Sunt prezentate mineralogia, stadiile paragenetice şi geneza posibilă a skarnelor precum şi a rocilor de tranziţie derivate prin reactii metasomatice. 7 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Mineralogia skarnelor este reprezentată de asociaţia calcit, granat (grossular 80- almandin 20 ), hedembergit, epidot, sfen, cuarţ. Iar în rocile de tranziţie au fost identificaţi amfiboli , plagioclazi relicţi (anortit 40), clorit magnezian în asociaţie cu talc alaturi de actinot, cuarţ, epidot şi sfen . Aceste minerale în rocile vecine skarnelor se asociază în benzi bi, tri sau poliminerale . Benzile de compoziţie diferită precum şi gradul de idiomorfism al mineralelor sugerează o zonalitate de tip metasomatic. Considerăm că geneza skarnelor şi a rocilor de tranziţie este legată de reacţii metasomatice pe un protolit gabbroic în prezenţa unei faze fluide cu compozitie variabilă locală (actiunea C02 >acţiunea H2O în skarne şi acţiunea C02 <acţiunea H2O pe masură ce ne depărtăm de skarne). Relaţiile de teren precum şi imaginile microscopice arată deformări intense ale asociaţiilor minerale pe zonele de tranziţie skarne – şisturi gazdă (gnaise oculare , gnaise plagioclazice, amfibolite). Această deformare ductilă intensă (în regim decrosant) asociată cu temperaturi relativ ridicate (cute ptigmatice în rocile gazdă) şi influxul de CO2 sugerează o geneză metasomatică a skarnelor în condiţii sincinematice, asociată probabil unei zone de forfecare profundă . Sursa CO2 ar putea fi asociată prezenţei unor “slice-uri” tectonice de natură corbonatică în profunzime (grupul de Făgăraş încălecat de grupul Cumpăna) . La adâncimi mari, carbonaţii din astfel de roci carbonatice , tectonic supraîncălzite , se pot disocia eliberând CO2. Fluidul metasomatic astfel produs localizează strainul generând o zonă de forfecare de-a lungul căreia CO2 alături de H2O poate migra ascendent , producând pe parcurs reacţii metasomatice ca cele descrise în lucrarea de faţă. GEOMAGNETIC EXPRESSION OF AN ANCIENT PLATE BOUNDARY SOUTHERN SOUTH CARPATHIANS, ROMANIA. TRANS-GETICA FAULT Lucian BEŞUŢIU Institute for Geodynamics of the Romanian Academy, Solid Earth Dynamics Department 70201 Bucharest, 19-21 Jean Louis Calderon Str., sector 2, e-mail: [email protected] Key words: geomagnetic map, complex interpretation, crustal fault, plate tectonics, South Carpathians, Moesian Plate The reconstruction of the national ground geomagnetic map of Romania, after removing the secular variation effect, provided the opportunity to take into consideration and appropriate interpreting some previously hidden or distorted large-scale peculiarities of the vertical component geomagnetic anomaly. By appropriate filtering the newly achieved images, a large discordance in the geomagnetic anomaly pattern southern South Carpathians occurred. It was associated to the presence of a large-scale discontinuity affecting the crust at least down to the crystalline basement. It has been named Trans-Getica Fault (TGF) and seems to be the northern boundary of the Moesian microplate (MoP), playing a major role in the tectonics of the area. Additional information provided by magnetotelluric soundings (MTS) and deep seismic soundings (DSS) data on the western sector evidenced for its trans-crustal features. Actually, the trans-crustal Tg. Jiu-Călimăneşti fault (Visarion et al, 1994) appears as the western segment of TGF. Divergent Wiese vectors (Soare, 1989) along the geomagnetic revealed fault path mark the presence of a high electrical conductive element in the lower crust, which seems to correspond to the contact between MoP and the IntraAlpine microplate (IaP). Normal seismicity recorded along TGF advocate for both its deep and actual active nature. The contact area can be easily followed eastward up to a meridian where it seems to met another major geotectonic discontinuity, Peceneaga-Camena fault (PCF). Active seismicity along its track fully supports the idea of a plate contact. Several evidence, such as the geomagnetic pattern within the neighboring compartments, and the repartition of the regional stress within MoP, as inferred from the analysis of the normal earthquake mechanism (Zugrăvescu and Polonic, 1997), advocate for its transform features. 8 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai It is very hard to interpret the TGF age. Taking into account the almost unfolded Palaeozoic deposits within South Carpathians, except for their westernmost bending segment (Pavelescu and Niţu, 1977), it is likely that in a primary geodynamic stage, probably during the Late PalaeozoicEarly Triassic, an important block of East European Plate was shifted westward along TGF. Thereafter, it acted by distorting the shape of the Carpathians geosyncline, and tightly folding Palaeozoic deposits located in front of it. Similarities between the basement of the Walachian sector of the Moesian Platform (with Archaean granite to diorite rocks, and Lower Triassic large volumes of basic effusives), and the basement of the SW margin of East European Platform, as revealed by deep drillings support the idea. Consequently, it seems that Tornquist-Teisseyre Zone was broken somewhere in the Vrancea active seismic area, and shifted westward hundreds of kilometers, in the Serb Banat area. Europe gravity images seem to support the idea. Present active dynamics along TGF are evidenced by intense normal seismicity and stress distribution within South Carpathians area. Selected references: Pavelescu, L., Niţu, Gh. (1977) Le probléme de l’Arc Carpato-Balcanique; An. Univ. Bucuresti, Geologie, An. XXIV, 19-35 Soare, A. (1989) Preliminary results of some tectonomagnetic researches at the Surlari Geophysical Observatory; Rev. roum. géol. géophys. géogr., Géophys., 33, 43-47 Visarion, M., Stănică, D., Stănică, M.(1984) Deep-structure of the region between the Motru valley and Argeş valley, Romania, as shown by the results of geophysical surveys; Acta Geodaet., Geophys. et Montanist. Hung. Volume 19,1-2, 173-184 Zugrăvescu, D., Polonic, G. (1997) Geodynamic compartments and present-day stress state on the Romanian territory; Rev. Roum. Géophys., 41, 3-24 MIGRATION OF THE VRANCEA INTERMEDIATE-DEPTH SEISMICITY: REALITY OR MATHEMATICAL FICTION? Lucian BEŞUŢIU and Nicoleta CADICHEANU Institute for Geodynamics “Sabba S. Ştefănescu” of the Romanian Academy, Solid Earth Dynamics Department RO-70201 Bucharest 37, 19-21, Jean Louis Calderon Str., sector 2, e-mail: [email protected] Key words: intermediate-depth seismicity, geodynamics, space-time migration General considerations Vrancea intermediate-depth seismicity stands for a long time as a challenge to geoscientists all over the world. Many efforts have been made during the years to decipher the strange mechanism generating strong intermediate-depth earthquakes in a rather confined area located in the East Carpathians bending region. The special geometry of the epicentral zone, with its strong NE-SW elongation suggested to some authors the presence of a rectangular fragment of an assumed sinking slab in the area. Paper aim Unlike previous works, the present paper is intended to demonstrate, based on a statistical analysis of the seismic event occurrence, that the elongated shape of the epicenter region is at least partly due to a space-time migration of the intermediate-depth seismicity developed within a smaller, more isometric active seismic zone moving towards SW. Data The statistics has been performed on a data set provided by the ROMPLUS catalogue (Oncescu et al, 1998), which has been completed with more recent events as provided by the website of the National Institute for Earth Physics. The time span after the major event of November 1940 was considered. To study the intermediate-depth seismicity, earthquake hypocenters located beneath 60 km depth were considered only. Besides, several deep events located far outside 9 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Vrancea geotectonic area were also excluded. All in all, more than 2100 seismic events were taken into consideration, which represent, in our opinion, a significant statistical database. The approach Basic idea in developing the carried out research was that an eventual migration of the seismic activity should be the result of two components: (i) a random occurrence of the earthquakes within an inhomogeneous seismic body, and (ii) a systematic (deterministic) trend generated by an assumed displacement of sub-crustal masses under the influence of convective currents in the upper mantle. To avoid, or at least to attenuate the stochastic component, seismic activity within Vrancea area was integrated along time intervals between major seismic events (of distinct moment magnitude): 1940 (Mw = 7.7), 1977 (Mw = 7.4), 1986 (Mw=7.1), and 1990 (Mw = 6.9). Among them, several sub-intervals, related to the solar activity cycle were inserted, where the case. Both simple and weighted averages have been used for determining the centers of the seismic activity within each interval. Main results By performing the above-mentioned analysis an obvious migration of the intermediate-depth seismicity in the Vrancea area was pointed out. Generally, the seismic activity seems to move SW, by gently dipping, except for the moment around the major earthquake of March 4, 1977, when the trend reversed. Unlike previous and following intervals, during the 1970-1977 the seismic activity center fallen down at about 140 km depth, to come back on the trend within 1977-1986 interval. After the 1977 catastrophic earthquake, the westward displacement was also reversed, the seismic activity moving eastward during the next interval. Selected references Oncescu, M.C., Mârza, V.I., Rizescu, M., Popa, M., 1998. The Romanian earthquake catalogue between 984-1997: In Vrancea Earthquakes: Tectonics, Hazard and Risk Mitigation. Wenzel, F., Lungu, D. (Editors) and Novak, O. (co-Editor)). Kluwer Acad. Publ., Dordrecht/Boston/London, 43-48 ASPECTE PRIVIND INFLUENŢA METODELOR EOR ASUPRA ROCILOR COLECTOARE Gheorghe Adrian BRĂNOIU Universitatea Petrol-Gaze Ploieşti, Facultatea de Forajul Sondelor şi Exploatarea Zăcămintelor, Catedra Geologie-Geofizică, B-dul Bucureşti nr. 39 KEY WORDS: EOR methods. Mineralogical changes. Modified physical properties of rocks. The purpose of this paper is to analyse the some aspects of the influence of EOR (Enhanced Oil Recovery) methods on reservoir rocks. Getting to know this influence which consists in mineralogical changes, the modification of the physical properties of rocks (porosity, permeability) is useful in reservoir engineering helping in choosing the most efficient EOR methods. CATEVA DATE NOI ASUPRA CALCARELOR DE LA POIANA AIUDULUI Ioan I. BUCUR, Emanoil SÃSÃRAN, Endre PAP. Universitatea Babeş-Bolyai, Departamentul de Geologie-paleontologie, Str. M. Kogălniceanu nr.1, 3400 Cl;uj-Napoca. E-mail: [email protected] Cariera de calcar de la Poiana Aiudului este deschisă în versantul sud-vestic al Dealului Mare, într-un olistolit de dimensiuni considerabile, prins în depozitele terigene ale flişului cretacic superior ce aflorează atât în baza căt şi în partea superioară a succesiunii calcaroase. Grosimea 10 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai totală a calcarului depăşeşte 125 m, fiind însă greu de făcut o estimare foarte exactă datorită faptului că nu se poate urmări un profil continuu pe întreaga deschidere. Analiza secţiunilor subţiri efectuate prin eşantioanele recoltate a pus în evidentţă o gamă largă de microfaciesuri, de la bioclastite de pantă a platformei carbonatice până la calcare fenestrale şi laminite intertidale. Au fost recunoscute de asemenea suprafeţe de discontinuitate marcate de fenomene de carstificare. Asociaţiile micropaleontologice determinate au pus în evidenţă două pachete distincte ca vârstă: unul Berriasian?-Valanginian (în partea inferioară a succesiunii) şi altul Barremian-Apţian inferior (în partea superioară). Limita dintre cele două pachete nu a putut fi practic observată în teren. Calcarele berriasian?-valanginiene conţin o asociaţie cu : Actinoporella podolica, Salpingoporella annulata, Salpingoporella pygmaea, Salpingoporella circassa, Seliporella neocomiensis, Andersenolina alpina, Andersenolina aff. elongata, Protopeneroplis banatica, Haplophragmoides joukowskyi şi Meandrospira favrei. Asociaţia din calcarele barremian-apţiene cuprinde: Neomeris cretacea, Triploporella cf. marsicana, “Coptocampylodon” fontis, Palorbitolina ? sp. şi Paleodictyoconus arabicus. Din această asociaţie se remarcă prezenţa orbitolinidului Paleodictyoconus arabicus, întâlnit cel mai frecvent în depozite situate la limita Barremian-Apţian. Dacă vârsta valanginiană a calcarelor de la Poiana Aiudului era deja de mult cunoscută (e.g. BEDELEAN, 1966), prezenţa depozitelor Barremian-Apţiene în partea superioară a succesiunii deschise în carieră reprezintă o noutate notabilă. SECVENŢE EVAPORITICE ÎN MOLASA MIOCENĂ A CARPAŢILOR ORIENTALI DE CURBURĂ – SEMNIFICAŢII PALEOAMBIENTALE Marius BULBUC (anul IV), Răzvan ARGHIR (anul II), Dragoş PORUMB (anul II) Centrul de Sedimentologie, Universitatea din Bucureşti/ Facultatea de Geologie şi Geofizică Îndrumător: Lector Dr. Marius POPA Prezentul studiu este o abordare sedimentologică preliminară asupra secvenţelor evaporitice "molasice" miocene ale Carpaţilor Orientali (zona de curbură), ce aflorează în lungul profilelor deschise de V. Teleajen şi Prahova, în scopul reconstituirii mediilor de sedimentare specifice. Metodologic, analiza sedimentologică efectuată a urmărit identificarea faciesurilor evaporitice (sulfatice) în succesiune litologică (ca tip petrografic; morfologii şi microstructuri specifice; structuri depoziţionale/ postdepoziţionale, definitorii si asociate) şi caracterizarea secvenţelor evaporitice (petrografic; succesiuni; limite). În secţiunile stratigrafice analizate au fost determinate 14 faciesuri evaporitice sulfatice, depoziţionale şi postdepoziţionale, asociate în secvenţe de două ordine de mărime. Din punct de vedere depoziţional, microsecvenţele separate (mm- cm în grosime) constituie de fapt microritmuri rezultate în urma unor variaţii ciclice, pe termen scurt, ale gradului de salinitate (ex. gips- argilă/ marnă, gips- mat cianobacterial) şi/ sau al tipului sedimentării (ex. gips clastic- marnă/ argilă). Asocierea acestora defineşte mai multe tipuri de mezosecvenţe – în grosimi dm- m – care au fost încadrate ambiental. Astfel, pe baza faciesurilor diagnostic, a tranziţiilor în succesiune şi a caracterului suprafeţelor de discontinuitate (interne şi limită), mezosecvenţele analizate sugerează depuneri în ambianţe marine costiere şi adiacente, reprezentate în principal de plaje evaporitice ("coastal sabkha"), lagune saline ("lagoon"), lacuri/ bazinete marginale sărate ("saline pan") şi ambianţe litorale. Controlul acestor mezosecvenţe a fost în principal climatic, dar şi tectonic (fapt demonstrat de prezenţa în anumite secvenţe a unor parabrecii sulfatice de resedimentare gravitaţională şi a structurilor de injecţie hidroplastică). Procesele diagenetice (postdepoziţionale) au avut un rol important în modificarea trăsăturilor faciale primare. 11 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai MAGMATITELE ACIDE ŞI SKARNELE ASOCIATE DIN CRISTALINUL MUNŢILOR SEBEŞ: MINERALOGIE ŞI PETROGENEZĂ Mihai CIOCÎRDEL (masterand) Îndrumători: Lect. Dr. Gelu COSTIN, Prof. Dr. Marin ŞECLĂMAN Magmatite acide, porfirice, afanitice, holocristaline (de compoziţie granodioritică) aflorează sub formă de corpuri miciţ izolate în cristalinul M-ţilor Sebeş. Lucrarea prezintă mineralogia corpurilor granodioritice, succesiunea de cristalizare magmatică precum şi evoluţia compoziţiei topiturii ca urmare a cristalizării şi contaminării magmatice. Sunt de asemenea prezentate şi skarnele asociate genetic acestor corpuri. Distribuţia areală relativ liniamentară a corpurilor magmatice (asociate spaţial cu zona de forfecare Răşinari – Stelea, 1996) precum şi lipsa deformărilor ductile penetrative, sugerează o origine post- sau tarde-colizională a acestor magmatite. Geneza magmelor granodioritice o considerăm a fi legată de o anatexie parţială a crustei continentale asociată formării zonei de forfecare Răşinari (Cărpiniş-Căpâlna) în regim decroşant. Magmele astfel generate au putut asimila diferite tipuri de şisturi cristaline, modificându-şi chimismul şi succesiunea de cristalizare. Mineralogia skarnelor, relaţiile de teren, şi prezenţa unor zonalităţi de tip metasomatic arată că skarnele se formează prin reacţii metasomatice în prezenţa unor volatile bogate în CO2. AN ACTIVE LANDSLIDE INVESTIGATION CASE STUDY: EASTERN CARPATHIAN MOUNTAINS, ROMANIA Horatiu V. CORBEANU1, Tom H. BRIKOWSKI2, Carlos V. AIKEN2 1 - SC COGES GRUP SRL - Campina, 2150, Prahova, Romania, [email protected] - Geosciences Department, University of Texas at Dallas, Richardson, 75083, USA 2 Keywords: landslide, failure mechanisms, GPS, VES, Romania The areal density of destructive landslides in the oilfields of the Eastern Carpathian Mountains is one of the highest in Romania. Detailed study of one rainfall-triggered landslide reveals a complex kinematic history. A variety of investigative tools were used to evaluate this history and determine the landslide characteristics. Detailed global-positioning surveys (GPS) of landslide movement uncovered the mechanisms of deformation, and demonstrated the relationships between the triggering factors and the dynamics of the movement. Geotechnical and vertical electrical sounding investigations were carried out to determine the quantitative stability conditions of the slope and the geometry of the failure surface. All this information was combined to generate a failure-prediction model, which can be used to define prevention measures for the mitigation of slide effects, and reduce the loss of human lives and assets. The model illustrates the complex process leading to recurrent landsliding at the site. The upper part of the landslide moves and loads continuously onto the lower part, which in turn fails critically and episodically. The landslide, characterized mostly as a translation slide, presents multiple failure surfaces at depths 2, 8 and 13 m. The whole landslide developed in four stages: accumulation of colluvial deposits at the upper part, creep sliding, rotational failure at the lower part, and finally massive translational failure. Analysis of this slide and development of a failure model required application and integration of a diverse set of methods (GPS, boreholes and geophysical methods). Complete analysis of most active landslides can be expected to require a similarly diverse approach. 12 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai AN ATTEMPT TO USE THE OLIGOCENE-LOWERMOST MIOCENE ICHTHYOFAUNA (TELEOSTEI) IN THE RECONSTRUCTION OF SOME ANCIENT ENVIRONMENTS FACTORS FROM EASTERN CARPATHIANS FLYSCH ZONE (CENTRAL-SOUTH AREA) Paul CONSTANTIN Geological Institute of Romania, 1 Caransebes street, 78344 Bucharest; E-mail: [email protected] Key words: ichthyofauna, Teleostei, Oligocene, Lowermost Miocene, Eastern Carpathians, paleoenvironment factors, mass mortality. In the lack of other groups of organisms, classical for paleoecological reconstructions, the study of fossil fishes has been possible as an alternative in order to determine some paleoenvironment factors. Thus, an example can be offered by the rich Oligocene - Lowermost Miocene ichthyofauna, which has been known for a long time from the formations developed in the bituminous facies in the carpathic flysch area, generally lacking other fossil organisms. The above mentioned ichthyofauna represented the goal of our latest studies in the Central and South area of the Eastern Carpathians. The fossil fish-fauna (71 teleostean species belonging to 39 genera and 30 families) which has been revealed so far due to the field research, completed with museal collections investigation or published data examination, was generally provided by fine pelitic, bituminous shales, laminitic limestones or bituminous marls, found on different stratigraphic levels in the Oligocene - Lowermost Miocene, being predominant in its lower part (Rupelian) among all the 34 localities indentified in our studies. The bearing fossil fish-fauna formations belong as well to all the Oligocene - Lowermost Miocene lithofacies known in the Romanian Eastern Carpathians: Valea Caselor Facies (Inner Bituminous Facies), Fusaru-Pucioasa Facies, Slon Facies, Mixed Facies, and Bituminous Facies with Kliwa Sandstone (Outer Bituminous Facies). In order to use the fossil fish-fauna to establish some paleoecological factors, the fosiliferous material nature was taken into account. The taphonomic aspects showed that the ichthyofauna was generally represented by "in situ" specimens, preserved under favourable fossilization conditions (anaerobic environment, lack of streams, very fine sedimentary material, etc.). Only for the ichthyofauna borne in the formations belonging to the Valea Caselor lithofacies, the mass mortality could be recognized, due to some catastrophic conditions (changes in the depth where H2S was borne, under some temperature and pression conditions) As fishes are mainly nectonic organisms, characterized by a great mobility, the whole association was taken into account, as much as possible, in the interpretation of the environment significance, trying to detect the predominant (autochtonous) species from those which were accidentally present in the association, due to the migrations. Comparing the fossil ichthyofauna with the Recent one (taking into account the limits imposed by this approach) or using the fossil species morpho-functional studies, a paleotemperature reconstruction was tried (subtropical climate for Rupelian, with a possible cooling during Lowermost Miocene), a paleosalinity one (marine basin, with normal salinity during Rupelian, but with possible brackish waters during Lowermost Miocene, at least in areas closely to the shore, within perilitoral basins, temporary closed), and the sedimentation basin paleobathymetry as well, basin corresponding to the Oligocene -Lowermost Miocene formations from the South of the Trotus Valley (the sedimentation basin reached different depths, according to the place and the period analysed). 13 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai ULTRASTRUCTURE AND CHEMISTRY OF ZOOPHYCOS PELETS MASSALONGO 1855 (PRELIMINARY CONSIDERATIONS) Constantin COSTEA*, Titus BRUSTUR** * Institutul Geologic al României, str. Caransebes 1, 78344, Bucuresti 32 ** Institutul National de Geologie si Geoecologie Marinã, str. D. Onciul 23-25, P.O. Box 34-51, Bucuresti Zoophycos ichnogenus represents an interesting biogenic sedimentary structure. Its origin is still controversial. The simple to complex “spreite” type morphology is the result of a detritus– feeding vermiform organism living in transitional sublittoral–bathial marine areas. We present some preliminary data on the Zoophycos pelets ultrastructure and chemistry in the Hangu Formation from the Bucovina Eastern Carpathians Outer Flysch. MINERALOGICAL AND MICROSTRUCTURAL PROPERTIES OF KLIWA SANDSTONE FROM THE CORNER OF THE EAST CARPATHIANS – ON THE ROLE FOR A RESERVOIR QUALITY Eduard V. DRĂGAN, Nicolae ANASTASIU, Lidia NUTU Bucharest University, Faculty of Geology and Geophysics Keyword: East Carpathian, Kliwa sandstone, diagenesis, cathodoluminescence, UV fluorescence, reservoir quality One of the famous reservoir in the Carpathians, Kliwa Sandstone (Oligocene –early Miocene age) was documented, using raffined technics (textural analysis, optical microscopy, cathodoluminescence, UV fluorescence) in mineralogical and microstructural aspects of grains and intergrains framework, on the samples both from wells (5003500m depth) and outcrops. Quartz, the main component of arenites, is monocrystalline (80-85%), or polycrystalline. Quartz is present also as detrital grains (<10-20 microns) concentrated in lens and laminaes in interbeded dysodilic shales and slates. Others component are feldspars, ortoclase, microcline and plagioclase, rock fragments, dominantly wackes, micrograywackes, phyllites, mud clasts. Micas are represented by muscovite and biotite, and heavy minerals common are epidote zircon, apatite, ilmenite, magnetite, rutile, tourmaline, sillimanite, monazite, sphene. Glauconite is pelletes and, less common authigen. Skeletal fragments are, generally, bioclasts of radiloari, sponge spicules, foraminiferas. Optical porosity show a mean value of 6%, with a maximum of 25% in the Runcu site. The compaction was active in the whole sedimantary sequence; in this reason microfaults are very common, also ductile deffects. Deformed mica grains in thin sections observations evidence mechanical compaction and physical readjustment to the overburden load in the sandstones. Floating grains is very common, other type of grain contacts are long, point, concav-convex. Sutured contacts and pressure solutions are very rare. Particularly, in some samples floating grains are the result of corrosion of detrital grain and modification of textural parameters by cementing. Diagenetic silica is a very common mineral phase. Porosity leaves an open system, and following compaction, diagenetic modifications are mainly related to changes in the pore-water chemistry. Large existence of the metastabile silica cement, amorphous silica and calcedony, suggest that cement does not precipitate for kinetic reasons. Quartz overgrowths are not common, and some samples show evidence of reworking quartz grain with overgrowths. Secundary porosity (up to 10% in some cases) developed in depth over 2500m was caused by a large chemical activtiy of pore fluids. Replacement processes were responsible for dissolution and leaching of feldspar grains, precipitation of calcite as mosaic cement, disintegration of unstable ferromagnesian minerals, release of iron oxides and formating of infiltrated clay in the interparticle pore spaces. Reservoir quality of the analysed interval is medium, due by secundary porosity as a result of partial clast dissolution and microfaulting processes. Microfaults, in our case, have a dual role: as high permeability pathways and as seals (constrain fluid flow and generate permeability barriers). However, partially, microfaults developed are later by oil emplacement. Argilaceous minerals, as matrix, is a negativ factor during production process. 14 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai DEEP GEOTECTONICS OF THE NORTHWESTERN BLACK SEA CONTINENTAL MARGIN BY GRAVITY AND MAGNETIC DATA Radu G. DIMITRIU GeoEcoMar, 23-25, Dimitrie Onciu Street, 70318 Bucharest, Romania, [email protected] The northwestern continental margin of the Black Sea basin consists of the following main geotectonic units: the Scythian Platform (SP), the North Dobrogea Orogen (NDO) and the dobrogean sector of the Moesian Platform (MP), separated by crustal-scale faults. These major geotectonic units both extend onshore and offshore, where they are dipping and concealed by the Albian to Quaternary sediments of the Black Sea basin. All gravity and magnetic data available both onshore and offshore have been re-processed in order to obtain the gravity and magnetic anomalies maps of the Romanian sector of the western Black Sea continental margin and integrated with information resulted from newest geological investigation and seismic prospecting. Geological interpretation of geophysical data suggests a shear-type model for the western Black Sea continental margin, developed through: (a) rifting processes, initiated in the Early Cretaceous on a quasi-normal direction compared to the nowadays margin and developed until the end of the Cretaceous or Paleocene; (b) southward migration of the rift axis and development of a N-S trending active transform boundary and (c) formation of a passive margin along an inactive fracture zone that separates continental from oceanic crust. The first consequence of the described process and one major feature of the shear margin is the presence of a relatively narrow transition sector. This transition sector is 50 to 80 km wide and separates the continental and oceanic crust, along which the thickness of the consolidated crust decreases from 30-35 km to only 5-12 km. This process is partly compensated offshore by the important thickening of the Black Sea sedimentary cover to values exceeding 10-12 km. A greater continental crust thickness, exceeding 40-45 km, appears in the onshore sector of the NDO and SP. The large, vertical displacements occurring along Peceneaga-Camena Fault (2-3 km offshore to 8-10 km onshore), affecting both Conrad and Moho discontinuities, prove its crustal scale. Some of the main geotectonic features of the continental margin, pointed out by geophysical data interpretation and modeling performed, are as follow: [1] Two half-grabens and three subbasins, whose infill is represented by bimodal volcanics and continental clastics, resulted during Late Permian-Early Triassic rifting, have been recognized within the SP; [2] The relativelly shallow emplacement of several intrusives within the crystalline basement and Paleozoic deposits of the SP has been pointed out; [3] Several tectono-magmatic alignments, showing different ages and structural significance, have been recognized within the sector corresponding to NDO. Calcalkaline Hercynian intrusives outcropping onshore in the northwestern Dobrogea lie at 3-5 km depth in the littoral area and at 8-10 km further seaward; [4] The tectonic block bordered by the Sf. Gheorghe and Văcăreni-Agighiol Faults, mainly consisting of turbiditic and pelagic Early Paleozoic sediments, devoid of calc-alkaline magmatites, represents a remnant of the accretionary wedge formed during the South directed Late Paleozoic subduction of the Rheic oceanic crust; [5] A limited side extension and oblique trend of the former Early Triassic intracontinental rift axis, have been observed in the central part of NDO; [6] Late Jurassic effusive rocks occur both onshore and offshore in the footwall of the Peceneaga-Camena Fault; [7] A great structural importance for the regional architecture of the moesian crystalline basement have been played, both within the continental and marine domains, by the oldest (Neo-Proterozoic) tectonic element of Dobrogea which is the Palazu overthrust line; [8] A major structural significance also play the highly magnetized metamorphic rocks of Palazu Group, which act as a genuine magnetic marker for the whole Moesian realm; [9] The presence of two main fault systems in the investigated area is obvious: the older, Paleozoic to Cretaceous fault system, gathers mainly NW-SE trending faults 15 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai (e.g. Sf. Gheorghe, Peceneaga-Camena, Capidava-Ovidiu, Intramoesian, etc.), which are both normal and reverse; the younger, NE-SW trending fault system, includes normal and strike-slip faults (e.g. Constanţa-Dunavăţ, Lacu Roşu, West Midia, etc.). The most important structures resulted from the interaction between these two fault systems are: Sărata-Tuzla and Sulina Grabens, separated by the Chilia-Snakes Island High in the SP, the Histria Depression on the NDO offshore, between the Sacalin and the Central Highs, the Corbu, Constanţa and Delfin Depressions, separated by Constanţa Horst and the uplifted Midia Block on the Moesian offshore; [10] During syn- and post-rift times, a major structural significance was played by the marginal ridge, that includes the Central and Midia Blocks on the Romanian offshore, as well as the Tulenovo and Nanevo Blocks on the Bulgarian offshore. SOME QUESTIONS REGARDING THE GEOTECTONIC STRUCTURE OF THE SOUTH APUSENI MOUNTAINS (ROMANIA) Dorin Gheorghe DORDEA, Viorel SPRANCEANA Prospectiuni S.A., 1 Caransebes st., 78.344-Bucharest, Romania, Phone: +401-224.18.85, Fax: +401-224 35 56, E-mail: [email protected] Key words: South Apuseni Mountains, Midd Ocean Ridge Basalts -ophiolites, Island Arc Volcanics, nappe structure, suture slide structure The Mesozoic igneous rocks of South Apuseni Mountain (SAM) are composed by J – K1 Ntype Midd Ocean Ridge Basalts (MORB) sequences of ultramafic-mafic isotropic cumulates of gabbros and diorites / sheeted dykes / pillow lava forming an ophiolitic complex and volcanic island arc rocks (IAV) of J3 and K1 age. The geologic setting of SAM is completed by a variety of J - K sedimentary deposits which compose, together with the Mesozoic magmatic suites, the nappe structure. Different interpretations of this nappe structure have been advanced. A lot of unclear issues still persist on nappe postulate because: - There is no detailed mapping to discriminate MORB, IAV and the Mesozoic sedimentary deposits (generally covered with soil and vegetation); - No systematical detailed photogeological mapping was performed untill now; - Widespread ophiolitic tectonic breccias occurring within Capalnas-Techereu unit has been considered cartographically as “pyroclasics”; - Breccias-type of the limestone olistolithes is entirely ignored; - The olistolith elongation and straight alignement of few kilometers, despite the narrow width, of hundreds of meters, is also ignored; - The obvious recurrence of some discordant stratigraphic successions (the Fenes unit) are interpreted as successive faulting; - The presence of crystalline rocks in the ophiolitic Capalnas-Techereu unit still remains exotic, unaccountable in a unitary remnant of ocean floor crust. The photogeological interpretation reveals the development of some long, imbricate slides on the entire Transilvanides area. The slides are formed exclusively of Mesozoic rocks. Successive slides of ophiolites, limestone and flysch rocks, as well as successive ophiolitic and island arc volcanic rocks may develop. Only the thickness of the limestone slides may exceed 200-300 m. Within the ophiolitic slides, the typical succession of an ophiolitic complex (peridotite/gabbro/sheeted dikes/pillow lava) cannot be distinguished, though the specific ophiolitic types have been randomly described all over the Transilvanide area. However, the basaltic pillowlavas prevail, though frequently transformed into tectonic breccias. Both the carbonatic and the carbonatic - ophiolitic “olistolithes” develop linearly as continuous or discontinuous slides. Within the alignments of regional maximum gravity, associated mainly to the ophiolitic piles, the subsequent detailed measurements (upon the Valisoara – Luncoiul de Jos area) have revealed a succession of gravity maximum and minimum relative parallel to the main direction (WSW - ENE) of the ophiolites. The relative gravity minimum may be associated either to the 16 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai presence of IAV, or to sedimentary rocks. This alternation is better reflected by the horizontal gravity gradient (detailed), which suggests a possible suture slides structure. The entire SAM area represents a suture mélange formed by slides of oceanic crust (equally composed by MORB, IAV and sedimentary rocks), which randomly solders to the continental margins. The design of the majority of the nappes forehead, represented cartographically, may constitute a structural local reality, but the real nature of the nappes, as a whole, represents in fact, a recurrence in an uncountable number of such slides. A DETAILED MAGNETOTELLURIC SURVEY FOR DEEP GAS STRUCTURE FRASIN, ROMANIA C.DAVID1, G.IOAN1, L.IONESCU2, Beatrice LACATUSU2 1 S.C.Prospectiuni S.A.,Bucharest, 2ROMGAZ,Medias, Romania Even the seismic in the external flysch zone of the Eastern Carpathians is the main geophysical method used for oil and gas exploration, due to increased costs in areas with complex geological structures (such as flysch zone) and rough topography, non-seismic methods were applied in order to retrieve the deep structures. The V5-2000 MT satellite synchronized system (Phoenix-Geophysics, Canada) working in remote reference mode was used to collect data in an area of Frasin gas accumulations, northern Romania (see fig.1). More than 250 MT soundings were recorded in an almost regular net (0.25x0.25 km) covering about 12km2 area. Two-dimensional inversion of the transverse magnetic (TM) data along 20 lines allowed to point out the major geological structure, characterized by the presence of NNW to SSE up lifted block situated in the basement of the flysch nappes, at depths exceeding 4000m. This structure is governed by the existence of the complex system of faults, directional and senestral strike-slip faults at the level under thrust platform. The study area is situated near Moldova Valley, in the external flysch zone of the Eastern Carpathians. Lithological units present in the area belong to Moldavides (Tarcau, Marginal Folds and Subcarpathian Nappes). From east to west they comprise the following units: a) Subcarpathian unit is mainly made up of Lower and Middle Miocene, mostly molassic sediments; in this area occur two subunits, Valea Mare and Pietricica. b) The Marginal Folds, detached from their substratum in the Cretaceous black shale level, usually form two or three superimposed duplexes. They have been thoroughly investigated by exploration wells, and their Oligocene sandstone reservoirs (Kliwa sandstone) have constituted the main objective of Carpathian petroleum exploration since its early days. c) The Tarcau Nappe, which has entirely overthrust the Marginal Folds and locally directly overlies the Subcarpathian domain, still comprise both Cretaceous and Paleogene flysch sequences; in this area three subunits occur: Vama, Frasin-Tazlau and Voronet The MT survey was conducted for studying its possibility to outline deep buried structures beneath the flysch units, at depth exceeding 4000m. Several wells in Frasin area are productive but there are also several with bad results. The feasibility of MT method is based upon the resistivity contrasts between different geological formations of the flysch units. These contrasts came as a result of thorough examination of numerous resistivity well logs. Lithological units of Moldavidian Nappes may have different properties. For instance, low resistivity values are typical for Black Shales Formation (Lower Cretaceous) or for salt formation (lower Miocene). On contrary, high values of resistivity are characteristic for sandy or calcareous flysch deposits. A very strong contrast appears between sedimentary cover and the crystalline basement of the platform. 17 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Data processing was performed using Phoenix programs. The data analysis, 1D interpretation and 2D inversion were made using Winglink software. The results show that the impedance strike direction is N to N200 and it remains about the same from the lower to the highest frequencies. Some significant distortions of sounding curves, at high frequencies, appear in the middle part of the delimited area where two directional faults determine outcrops of formations with high contrast of resistivity. 2D inversion model shows three elements: a) crystalline basement, at depth exceeding 5000m, with an up-lifted zone in the central part of the section; this one represents a very important structure which is explored for gas accumulations; b) platform cover, including Paleozoic up to Badenian deposits, having the same trend as the basement; a high resistivity contrast is reflected between Badenian Formation (few hundred meters thick, consisting in anhydrite and sandstone able to be reservoirs) and formation and the Neogene upper deposits; c) flysch deposits, characterized by a very complicate structure and a lot of contrasts but suggesting eastward overthrust of the units. GEOLOGICAL EVOLUTION OF THE SOUTH-WESTERN PART OF THE MOESIAN PLATFORM DURING THE PLIOCENE-QUATERNARY TIME Petru ENCIU 1, Mariana ENCIU 2 1. Institute of Geography, Romanian Academy, e-mail: [email protected] 2. INCERTRANS Research Institute, e-mail: [email protected] Key words: river-dominated delta, braided river system, Pliocene, Pleistocene In the Late Miocene (Pontian), the under-Carpathians slipping of the western panel of the Moesian Plate was roughly stopped. Subsequently, the slow descending motion of the Vanju Mare – Prunisor, Lom-Bailesti-Filiasi and Giurgita-Valea Stanciului buried Depressions, and the prevalently upward movement of the inserted Strehaia-Calafat, Balsi-Leu-Teasc and Gura Vaii Jiului Uplifts, are the driving force for the filling process of the south-western corner of the Central Paratethys (Dacian Basin). As result of the general cooling (around of 5.5 million years BP) the level of the Central Paratethys decreased and the Danube river-dominated delta plane extended in the Turnu Severin – Vanju Mare – Prunisor portion, 160 m thick of sandy pile. (Enciu, 1995) In the Bailesti sector (150 m thick of sandy distributary Lom channel) and in the Macesu de Jos area (110 m thickness of sandy littoral sheet), the Berbesti formation developed, too. On the main Lom-Bailesti-Filiasi and Gura Vaii Jiului Uplifts, the mixted lacustrine-river dominated delta plain environments are partially kept up (25-40 thick of sands, the Berbesti formation, Lower Dacian in age). Then, during the Upper Dacian- Middle Romanian, the constructive deltaic phase was succeeded by the upper delta plain and flood plain phases (the JiuMotru Formation). Its lower part consists of several distributaries-fill in the main mud-filled area (0-115 sequences with sands, silts, clays, gleic paleosoils or 2-9 coal seams). The middle and upper part of the Jiu-Motru formation preserved ca 0-125 m of river channels multistoried infill, interstratified with compacting fine-grained rocks. Generally, from the western and south edges of the Dacian Basin to the axis (FiliasiTurceni-Bibesti line), during the Middle Romanian substage, the Jiu-Motru formation passed from proximal braided river stage, including alluvial fans (Poroina Mare, Caraula, Maracinele, Podari etc.) to the meandering river stage. In the Upper Romanian – first part of the Lower Pleistocene, as result of the progressive cooling of the climate, of the uplift of the Carpathians Realm, the feeding with alluvia and fresh 18 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai water of the westernmost part of the Dacian Basin was intensified. In the present Serbia-Romania territory, the Danube built the Alluvial Fan (Lower Member of the Danube Formation, Enciu, 1998). On the southern edge of the Getic Piedmont, an increasing W-E elongated strip (5-20 km wide, over 75 km long) representing the lateral north edge of the Lower Member, preserves. The axial part of the Lower Member of the Danube formation was self-evacuated in the Middle-Upper Pleistocene (when it deposited the frontal load in the north-easternmost part of the Dacic Basin). Starting with the second part of the Lower Pleistocene, the Danube cut the actual profile of the valley. As a result, the higher relief of the Oltenia Plain, ensured repeated down-cutting of the stairway-like seven terraces sequence and the actual alluvia of the meadow (the Upper Member of the Danube Formation). FLUID INCLUSIONS IN NEPHELINE: THE ROLE OF THE FLUIDS IN THE PETROLOGIC EVOLUTION OF THE NEPHELINE SYENITES OF THE DITRĂU ALKALINE MASSIF András FALL1, Csaba SZABÓ2 1 Univesity of Bucharest, Faculty of Geology & Geophysics, 1, N. Balcescu Ave., sect.1, RO-70111, Bucharest, e-mail: [email protected] 2 Eötvös University, Department of Petrology and Geochemisrty, 1/C, Pázmány Péter Ave., 1117 Budapest, e-mail: [email protected] Keywords: fluid inclusions, nepheline, Ditrău Alkaline Massif The Ditrău Alkaline Massif is one of the best-studied and most complicated geological formation in Romania. Many works and publications are addressed to the mineralogy, petrology, structure, genesis, age and economic potential of the rocks of the Massif. The complex geological built up, the specific rocktypes and their variable occurrence in the Massif led to numerous unequivocal theories about the genesis of the Alkaline Massif. However, several questions about the petrogenesis of the Massif still persist. The nepheline syenite is the most abundant rock type in the Massif. The rock is composed of pertitic feldspars, nepheline, biotite, amphibole, pyroxene, cancrinite, sodalite and calcite. This rock type occurs in the central and eastern part of the complex and represents the youngest intrusion of the complex. We observed fluid inclusions in nepheline during the petrographic examination of nepheline syenite samples from Ditrău. The inclusions are two-phase (liquid and 2-8 % vapor) or three-phase (liquid, 2-8 % vapor, 5-15 % solid), with elongated, negative crystal shapes and sizes between 2-40 µm. In as much as the inclusions have primary character they preserve the original geochemical environment during the crystallization of the nepheline and the formation of the nepheline syenites, respectively (ROEDDER 1984). The examinations of the fluid inclusions were carried out by microthermometric methods, with a Fluid Inc. USGS type heating-cooling stage. The results of the microthermometric studies show that the composition of the majority of the inclusions can be modeled as simple H2O-NaCl solutions, with an average salinity of 21.2 wt% NaCl. However, a few phase-changing temperatures suggest more complex composition of the fluids, with ions of Na+, Cl-, K+, Ca2+, Mg2+, SO42-, CO32-, OH-, H+ in them. The homogenization temperatures vary between 172.5 and 305.0 °C. This variation could be in relation with the long formation period of the nepheline and the cooling history of the nepheline syenites. Microthermometric results made possible the valuation of the pressure and temperature conditions during the trapping of fluid inclusions in the nepheline. These conditions are between 400-700 °C and 2.5-5 kbar. Knowing the composition of the fluids and the significance of these elements in the formation and evolution of the whole massif, mentioned also by the literature (IANOVICI 1938, STRECKEISEN şi HUNZIKER 1974, KRÄUTNER şi BINDEA 1998, MOROGAN et al. 2000), we can point out that the chemical elements present in the fluids had played a significant role in formation of the nepheline-postdated 19 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai cancrinite, sodalite, analcite and maybe scapolite to. REFERENCES: IANOVICI, V. (1938): C. R. Acad. Sci. Roum. 2., 689-694. KRÄUTNER, H. G., BINDEA, G. (1998): Slovak Geol. Mag., 4, 213-223. MOROGAN, V. et al. (2000): Min. and Petr. 69, 227-265. ROEDDER, E. (1984): Rev. In Min., Vol 12., 646 p. STRECKEISEN, A., HUNZIKER, J. C. (1974): Min. und Petr. Mitt., LIV, 59-74. TYPES OF SEQUENCES AND LITHOLOGIC SUCCESSIONS IN THE TUFF AND GYPSUM SUBFORMATION OF THE LOWER BADENIAN FROM PIATRA VERDE, SLANIC-TEISANI Dumitru FRUNZESCU University of Petroleum-Gas of Ploiesti, Faculty of Drilling, Geology-Geophysics Section 39, Bvd. Bucuresti, 2000, Ploiesti, Prahova e-mail: [email protected] Key words: Miocene, Slanic sycline, evaporitic megasequences, Paleoenvironments The paper presents details on the succession of Badenian sulphatic evaporitic deposits from Piatra Verde, concerning the presentation of various, special evaporitic facies, with their specific structures which allow the diagnosis of primary genetic environments. Their cyclicity is used in the integrated interpretation of the basinal evolution from Miocene. THE SEDIMENTOLOGICAL ANALYSIS OF SULPHATIC EVAPORITIC LITHOFACIES BELONGING TO SALT BRECCIA FORMATION FROM VALEA REA, ISTRITA HILL Dumitru FRUNZESCU University of Petroleum-Gas of Ploiesti, Faculty of Drilling, Geology-Geophysics Section 39, Bvd. Bucuresti, 2000, Ploiesti, Prahova e-mail: [email protected] Key words: Miocene, East Carphatian Folded Area, sulphatic evaporites, sedimentological analysis The paper presents details concerning petrographic structural varieties of the sulphatic evaporites from the Badenian salt breccia formation which appears on Istrita Hill. These varieties are known as Valea Rea selenite. The varieties, unique in Romania, which are met, are described and genetically interpreted as characterizing salt lake environments, with a prolonged residence of salinity. Data concerning the evaporitic sequences which were registered are similar to the ones in Sub-Carpathian Ucraine and Poland and allow the elucidation of some aspects of Miocene evolution of the Carphatian Foredeep Basin. THE SEDIMENTOLOGICAL INTERPRETATION OF THE PALINOMORPHES DISTRIBUTION BELONGING TO THE LOWER TUFF AND GYPSUM SUBFORMATION FROM PIATRA-VERDE, SLANIC-TEISANI Dumitru FRUNZESCU, Victor BACARAN University of Petroleum-Gas of Ploiesti, Faculty of Drilling, Geology-Geophysics Section 39, Bvd. Bucuresti, 2000, Ploiesti, Prahova e-mail: [email protected] 283, Bvd. Republicii, bl. 3 B1, ap. 9, Ploiesti, 2000, Prahova 20 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Key words: Miocence, Slanic syncline, palinomorphes, sedimentological analysis The paper presents the palinomorphes distribution belonging to the lithological sucession of the lower tuff and gypsum subformation from Piatra-Verde (Slanic-Teisani). The frequence which was registered in different lithons strenghtens the sedimentological conclusions which were petrographically deduced: the great diversity of taxons and the great frequence of heavy palinomophes are indicators of some stages of lowstand systems tract and the reduced diversity and the great frequence of light palinomorphes suggest the dillution in highstand systems tract stages. TRANSPORT AND EMPLACEMENT MECHANISMS OF IGNIMBRITES FROM GUTAI MTS., EASTERN CARPATHIANS, ROMANIA Alexandrina FULOP North University, 62A, V. Babes street, Baia Mare, e-mail:[email protected] Key words: Gutai Mts, rhyolitic ignimbrites, sedimentary structures, flow regime, transport and emplacement mechanisms The 15.4 Ma rhyolitic ignimbrites were the first volcanic products from Gutai Mts. They covered the south-western border of Gutai Mts. on 20 km length and 10 km width. Their thickness decreases from 350 m in west to 30 m in east. Tens of boreholes and large outcrops offer an control on the ignimbrites spreading and allow a detailed study. The focus on the sedimentary structures of the ignimbrites show what kind of mechanisms were essential for the transport and emplacement and which processes developed in those conditions. They bring us in the field of conceptual models related to sustained suspension currents and their rheological extremes: dense and dilute flow regimes, subcritical and supercritical styles of flowing. The ignimbrites form a thick stratified deposit composed of multiple units. Each unit develops a massive structure showing a weak reverse coarse-tail grading of the pumice clasts. Deposits, as a whole, show the normal coarse-tail grading of the large, mainly sedimentary xenoliths. These primary sedimentary structures are indicators of the parental flows regime suggesting highly concentrated laminar flows or dilute, subcritical flows, both emplaced by progressive aggradation. The secondary sedimentary structures bring information about the eruptive style, flow rheology, volatiles and temperature regime. The columnar jointings assess the hot-state deposition of the ignimbrites as a highly cohesive deposits.The eutaxitic texture is present on the whole thickness, showing the general high degree of welding. It is compatible with a gas-retention regime preserving high temperatures and explains the scarce lack of welding by local increase of cooling rate. Welding, preserved on 20 km length, excludes the dense laminar parental flow that would cause a massive, near source aggradation. The cooling textures, such as spherulitic and perlitic textures, bring informations about the cooling history and the gas-escape regime. Spherulites show high eruption temperatures and slowly cooling rates. Perlites suggest syn-emplacement contraction or post-emplacement hydration processes. Very scarse gas-escape pipes are compatible with volatile-retention regime and indicate a weak degree of fluidization. The data are compatible with a steady, maintained, dilute turbulent pyroclastic current, moving on a surface of constant slope and roughness. The primary and secondary structures suggest mass flows in subcritical regime which allowed the areal development of welding. The subcritical flow is slow and deep, have a relatively small amount of kinetic energy and cannot entrain significant quantities of air as they propagate. That explains the long run-off, enhanced by the spreading along a confined channel. This lowfluidized flow regime preserved the high temperature up to 20 km away from the source because of the volatile-retention regime. According to the stratified suspension current behaviour, the ignimbrites were emplaced from the basal, dense part of the dilute suspension current, by 21 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai progressive aggradation processes. Multiple units were rapidly emplaced, cooling together as a single cooling unit. LONG PERIOD SEISMOELECTRIC SIGNAL Valentin Constantin FURNICA Romanian Academy-Institute of Geodynamics 19-21, Jean-Louis Calderon St., R-70201, Bucharest, sector 2, Romania, e-mail:[email protected] Keywords: earthquake, seismoelectric precursor Modern research regarding the ultra-low frequency (ULF, <10Hz) natural electric and electromagnetic fields, for the identification of anomalies with earthquakes precursory characteristics, allowed to classify them in seismoelectric signals (SES) of short (few minutes to many hours), medium (half a day to several days) and long period (half a month to six month). Starting from the assumption that between the seismic source and a point in the epicentral area there is an energetic transfer by means of the ULF electromagnetic field, and observing the Kirchhoff’s law, we made a sensor which works like an electric micropile, in similar conditions with those which are specific for electrochemical corrosion phenomena in stationary weak solution of sodium chloride. The V variation (in mV) between November 2000 and April 2002 is presented. Its main anomaly, bipolar, could be classified in the long period seismoelectric signals category. During this anomaly, the seismic activity on the Earth, of magnitude M5, has been controlled by a phenomenon which had a strong influence on the Earth’s electrical activity, earthquakes greater than 7 degrees not being recorded by any international seismological network. In the Vrancea seismic area, two earthquakes are coincident with anomaly morphological features, which could become important geodynamic indicators. There are evident causal links with astronomical events (equinox, lunar and solar eclipses) and with the strongest earthquake (M=8.4) which occurred on Earth during 2001. ALTERATION PROCESSES OF THE HYDROCARBON ROCK MAGAZINES FROM THE FISSURED CRYSTALLINE BASEMENT. A CASE STUDY - CHEŢ STRUCTURE PANNONIAN BASIN Octavian GEORGESCU University "Petrol-Gaze" Ploieşti, Departement of Geology and Geophysics, Bd. Bucureşti 39, 2000 Ploieşti, [email protected] Key words: alteration, fissuration, crystalline basement, rock magazine. The paper proposes the use of the physical methods of mineralogical analysis for the determination of the alteration degree of the rocks from the crystalline basement. Correlating the degree of alteration with the degree of fissuration the rocks capable to become hydrocarbon rock magasines can be identified. This aspect is demonstrated on the Cheţ Structure from the northern part of the romanian sector of the Pannonian Depression. STRUCTURI SEDIMENTARE MECANICE ÎN DEPOZITELE VULCANOCLASTICE ALE CARPAŢILOR ORIENTALI DE CURBURĂ – PROCESE SPECIFICE 22 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Monica GHENCIU (anul IV), Maria ANDRONE (anul III) Centrul de Sedimentologie, Universitatea din Bucureşti/ Facultatea de Geologie şi Geofizică Îndrumător: Marius POPA Lucrarea de faţă este un studiu sedimentologic preliminar asupra structofaciesurilor mecanice ale depozitelor vulcanoclastice din alcătuirea "Tufului de Slănic". Aceste depozite apar în structura formaţiunilor "molasice" acumulate în unitatea Pânzei de Tarcău, şi sunt bine dezvoltate în zona de curbură a Carpaţilor Orientali. În acest scop s-au urmărit secţiunile stratigrafice ce aflorează în Dl. Piatra Verde (loc. Slănic- Prahova) şi în profilele deschise de V. Teleajenului şi Lupa. Algoritmul de analiză aplicat a urmărit identificarea şi caracterizarea faciesurilor vulcanoclastice în succesiuni (secvenţe) şi detalierea structurilor mecanice - din punct de vedere al poziţiei în cadrul litonilor (intern/ la suprafaţă), a elementelor dimensionale şi morfologice, a categoriilor granulometrice, a structurilor asociate (în extindere laterală şi succesiune) – în scopul identificării proceselor care le-au controlat. Au fost puse astfel în evidenţă mai multe categorii de structuri construcţionale (masive, stratificate/ laminate paralel, granoclasate normal, oblic- tabulare şi concoide, lenticulare, ondulate), erozionale (scour marks, flute casts) şi deformaţionale (load casts, dish- and- pillar), legate genetic de procese mecanice distincte. Interpretările elementelor descriptive ale acestora au evidenţiat că procesele de sedimentare ale unităţilor vulcanoclastice au avut la origine procese de transport controlate de mecanisme individuale – prin suspensii în general turbulente, fluide, uneori cu capacitate erozională ridicată - şi în masă – prin curgeri gravitaţionale de diverse tipuri (între care sau recunoscut şi produse ale curenţilor de turbiditate). În aceste condiţii depunerea s-a făcut prin mecanisme variate (agradare, progradare, îngheţare) în ambianţe marine de apă puţin adâncă (litorale şi de şelf, ce evoluau în proximitate cu sisteme deltaice), situate într-un cadru geotectonic activ – aşa cum este indicat de modul de asociere al structurilor şi de prezenţa unor structuri diagnostic. THE SOLAR SYSTEM FORMING AS SUMERIANS HAVE KNOWN Teofil GRIDAN S.C. PROSPECTIUNI S.A., 1 Caransebes st., 78344-Bucharest, Romania, Phone: 6845306 The modern man and more than him the scientist is tented to clasify the myth, legends and epics somewere in the literature domain. He is wrong obviously, because he ignores the “scientific” mesage, ciphered conveyed by long time ago extincted cultures and civilizations. The epic Enuma Elis was puzzled from sumerian tells writen on 7 broken slates, descovered by archeologists in the suposed Asurbanipal’s Library from Ninive. The epic related “The Creation Story”, in fact, the sumerians concept about the solar system genesis. The present paper trys, following the epic verses, tablet by tablet, to descipher “the scientific mesage” which reveal an amazing advanced knowledge of sumerian civilization, in Mesopotania teritory, statued 4000 years before Jesus Christ. The sumerians have known all the plates of the solar system, including the asteroids belt and have had credible explanations for ther genesis. Their knowledge remained coverd under the Ninive ruins. And who to belive them, because only in the XIXth century there were (re)descovered the last three planets of the solar system: Uranus, Neptun and Pluto? As well as in the other science domains, in cosmogeology, the roots are long time ago seeded and we are only continueing the sumerian knowledge. 23 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai LIMITA JURASIC MEDIU-JURASIC SUPERIOR IN CADRUL OLISTOLITULUI DE PE VALEA PELESULUI (MASIVUL BUCEGI) Ioana HOBLE (anul IV) Îndrumător: Prof. Dr. Ovidiu DRAGASTAN Versantul estic al Masivului Bucegi este caracterizat prin prezenta unui contact tectonic peste zona flisului marcat de olistolite calcaroase Triasic-Cretacic inferior. Caracteristic pentru succesiunea depozitelor Jurasicului superior de pe flancul estic al Masivului Bucegi este Olistolitul A de pe Valea Pelesului. Depzitele incep prin o succesiune de gresii cu intercalatii de marne si sisturi argiloase marnoase Bathovian superior-Callovian inferior, probabil mediu, peste care se dispun transgresiv si discordant radiolaritele si calcarele cenusii-albicioase de varsta Oxfordian-Tithonian. Limita Oxfordian-Kimmeridgian se poate trasa atat litologic, prin trecerea de la radiolarite rosii la calcare cenusii; cat si paleontologic. Varsta Oxfordian este data de asociatia de radiolari si foraminifere ca Globuligerina oxfordiana. Urmeaza in Kimmeridgian-Tithonian faciesul dominat de foraminifere bentonice cu Lenticulinide si Nodosarii, iar in Kimmeridgian-Tithonian intalnim micrite si pelsparite cu Saccocome, Globochaete alpina si Mercierella dacica (Dragastan). Asociatia de microfosile indica un domeniu de sedimentare din zona slope-ului superior, la marginea platformei carbonatate, respectiv selful extern. ON SOME GEOLOGICAL AND GEO-MECHANIC ASPECTS OF THE COAL AND ADJACENT SOFT ROCKS IN JILT MINING FIELD - GORJ COUNTRY - ROMANIA Radu Virgil HOBINCU, Florica STROIA, Ion STOICAN Key words: coal-oriented samples; variogramme; hyperbolic model; nugget-effect. The Jilt coalfield belongs to Getic Depression, i.e. southern part of the Carpathian foredeep, characterized by presence of molasse sediments, continental association variety [Anastasiu, 1998]. Formed in late Laramic diastrophism, stratigraphical succession begins from low Eocene and end at upper Pliocene. Some scientists consider that here, the low Pleistocene in present like a continuation of the Pliocene sedimentary process. In the Jilt mining field are exploited in this moment, especially the layers numbered VI-VII, VIII, and X and, in a few places XI and XII. The coal is a light brown coal (lignite), cantonal soft rocks being clays, silt-clays, marl-clays and sands of different compositions and textures. In underground is exploited X coal seam by the longwall method, the others being exploited in quarries. Like in others fields in Oltenia coal basin, the mining works design was based on the hypothesis of a simple tectonic structure of the coal deposits and an isotropy of the rocks themselves. The researches developed especially in the last fifteen years shown that the tectonic structure is more complicated in rapport with the initial model and also that nor coal seam, neither the other rocks are isotropic. 24 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The heterotropy of entire structure is demonstrated at small and large scale too. The main results of the researches consist in the elaboration of a new macro-tectonic and micro-tectonic model based on the field investigation, identification of the structural and mechanical anisotropy elements and geostatistical characterization of some of these properties. Structural researches in field has proof a more complicate tectonic than previously was considerate; the structure is not a "monocline" but a southern side of an anticline, containing also secondary folds. This plicate structure has an approximate strike E-W. It is affected by disjunctive major elements consisting in direct faults occurring especially in the inflexion synclinal - anticline sides introducing a significant displacement of the coal seams. The microtectonic is present by dilation tension joints, mainly observed in the coal. Was measured (using the dip / dip-direction method) two joints directions, the main set being parallel and the co-set orthogonal in rapport with the principal tectonic axis. All the joins are quasi-perpendicular on coal bedding. The results of the laboratory mechanic test, realized on coal-oriented samples, show that the coal resistance has different values in different directions, i.e. the coal is a natural anisotropic material, concordant to general structure. The geostatistical data analysis demonstrates that many of the layer properties (like whiteness, calorific power and other) are regionalized variables. The most part of the variogramme can be modeled through the spherical Matheron model or the hyperbolic model. In the both cases appears a strong nugget-effect interpreted by the authors in an own new manner. Two geostatistical methods (variogramme and absolute dispersion) demonstrate that influence radius for the most of layer parameters is greater than the specific dimension of the exploration boreholes network. Consequent of these results, some natural and techniques phenomena can be explained. To this category belong the fossil landslips and a part of the stability problems appearing in mining practice in underground mine and also in quarries. The link existing between natural peculiarities and the mining activity conduce to many environmental effects, like topical landslips and soil surface degradation. The results can be used equally in layer exploration, mining activity and also in environmental geologic problems, like risk map elaboration. THE SOUTH CARPATHIANS, FAGARAS AND LEAOTA-IEZER MOUNTAINS. Viorica IANCU1, Valerica AXENTE2, Henri MALUSKI3 1 Geological Institute of Romania, 1, Caransebes Street, sect. 1, RO-78344, Bucharest, e-mail: [email protected] 2 Univesity of Bucharest, Faculty of Geology & Geophysics, 1, N. Balcescu Ave., sect.1, RO-70111, Bucharest, e-mail: [email protected] 3 Laboratoire de Geochronologie, UMR 5567, Universite Montpellier 2 Place Eugene Bataillon 34095, Montpellier, Cedex 05, e-mail: [email protected] The pre-Mesozoic rock assemblages and litho-tectonic units in the South Carpathians are well preserved in the Alpine Getic and Supragetic basement napes, especially in the eastern part of the Fagaras and Leaota-Iezer Mountains. The sedimentary cover sealing the pre-Alpine nappe stacks (Iancu et al., 1998) in Fagaras and Iezer-Leaota Mountains begin with lower Jurassic. 40Ar/39Ar ages of 309-320 Ma (Dallmeyer et al., 1996) support a thermal activity related to the Late Variscan orogeny. The basement of the Fagaras-Iezer-Leaota Mountains includes: - Gneissic terranes (Fagaras, Cumpana and Sebes pre-Alpine units cf. Iancu & Maruntiu, 1994); they partly correspond to metamorphic series described by Balintoni et al., 1986 and Gheuca, 1988). The protoliths ages are not known but Upper Proterozoic to Lower Paleozoic could be accounted. 25 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai - Low to medium grade metamorphic terranes; the Calusu and Leaota units, (greenschist to epidote-amphibolite facies, cf. Iancu, 1998) are assigned to the Paleozoic (Dimitrescu et al., 1990) sedimentary and geotectonic cycle. New Ar/Ar age data of 354-331 Ma (Maluski, unpublished results) and Sm/Nd of 358-323 Ma (Dragusanu, Tanaka, 1999) are good proofs for the Variscan ss. timing of the final regional metamorphic evolution and nappe stacking in the area; the inherited metamorphic terranes are so of Variscan affinities. A polystage nappe stacking evolution related to the Variscan collision, following the oceantype and continental subduction processes, can be recognized in the Fagaras and Iezer-Leaota Mountains. Complex normal to strike-slip faulting activity was subsequently followed by extension and up-lift processes. Shear zones correspond to the main tectonic boundaries of thrust-overthrust and strike-slip type (Iancu, Maruntiu, 1994; Iancu, 1998). They are strongly diversified depending on the physical conditions and rheological properties. Detailed analysis of the mylonitic and pre-mylonitic paragenesis and the reconstitution of the blastesis-deformation progressive history deciphered the dynamic metamorphism. Retrograded and folded mylonites suggest a complex tectonic history. There are distinguished: - Low to medium-grade mylonites; they are generally connected to tectonic boundaries cropping out at upper crust level; biotite-garnet-muscovite-chlorite-epidote (greenschist to epidoteamphibolite facies) neoblasts overprint different types of protoliths and pre-mylonitic metamorphic rocks whose porphyroclasts are passively rotated and recrystallized in a S-C-C’ type matrix. - Medium to high-grade mylonites; the kyanite-sillimanite-garnet-biotite and omphacitepyrop-amphibole-kyanite-phengite-rutile bearing mylonites are the best examples from Fagaras and respectively Iezer-Leaota Mountains. Their almost complete re-equilibration in the amphibolite (M2) to greenschist facies conditions is related to Late Variscan evolution. Bodies of magmatic protoliths (coronitic metagranites of Albesti type) and eclogite facies mylonites are well preserved in the Bughea tectonic zone; these bodies can be interpreted as exhumed subduction-related HP rocks lately incorporated into an epidote-amphibolite facies matrix. First 40Ar/39Ar data in the Iezer-Leaota Mountains are: 354+/-4Ma and 342.6+/-3Ma on amphibole and phengite from the retrograded eclogite of the Bughea shear zone; 346+/-3Ma on muscovite from mica-chlorite schist belonging to Calusu Unit; 331.3+/-4Ma on biotite from biotitegarnet-epidote-bearing mylonites on Cumpana type rocks. These Ar/Ar data argue for a Late Variscan tectono-metamorphic evolution in the Lower Carboniferous (pre-Westphalian) time. GEOLOGICAL CONDITIONS OF EXPLOITING HIDROCARBON RESERVOIRS THROUGH MINING WORKS Mircea N. IONESCU „Petroleum-Gas” University of Ploiesti Key words: bituminous sands, petroleum sands, mining works. The practice of putting in value de petroleum reservoirs for a century and a half indicated an increase of the world production. The process was first slow in the first century of exploatation and it was followed by a high rhythm in the second half of the twentieth century. In the last decade a period of stabilisation took place. Starting from the second and third decades of the latest century, the prognoses indicate a decline. This evolution is the consequence of the fact that these natural resources were exhausted and it is due to the physical limits of the used technologies. A good part of the prognosed resources cannot be recovered from resources through classical methods. Under such circumstances new methods of exploiting the reservoirs are imposed. The author analyses the possibility of putting in value the hidrocarbon resources, by means of mining works and shallow, underground or mixed mining-drilling works. 26 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The new technologies become interesting under several circumstances concerning price evolutions. Therefore some petroleum sands, bituminous scistes, and shallow depleted petroleum sands under 300-500 metres can be efficiently valued. RECONSTRUCTING A LOWER ROMANIAN FLUVIAL BELT IN THE COAL BEARING DEPOSITS, MĂTĂSARI-ROVINARI AREA Dan C. JIPA1, Marian PALCU, Corina FURTUNA1 1 National Institute for marine Geology and Geoecology- GeoEcoMar 23-25 Dimitrie Onciul St., Bucharest, e-mail: [email protected] Key words: fluvial paleomorphology, point bar, longitudinal bar The Upper Dacian - Pleistocene deposits in the Dacian Basin display a rather wide variety of fluvial features. Observed in outcrops or interpreted from subsurface information, the fluvial features appear practically always in vertical intersects, with restricted extenuation. Taking advantage of the dense well exploration network in the study area, isopach map information led to the partial reconstruction of a fluvial belt. The investigated fluvial sequence, of Lower Romanian age, is bounded by the coal layers VII and VIII. Information concerning the fluvial sedimentary process have been derived from sedimentological investigations in open mines. Extending for 18 km, in between Jiltz and Rovinari coal pits, the reconstructed fluvial belt segment is 1,5 km to more than 3 km wide. A meandered river was flowing along this belt, with a general flow directed from south-west towards north-east. The river water depth was significant, as the thickness of the fluvial sand filling is sometime amounting to more than 20 m. Tabular cross laminated units indicate the existence of longitudinal fluvial bars on the river channel floor. A large point bar developed in the Jiltz section of the fluvial belt. The Jiltz point bar registered a lateral development of about 1 km. Inclined bedding of the bar is made obvious by thin clay drapes. Tributary channels have been outlined on the both sides of the main fluvial belt. The largest tributary is up to 1.5 km wide and can be traced on a 6 km length. Compared with the main river channel, the sandy fluvial load of this important tributary channel is finer grained, as indicated by observations in the Rosia de Jiu quarry. UPPER NEOGENE SEDIMENTATION OF THE DACIAN BASIN UNDER THE INFLUENCE OF GLOBAL FACTORS: STATE-OF-THE-ART. Dan C. JIPA National Institute of Marine Geology and Geoecology – GeoEcoMar, 23-25 Dimitrie Onciul St., 70318 Bucharest, e-mail: [email protected] Key words: sediment fan, source-area, paleoenvironment, global factor Located in between the Carpathian chain and the Euxinic area, the Pliocene Dacian Basin acted as a moderator in between the sediment source-area and the final deep-sea sediment accumulation area. In the same time the Basin evolved under the influence of the global factors represented by the two (mountainous and marine) major neighboring areas. The analysis of the sediment thickness distribution reveales that within the Dacian Basin two independent sediment accumulation areas co-existed. The eastern, most extensive Dacian sedimentation area appears as a large sediment fan. The more restricted, western sedimentation area seems to accommodate a space centered on a possible local subsidence zone. The Eastern Dacian Fan shows an active western progradation, while aggradation is dominant over its central and northern parts. In contrast, the western sedimentary area of the Dacian Basin has a distinct retrogradation character. 27 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Based on surface (outcrops) and subsurface (well) data, the paleo-environmental analysis pointed out three main types of sedimentary environments: lacustrine, littoral lacustrine (deltaic and shoreline) and fluvial (in the channel, near the channel and out of channel). The three paleo-environments occur within three distinct genetic intervals. The succession of these genetic sediment intervals points out the environmental evolution of the Dacian Basin during the Pliocene time. The lacustrine phase of the Dacian Basin corresponds to the Pontian time. Coarsening upward sediments (sometime with wave ripples or hummocky sedimentary structures) point out the shallow water, prograding, littoral-lacustrine phase of the Dacian Basin during the Lower Dacian. The littoral genetic interval represents the final episode of the Dacian Basin lacustrine development. Since the upper part of the Dacian time to the modern time the fluvial sedimentation was strongly dominant over the area of the Dacian basin. This fact outlines the possibility that an early feature of the Lower Danube River could have acted even from the Upper Dacian. The three major paleo-environmental intervals (lacustrine, littoral, fluvial) also represent stratigraphic units, with a potential use for an integrated both genetic and stratigraphic framework of the Dacian Basin. A dominantly one-side sediment supply coming from the Carpathian area indicates that the Dacian Basin sedimentation was strictly controlled by the tectonic factor. The governing role of the eustatic factor over the basin evolution seems to be indicated by a correlated occurrence of coarser sediments in the Dacian Basin and the Black Sea area. SEDIMENTOLOGY OF PANNONIAN (S.STR.) DEPOSITS IN THE NIRAJ VALLEY AREA (EASTERN TRANSYLVANIAN BASIN) Csaba KRÉZSEK University of Babeş-Bolyai, Faculty of Biology & Geology, Dep. Geology 1., M. Kogălniceanu, RO-3400, Cluj-Napoca, e-mail:[email protected] Keywords: sedimentology, submarine fan, Pannonian, Transylvanian Basin The Transylvanian Basin is an Upper Neogene strike-slip basin, located in the inner belt of the Carpathian Mountains, Romania. The uppermost basin-fill sediments are represented by Pannonian (s.str.) deposits. The studied Pannonian sedimentary succession comprises an epiclastic sequence of conglomerate, sandstone and mudstone. The entire sequence can be represented by 9 distinctive sedimentary facies organized into 3 facies associations (A, B, C). Facies association A is characterized by thick, coarse, sometimes gravelly sandstone and a minor amount of conglomerates interbedded with thin sandstones and mudstones. These were interpreted as products of coarse-grained or sandy debris-flows deposited in proximal fan areas. Facies association B consists of massive, stratified or laminated sandstone and mudstone which form graded bedding. This association represents turbidites and fine grained sandy debrisflows deposited in medial fan area. Facies association C are represented by laminated mudstones occasionally interlayered with thin horizontally or ripple-laminated fine-grained sandstones. This facies association was deposited in the lower fan area, representing distal lobe fringes. The sedimentary units are components of deep water siliciclastic fans, fed by coarse grained braid-plain- and fan-deltas, which fills the Eastern Transylvanian Basin during the Slavonian. In the studied area, the uppermost Pannonian (s.str.) sediments deposited in shallow water or continental setting were eroded during the strong Pliocene-Quaternary uplift of the Transylvanian Basin. 28 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai SOME EXQUISITIVELY PRESERVED, RARE FOSSILS FROM THE MIDDLE JURASSIC DEPOSITS OF THE BUCEGI MOUNTAINS Iuliana LAZĂR, Victor BARBU, Csiki ZOLTAN University of Bucharest, Faculty of Geology and Geophysics, Laboratory of Palaeontology 1, N. Balcescu Ave., 70111,Bucharest, ROMANIA. e-mail: [email protected]; [email protected]; [email protected] Key words: corals, nautiloids, arthropods, echinoids, fish teeth, Middle Jurassic, Bucegi, Romania. The Middle Jurassic deposits, outcropping on the western flank of the Bucegi Mountains, are known in the literature mainly by the richness of the bivalve and brachiopod assemblages. Many of the Jurassic macrofaunal associations from this area, dominated by bivalves, also contain other groups such as corals, gastropods, nautiloids, belemnites, serpulids, arthropods, bryozoans, crinoids, echinoids and fish teeth. These groups both show a reduced diversity and are represented by few specimens in the Middle Jurassic associations from Bucegi. The preservation pattern of the faunas is variable, being influenced by shell or skeletal morphology, the size of each taxon, their mode of life, the type of the sediment, as well as the taphonomic processes that affected these assemblages. From the rich fossil faunas that we collected from these deposits, in the present paper we introduce only some examples showing a high degree of preservation. The taxa belong to the following groups: solitary corals (Montlivaltia sp.), gastropods (Pleurotomaria monilifera DEFRANCE, Pyrgotrochus elongatus (SOWERBY)), nautiloids (Paracenoceras cf. hexagonum (SOWERBY), Eutrephoceras sp.), chelipod fragments belonging to some arthropods, bryozoans (Berenicea sp.), echinoids (Pygaster patelliformis (AGASSIZ), Pygaster sp.), as well as chondrichthian (Asteracanthus sp., ?”Orthacodus sp.”) and holostean (Lepidotus sp.) teeth. The presence of these groups or taxa was already reported in several previous papers, but none of them was figured or properly described. On the synthetic log recorded for the research area, the following marker levels are indicated: “Isognomoids Bed”, “Brachiopods Bed”, “Montlivaltia and Nerineids Bed”, “Cephalopods Bed”; the provenance of the above mentioned species is also marked. The systematic study and the detailed description of these taxa will be published in forthcoming papers. THE ORIGIN OF AMPHIBOLES OCCURRING IN MAFIC AND ULTRAMAFIC ROCKS OF THE DITRĂU ALKALINE MASSIF (EASTERN CARPATHIANS) István MÁRTON1 , Csaba SZABÓ2 , Elemér PÁL-MOLNÁR3 1 2 Univesity of Bucharest, Faculty of Geology & Geophysics, 1, N. Balcescu Ave., sect.1, RO-70111, Bucharest, e-mail: [email protected] Eötvös University, Department of Petrology and Geochemisrty 1/C, Pázmány Péter Ave., HU-1117 Budapest, e-mail: [email protected] 3 Univesity of Szeged, Department of Petrology, Geochemisrty and Mineralogy P.O. Box 651, HU-6701, Szeged, e-mail: [email protected] Keywords: alkaline magmatic body, ultramafic rocks, and amphibole metasomatism The Ditrău Alkaline Massif, Middle Triassic to Lower Cretaceous in age (PÁL MOLNÁR and ÁRVA-SÓS 1995, DALLMEYER et al. 1997; KRÄUTNER and BINDEA 1998, STRECKEISEN and HUNZIKER 1974), intruded into the pre-Alpine metamorphic rocks of the Bucovina Nappe in several phases. This series is related to the Alpine extensional tectonism, which began with the detachment of the Getic-Bucovinian microplate from the margin of the Eurasian platform (KRÄUTNER and BINDEA 1998). The mafic and ultramafic rocks of the Massif occur in a well-defined area (Tarnica Complex), interdigited, with gradual transitions or forming intercalations (PÁL MOLNÁR 2000). Their genesis is different from those of the other rock types in the Massif. MOROGAN et al. (2000) 29 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai suggest that the ultramafic rocks (clinopyroxenites and olivine-clinopyroxenites) are cumulates of mantle origin and they have been carried to higher crustal levels by the first intrusion of dioriticgabbroic magmas (KRÄUTNER and BINDEA 1998). The goal of our study is to describe samples from the ultramafic and mafic rocks, using detailed petrographic observations and mineral chemistry analyses, trying to express the characteristics of different rock types, focusing mostly on the genesis of the most abundant rockforming component, the amphibole. Detailed petrographic study shows that the occurrence of amphiboles varies in the different rock types. In alkaline diorites and hornblendites, with shape-preferred orientation, their habit is euhedral, prismatic indicating their primary magmatic origin. Textural analysis of the hornblendites show numerous deformation features in these rocks (kink bands in biotites and deformation twinning in amphiboles). Amphiboles in clinopyroxenites and olivine clinopyroxenites display typical textural features: 1) small, oriented crystals along clinopiroxen cleavages; 2) replacing and enclosing clinopyroxenes which cause poikilitic-like textures; and 3) large amphiboles containing tiny relicts of clinopyroxene. These textural features from type 1 to type 3 suggest a pro-grading amphibole metasomatism. Amphiboles are pargasites, kaersutites, ferro-kaersutites and magnesium-hastingsites. Amphiboles differ in their compositions with respect to their occurrence in different rock types (MOROGAN et al., 2000). The formation temperature of amphiboles is estimated to be in the interval of 1030-820oC (MOROGAN et al., 2000). Amphiboles in the hornblendites, with shape-preferred orientation, display strong chemical zonation, with high Si, Ti, Fe, K enrichment and Al, Mg, Na depletion at the rims. Compositional profiles through clinopyroxenes from clinopyroxenites suggest that amphiboles were formed by infiltrated Na-Fe-K-Ti enriched fluids reacting along with clinopyroxene cleavages. It is typical for clinopyroxenes in contact with amphiboles, that directly next to the amphibole they suddenly get depleted in mobile elements such as Na, Fe, K and Ti, which may be related to the metasomatic “front effect”. The experimental results of SEN and DUNN (1994) for modal metasomatism were applied to constrain the amphibole forming reactions. The reaction equation indicates that an infiltrating alkaline/syenitic metasomatic melts gives rise to continuous change in the composition of the origin ultramafic rocks, and that the production of amphiboles was controlled by the original clinopyroxene-olivine modal ratio. SOME ASPECTS CONCERNING THE DETERMINATION OF POROSITY VALUES FROM ACOUSTIC AND DENSITY LOGS Ion Mălureanu University "Petrol - Gaze" Ploieşti, Department of Geology and Geophysics, Bd. Bucureşti 39, 2000 Ploieşti Key words: porosity, borehole compensated log, density log The paper treats the problem of determining the porosity from the combination borehole compensated log - density log. For determining the porosity were established formulas for clean formations and for clayey formations on the basis of the acoustic impedance. The results obtained comparatively to the porosity determined by singular methods from the borehole compensated log and from the density log, as well as from the neutronic log are analysed. GEOLOGY OF FRASIN REGION (EAST CARPATHIANS FLYSCH ZONE) 30 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Mihai - Codru MICU S.C. Prospectiuni S.A., 1 Caransebes st., 78344-Bucharest, E-mail:prospec 1 @ sunu.rnc.ro. Key words: East Carpathians, Flysch Zone, Moldavides, Carpathian Foredeep, underthrusted platform, strike-slip faults, Neogene tectonics. Very detailed geological mapping carried out since 1997 within the Tarcau Nappe croppingout in the Moldova Valley Basin have led to a supply of new lithostratigraphic and structural data regarding the deposits of the Cretaceous - Paleogene Flysch Zone developed immediately westward of Gura Humorului. Among the previous geological researches concerning the above mentioned area it is worth mentioning those due to Bancila & Agheorghiesei (1964), Ionesi (1971), Dicea (1974), Sandulescu et al. (1987) and Micu (1997 - 2001 - unpublished reports). Following lithofacial and structural criteria we recognized in the study area two duplexes belonging to the Tarcau Nappe, Frasin Duplex and Voronet Duplex, separated by Obcina Mare Fault. The main lithological differences between these subunits are especially recorded at the level of Eocene deposits (Ciumarna Beds vs. Sucevita Beds and Pasieczna Limestone, Plopu Beds s. str. vs. Plopu and Bisericani Beds). Both Frasin and Voronet duplexes are made up by a series of unequally developed scales that overlap west - eastwards. In the area a series of transverse senestral strike - slip faults were for the first time pointed out too. These latter affect alike the entire pile of deposits belonging to the outer Moldavides (Tarcau, Marginal Folds and Subcarpathian Nappes), Carpathian Foredeep and the underthrusted platform as far as its crystalline basement. The youngest reactivation of these transverse faults was probably during intra - Bessarabian compressional events. MICROFAUNA DEPOZITELOR CRETACICULUI INFERIOR DE PE VALEA MUIERII, BAZINUL DAMBOVICIOARA Liliana MIHAILESCU (anul IV) Indrumator: Lector Marius STOICA In prezenta lucrare sunt descrise asociatiile microfaunistice (Foraminifere si Ostracode) din probele micropaleontologice recoltate de pe Valea Muierii, Bazinul Dambovicioara. Depozitele care afloreaza in acest profil sunt incadrate in Formatiune de Valea Muierii de varsta Barremian-Aptian inferior si sunt reprezentate in special printr-o alternanta de marnocalcare si calcare detritice cu intercalatii de marne moi. Microfauna recoltata, in special din nivelel marnoase, este foarte bogata in specii de foraminifere care pot fi incadrate la Biozona cu Lingulogavelinella sigmoicosta si L. barremiana (Barremian-Aptian bazal) si respectiv Biozona cu Epistomina spinulifera (Aptian inferior). Ostracodele identificate sunt tipice pentru intervalul Barremian Aptian fiind reprezentate pin specii ale genurilor Cytherella, Cytherelloidea, Cythereis, Protocythere, Schuleridea etc. Se fac referiri de natura paleoecologica, considerandu-se ca aceasta microfauna s-a dezvoltat in condiile unor ape relativ calde cu salinitate normala si adancimmi de pana la 200 m caracteristice shelfului distal. In baza Aptianului exista cateva nivele calcaroase cu orbitoline, ceea ce demonstreaza ca adancime bazinului putea sa fie si mai scazuta in acest interval. LA PRESENCE ET LA SIGNIFICATION DES SCHISTES A PHYLLOSILICATES PAUVRES EN QUARTZ DANS LA PILE EPIMETAMORPHIQUE DU GROUPE TULGHES – ORDOVICIEN INFERIEUR (CARPATES ORIENTALES) Mircea MUREŞAN Institutul Geologic al Romaniei – str. Caransebes 1, Sector 1, 78.344 Bucuresti 32, Romania 31 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Le Groupe Tulgheş (Tg), logé dans la Zone cristallino-mesozoïque (ZCM) des Carpates Orientales, renferme une pile formée pendant l’Ordovicien inférieur, puis épimetamorphisée régionalement à la fin du celui-ci (Mureşan, 2000 a), sous un régime barrovien (Kräutner et al., 1975). Le Tg a quatre formations lithostratigraphiques : Tg 1, Tg 2, Tg 3, Tg 4 (Bercia et al., 1976; Vodă, 1980; Kräutner et al., 1992). Étudiant les nombreux forages (plus de 70), effectués (par GEOLEX S. A. – Miercurea Ciuc) dans la région Tulgheş-Hagota-Vallée Belcina-Gherpotoc- Pângărati (située dans la partie méridionale de la ZCM), nous avons découvert, dans la pile du Tg (logée dans le socle métamorphique de la Nappe alpine bucovinienne (établie par Săndulescu, 1967, 1975, 1976), des intervalles constitués seulement par de roches terrigènes riches en phyllosilicates et pauvres en quartz (le quartz < 10 %, souvent, < 5% ): des schistes sériciteux pauvres en quartz (SSePQu) et des schistes sériciteux- chloriteux pauvres en quartz - SSeClPQu (dans ces poches, presque toujours, la séricite prédomine vis-à-vis de chlorite) ; le dernier type est moins repandu. Nous mentionnons que la plupart des roches terrigènes de la pile du Tg ont des pourcentages plus élevés de Qu (30-60 %, dans les SSeCl; plus que 60 %, dans les schistes quartzeuses). Les schistes à phyllosilicates pauvres en quartz n’ont pas été décrits dans la littérature concernant les épimétamorphites du Tg. Ces roches nous les avons trouvées presque exclusivement dans la Tg 4 et, sporadiquement, dans la Tg 3, étant mises en évidence, par exemple, dans les forages: 43 Vallée Baratu Mare (le plus grand intervalle de SSePQu, trouvé dans le Tg 4: 370-532 m; des SSeClPQu: 370-394 m); 24 Vallée Balaj (des SSePQu dans la Tg 4: 377-434 m); 53 au N de Vallée Bălaj (dans la Tg 4: 192-213 m); 42 Vallée Baratu Mare (dans la Tg 4: 84-99 m); 22 Vallée Putna (dans la Tg 4: 70-81 m; 93-97 m); 44 au sud de Vallée Bălaj (dans la Tg 4: 453-472 m); 8 Vallee Baratu mic (dans la Tg 3: 86-92 m; dans la Tg 4: 369-376 m). Les principaux traits de toutes ces roches phylliteuses pauvres en quartz sont: 1) la prédominance nette des phyllosilicates (Se ± Cl plus de 90 %) sur le Qu ± Fld (felspath – albite); 2) comme d’habitude, chaque intervalle renferme un seul type de roches pauvres en quartz: soit sériciteux, soit sériciteux-chloriteux; 3) le Qu est toujours présent, tandis que le Fld peut manquer; 4) le Qu et le Fld sont toujours disséminés uniformement dans la masse phylliteuse, sous forme de petits granules (autour de 0,5 mm) bien arrondies, de mêmes dimensions; 5) dans tous les cas, les granules de Fld sont tournés avec 40-90° vis-à-vis de la schistosité principale (S 1 synmétamorphique), fait demontré par les paillettes de Se renfermées dans les grains de Fld; donc, cette rotation du Fld s’est produit après la recristallisation de la Se, dans une phase tardécinematique vis-à-vis de S 1; 6) presque dans tous les cas, ces roches renferment des pseudomorphoses titaniferes (dans lesquelles l’ilmenite a ete remplace, comme d’habitude, par rutile) lamellaires et granulaires et, rarement des aiguilles de Ru; frequemment, dans ces roches, les pseudomorphoses titaniferes lamellaires se disposent habituellement parallelement ou quasi-parallelement vis-à-vis de S 1; parfois, ces lamelles ont été derangées partiellement ultérieurement, étant tansposées au long de la schistosité de clivage axial S 2. Les schistes phylliteux pauvres en quartz représentent l’aspect métamorphique des matériaux argileux, très faiblement impurifiés avec des éléments sableux (Qu, Fld et Ilm), signifiant des épisodes de sédimentation pélitiques, installés quand la puissance de transport des courants marines s’est diminuée sensiblement. L’abondance de la Se dans les roches examinées signifie des apports primaires massifs illitiques; la chlorite suppose des apports montmorillonitoorthochloritiques. Initialement, ces minéraux argileux primaires se sont formés dans une écorce d’altération continentale, sur un socle métamorphique, situé vers l’Est vis-à-vis de bassin (de type « back arc ») où s’est formée la pile primaire du Tg. Ce socle était constitué tant par de roches riches en Fld et Qu, que par de roches basiques (Muresan, 2002). EVOLUŢIA SUBSOLIDUS A GRANITELOR DE ALBESTI 32 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Mihaela NĂSTASE (anul IV) Îndrumător: Lector Dr. Gelu COSTIN Lucrarea urmăreşte să elucideze evoluţia subsolidus a granitelor de Albeşti (M-ţii IezerLeaota) din două ocurenţe: Râul Târgului, amonte de localitatea Lereşti şi valea Bughiţa de Sus (jud. Argeş). Sunt abordate: mineralogia cantitativă de detaliu a granitelor, studiul paragenetic, identificarea reacţiilor minerale, precum şi estimarea preliminară a condiţiilor PT de echilibrare a diverselor parageneze. Majoritatea reacţiilor minerale identificate (formarea granatului coronitic în jurul biotitului, pseudomorfozele complexe pe seama feldspaţilor magmatici şi eventual cordierit) demonstrează faptul că reacţiile se desfăşoară în condiţii allochimice în prezenţa unei faze fluide. Se încearcă o corelaţie între apariţia sau intensitatea unor reacţii minerale şi gradientul de strain. MARKERI DIAGENETICI IN FORMATIUNEA GRESIEI DE KLIWA - IMPLICATII IN DINAMICA HIDROCARBURILOR Lidia NUTU (anul IV), Florin STOICAN (anul II) Centrul de Sedimentologie, Universitatea din Bucuresti, Catedra de Mineralorgie Îndrumător: Profesor Dr. Nicolae ANASTASIU Rezervor celebru in zona Flisului Extern din Carpatii Orientali, Formatiunea Gresiei de Kliwa (Oligocen-Miocen inf.), nu este inca documentata din punct de vedere al inter-relatiilor variabilelor diagenetice si implicatiilor acestora in calitatea de rezervor de hidrocarburi. Studiul efectuat, pe probe din aflorimente deschise de V.Buzăului si V.Teleajen si pe carote din forajele din zona (500-3500m), se vrea o analiza pertinenta, prin metode de abordare specifice – microscopie optica, catodoluminescenta, fluorescenta UV – a produselor diagenetice, interpretarea acestora in termeni factori-procese si integrarea acestora intr-un model diagenetic, cu scop aplicativ in geologia petrolului. Analiza probelor, din punct de vedere diagenetic, arata o evolutie postdepozitionala complexa, marcata de procese de tasare, rearanjari mecanice, disolutii partiale, recristalizari, cimentari episodice, uneori dizolvari sub presiune, pentru un model imaginat incadrat in regimuri diagenetice hidrogeologice meteorice si compactationale (Galloway, 1984) cu recurente compozitionale. Porozitatea optica totala (Ehrenberg, 1995) arata valori medii 7% (primara si secundara), iar coroborarea acesteia cu date de petrofizica (porozitate medie 9,33%) indica o calitate a rezervorului medie (Zimmerle, 1995) in zona studiata. Procesele de porogeneza-poronecroza, pentru etapele diagenetice de eo-, mezo- si telogeneza in modelul imaginat, permit atat interpretarea migrarii, degradarii si acumularii hidrocarburilor cu diferite grade de participare, cat si modelari ale geometriilor corpurilor, omogene/heterogene-anizotrope/izotrope. BLACK SEA ROMANIAN SHELF: RECENT SEDIMENTARY PROCESSES AND SEDIMENT GEOCHEMISTRY Gheorghe OAIE, Dan SECRIERU National Institute for Marine Geology and Geoecology, Bucharest, 23-25, Dimitrie Onciul Str., sect. 1, RO – 703181 CP 34 – 51, [email protected], [email protected] Keywords: Black Sea, sediment fluxes, whether pollutants, coccolithic ooze 33 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The North-Western Black Sea shelf, characterised by important sedimentation rates (1.19 – 2.19 m/ka), preserves great quantities of sediments and associated pollutants. Sediment fluxes, originating from the important rivers (e.g. Danube, Dniestr, Dniepr), are distributed over a very large shelf area with a high retention degree. The average sediment discharge of the main contributor, the Danube River, is 30 – 40 million t/year. Total sediment fluxes (56.85Mt/yr) consist mainly of fine suspended sediment (mud, silty-mud, silt), with a small amount of coarser fraction (sandy silt, silty sand, fine sand). Sediments are transported sub-parallel to the Romanian – Bulgarian coast, being deposited to the south under the influence of the main longshore current. Controlling factors led to the formation of several sedimentary units (Danube delta front, Danube prodelta). Detailed sedimentological observations and X-ray photographs interpretations were made on superficial bottom sediments. According to grain size analyses, bottom sediments of the Black Sea shelf area are dominantly fine (silt, mud, muddy silt, silty mud). For the deeper part of the basin (water depth 200 m), silty clay, clayey silt and mud compose the Upper Holocene coccolithic ooze and Middle Holocene sapropelic mud. Sandy clayey silt and clayey silty sand form thin intercalations. Burrows, gas structures and, sometime, wood fragments and plant roots occur. The analysis of sediment cores helped identify whether pollutants (nutrients, heavy metals, organic matter, radionuclides, etc.) are transported by natural processes. Major, minor and trace components, including some of the heavy metals with the greatest toxicity (Cd, Pb, Cu, Zn) were analyzed. Chemical components are characterized by large variation ranges, with coefficients of variation (Cv) usually greater than 50%. Zr is the only component with a more homogenous distribution (Cv<30%), due to its presence exclusively as zircon and its ensuing independence. The chemical composition corresponds to sediments varying from purely terrigenous (<10% CaCO3 in the nearshore coarse sediments and 10-20% CaCO3 in terrigenous muds from the area under Danube influence), to carbonated ones (up to 80% CaCO3 in shelly sediments from the sediment starving shelf and the Upper Holocene coccolithic ooze). The TOC contents, reflecting the participation of organic matter in sediment constitution, vary from <0.5% in coarser, welloxygenated sediments, to 2-3% in finer shelf sediments and 3-5% in the abyssal zones (coccolithic ooze), with maximal values (>5% and up to 10%) in the sapropelic mud. The sequentially vertical sampling revealed a general manganese post-depositional mobilization and re-deposition at sediment-water interface. Owing to favorable conditions (vertical distribution of Eh, sediment permeability, etc.), the process is extremely active in the sediment starving continental shelf and oxygenated shelf break areas, leading to MnO concentrations in the superficial layer up to 1.6%, with the possibility to formation small manganese nodules. Statistical graphical and mathematical analyses of chemical data show abnormally high concentrations of most heavy metals at some stations. The upper 25-30 cm of sediment were measurably enriched in all of the considered heavy metals, excepting Cr and V, with a strong increasing tendency of metal excesses toward the sediment-water interface. The Danube prodelta is one of the most heavy metal polluted area, showing positive heavy metal excesses. The second heavily polluted area, the sediment starving continental shelf, was related to off-shore drilling activities, as determined by intensive Ba contamination. As sediments are normally poor in terrigenous components, the contamination degree can be higher than in the Danube Delta front. THE POLYMETALLIC MINERALIZATION GENESES IN SCRIND – RACHITELE – POIANA HOREA REGION, VLADEASA MOUNTAINS Mihai PANAITE, Ioana PANAIT S.C.ProspectiuniS.A.,Caransebes st.1, 78344, Bucuresti, e-mail [email protected] Key words:precambrian syngenetic strata bound; remobilized mineralizations;laramide veins. 34 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The polymetallic mineralizations in Scrind-Rachitele-Poiana Horea region belong to the folowing genetic types: 1. Stratiform, volcano-sedimentary-metamorphosed mineralization, of Kuroko type, interlayed in uper part of acid metatuff (Zn-Pb-Ag-Au), or in over layin muscovite-biotite micaschists (Cu-Au) 2. Hydrothermal metamorphosed veins, also associated to calco-alcaline volcanism, usualy localized near the fisrt ones; 3. Hydrothermal sulfide mineralizations, as veins, or mineralized column (stockwerk), mobilized from precambrian syngenetic mineralizations, in hercinian and alpine cycles 4. Hydrothermal laramide sulphide mineralization, as veins, at the boundary of the Somes series with Vladeasa volcano-plutonic structure. The syngenetic, stratiform, volcano-sedimentary mineralizations comprises the following types: massive, complex (Zn-Pb-Ag-Au), developed in Alunis valley; iron banded ore and massive diseminated Cu-Au ore, which outcrop in Gingineasa valley, Negru brook and Golumbat brook. The complex ore made up of pyrite, arsenopyrite, pyrothite, sphalerite, galena, chalcopyrite, freibergite, siderite, quartz and muscovite is developed as strata bound in acid metatuff and it passes in marginal zones to diseminated type, where only pyrite and arsenopyrite are present. This type of ore is equivalent with Burloaia central facies (East Carpathians). In the massive pyrite ore (Negru brook, Gingineasa valley), consisting mainly of pyrite and arsenopyrite (equivalent with the marginal facies, East Carpathians) and in the hydrothermal metamorphosed veins are sporadically pyrothite nests with pyrite relics, as a consequence of the aynmetamorphic origin. The massive, polymetallic ore was deposited near hydrotherms, while the massive iron ore and the massive and diseminated Cu-Au formation took place at the end of the volcanic period, distal to hydrotherms. The hydrothermal metamorphosed veins, highly brecciated as footwall and highwall metamorphics, consisting of siderite, pyrite, arsenopyrite, chalcopyrite, pyrothite and quartz, were formed in the same time with the stratiform polymetallic ore, on the fractures, near the main fault controlling hydroterms. The Somes metamorphics and syngenetic interlayed mineralizations were highly affected by the hercinian and alpine deformation movements, which caused minor mobilizations of the soft sulphide, remobilized as small discordant veins, but complex remobilizations, consisting of sphalertite vein, or small stockwork, made up of cloritized breccia mineralized with sphalerite, pyrothite, pyrite, arsenopyrite and galena. The ore consists of sphalerite and pyrothite ground mass, where recristalized pyrite, arsenopyrite and galena with tetraedrite exolutions are developed. The ore breccia is twice up to four times richer in Zn and Pb and tens times poorer in Ag and Au than massive syngenetic, polymetallic ore. In nothern side of the area, a low temperature hydrothermal mineralization, of sulphide and native gold, associated to laramide metalogeneses, outcrops. The vein mineralization is made up of pyrite, marcasite (which are sometime epitaxial intergrowed), sphalerite, galena, chalcopyrite and quartz. Its presence shows a possible influence of the laramide metalogeneses on the precambrian syngenetic, stratiform and hydrothermal metamorphosed mineralizations. COMBINED MAGNETIC, SEDIMENTOLOGIC AND ASTRONOMICAL CYCLICITIES FOR SOME ROMANIAN LOESS-PALEOSOL SEQUENCES Cristina PANAIOTU1, Cristian PANAIOTU1, Adrian GRAMA1, Cristian NECULA1 University of Bucharest, Paleomagnetism Laboratory ([email protected]) key words: loess, cyclic processes, orbital tunning, age model, Romania Loess deposits act as a key archive in the study of palaeoclimatic change. Investigation of loess sequences, mainly from Northern China, has led to the development of a number of 35 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai continuous palaeoclimatic records using physical parameters (magnetic properties, grain size, calcimetry) which demonstrated to be accurate proxies for climatic variations over the past 2.6 Myr. A number of studies have demonstrated a close correspondence in the susceptibility variations within loess sequences to signatures of past global climatic change derived from other archives, e.g. oceanic and ice-core δ18O profiles. The cyclic nature of the oceanic δ18 O signal allowed climatic variations to be calibrated in time via the association of identified isotopic oscillations to orbitally controlled changes in insolation. Orbital tuning has been utilized in the production of highresolution astrochronologies for both oceanic sediments and loess-paleosol sequences. Detailed rock magnetic profiles were measured recently on two loess-paleosol sequences: Mostiştea Lake (southeastern part of the Romanian Plane) and Costineşti (Dobrogea). All magnetic properties are similar with those recorded in the loess deposits of China. On the basis of this similarity, an age model was developed for the Romanian sequences by tuning the magnetic susceptibility record to time-series of insolation and to the orbitally tuned ODP677 δ18O records. To ensure that a consistent relationship between the proxyclimate record and the chosen target curves was maintained throughout the tuning procedure, a number of correlation criteria were imposed. Palaeosols were related to regional maxima in insolation, maxima in eccentricity and odd numbered marine oxygen isotope stages (MIS), whilst loess units were consistently assigned to insolation minima and evenly numbered MIS. The two susceptibility profiles from Mostiştea and Costineşti were tuned independently. Spectral analysis of obtained time-series of susceptibility was performed to determine whether coherent orbitally frequencies have successfully been introduced into palaeoclimatic time series during a tuning procedure. This analysis was performed using two different statistical algorithms specially designed for unevenly spaced time series: SPECTRUM and MC-CLEAN. We found that the susceptibility signal is dominated by the 100 ka eccentricity period, followed by the 41 ka period of obliquity and a very weak spectral peak corresponding to the 23 ka period of precession. Such a spectral composition dominated by the 100 ka period, is typical for paleoclimatic series younger than 1 Ma and demonstrates that the tuning of susceptibility profiles is reliable. The age model based on magnetic susceptibility was transfer to the calcimetry profiles measured at Mostiştea and Costineşti and to the grain size profile measured at Costineşti. Spectral analyses show that these time series have the same power spectrum dominated by Milankovitch periods. All these results demonstrate that an orbitally tuned palaeoclimatic timescale provides a robust, high-resolution chronological solution for the Romanian loess sequences. According to our age model the onset of loess accumulation started in Costineşti around 630 ka and in Mostiştea around 416 ka. HOW CONTINUOUS WAS THE ROTATION OF CARPATHIANS AROUND MOESIAN PLATFORM: PRELIMINARY PALEOMAGNETIC DATA FROM ROMANIAN AND SERBIAN BANAT Cristian PANAIOTU1, Cristina PANAIOTU1, Tudor BERZA2 and Dragan MILOVANOVIĆ3 1 University of Bucharest, Paleomagnetism Laboratory; 2 Geological Institute of Romania, Bucharest; 3 Faculty of Mining and Geology, Belgrade key words: paleomagnetism, jurassic limstones, banatites, Banat The aim of this paper is to use new paleomagnetic data for clarifying the mechanism of clockwise rotation of the Southern Carpathians around Moesian platform during the Tertiary. Previous paleomagnetic results from Romania showed that large areas from the Transylvanian Basin, the Apuseni Mountains and the Southern Carpathians were affected by a large clockwise rotation during Tertiary. To extend the area with paleomagnetic data further to the south, we sampled five sites in the Danube Valley on the Romanian territory and 6 sites in the Timok area from Eastern Serbia. From Romania, 4 sections in Middle Jurassic red limestones (Danubian Unit) were sampled along the Danube Valley and 1 site in the Upper Cretaceous magmatites from the Lilieci Valley (Getic Unit). From Eastern Serbia we sampled 5 sites in the Upper Cretaceous 36 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai volcanics and intrusions (1 site in Krepoljin and 4 sites in Bor area all in Getic Unit) and 1 site in Middle Jurassic red limestones from Tîrnaica, only 20 km south of the Danube (Danubian unit). The structure of the natural remanent magnetization was examined by progressive thermal and alternating field demagnetizations in the Paleomagnetism Laboratory of Bucharest University. All red limestones from the left bank of the Danube Valley are completely remagnetized and fold test was negative. Declination of this remagnetization, around 70º - 80º, is similar with the primary direction of the Upper Cretaceous magmatic rocks from the Lilieci Valley. In the Bor area one of the sites has reversed polarity and others have normal polarity, so the magnetization of these Upper Cretaceous magmatic rocks is primary. Declination of the mean direction is around 30º. A similar declination was also obtained from the remagnetized Middle Jurassic limestones from Tîrnaica. The new results from the left bank of the Danube Valley demonstrate that the area with large clockwise rotation extend about 330 km, from northern part of the Apuseni Mountains and Transylvanian Basin, until the Danube Valley. The transition to the less rotated Timok (Bor) area, with a Tertiary clockwise rotation around 30º, seems to be very sharp, in less than 20 km (Tîrnaica) Moreover, the amplitude of rotation measured in Bor area is similar with the post-Middle Eocene rotation observed in the western Balkan Mountains from northwestern Bulgaria. These preliminary data show that the Tertiary tectonic history cannot be modeled as a simple progressive rotation around the corner of the Moesian platform, but some other mechanism must be involved to explain this sharp transition from 30º to 80º clockwise rotation, in only a couple of tens of kilometers. CHANGES IN FLUID INCLUSIONS AFTER TRAPPING IN MINERALS Vasile POMÂRLEANU Geological Institut of Romania Caransebes, 4, 78344, Bucharest In this paper, some transformations of fluid inclusions subsequent their born, are presented. These to refere at physical and chemical changes. The physical changes comprehend: cristalization on the walls, necking down, shrinkage and imiscibilly, reversible and ireversible volume. Also migrations of fluid inclusions in a termal gradient have been exposed. Chemical changes consist turn up fluid daughter phases (daughter minerals) decrepitation and refilling phenomena. All fluid inclusions changes to pointed out various rocks and are deposita from Romanian territory. The transformations of fluid inclusions presented some genetic and practice significances. PHYSICAL STRUCTURES AND PECULIAR DEPOSITIONAL MECHANISMS AND ENVIRONMENTS IN THE MIOCENE SILICICLASTIC SEQUENCES FROM SOUTHERN EAST CARPATHIAN "MOLASSE", ROMANIA Marius POPA Bucharest University, Faculty of Geology & Geophysics, Mineralogy Dept. e-mail: [email protected] The study focused on Miocene Molassic clastic sequences of "Brebu Conglomerates" and "Doftana Formation" units, component of the East Carpathian system (southern part). Facies/ sequence analysis methodology has been applied on four stratigraphic sections in order to interpret peculiar aspects of different physical structures, as revealed by the depositional units separated within sequences. In our opinion, the examination of a physical structure of a depositional unit should be performed more accurately by taking into account all the facies features that could characterize the spatial distribution of the component clasts. This could be very important especially in the case of "heterogeneous" units (e.g. that ones which display lateral/ internal variations in aspects related to clast distribution) and associations (sequences) - as we have found in the studied deposits – or when 37 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai comparative analyses between the same structural types is intended. Accordingly, we have tried to describe physical structures by considering: textural (grain- size related) characteristics& heterogeneities (Popa& Anastasiu, 1997); main& associated (physical) structures (laterally& vertically); 3D aspects. The main structural types recognized have been grouped in four textural (grain- size related) categories, as follows: gravelly- massive, imbricated, normally-/ inversely- graded, cross- stratified, plane- stratified; sandy - massive, parallel (even or wavy) laminated, cross- stratified, hummocky stratified, rippled; heterolithic (sandy/muddy associations)- flaser-, lenticular or wavy- stratified; muddy- massive or laminated (Popa, 2000). By integrating the above- mentioned characteristics we have recognized peculiar depositional processes, controlled by different clast- supporting mechanisms (cohesive/ cohesionless, characterized by matrix strenght/ disperssive pressure forces/ collissional forces/ turbulence) and depositional mechanisms (en- masse freezing/ frictional freezing/ progressive freezing/ suspension settling), developed in (fan)- delta (in subaerial or subaequeous) areas and shallow- water (shoreface, offshore) settings, wave- and tide- influenced, tectonically- active. It is also to note that a good understanding on transport/ depositional mechanisms allows the recognition of the dynamic variability of the processes involved. This is particularly important in the case of gravity- flow products, where lateral and vertical facies variations may develop due to this reason. SILICICLASTIC SEQUENCES AND RELATED ARCHITECTURES IN THE MIOCENE DEPOSITS OF SOUTHERN- EAST CARPATHIANS, ROMANIA Marius POPA, Nicolae ANASTASIU Bucharest University, Faculty of Geology & Geophysics, Mineralogy Dept. e-mail: [email protected] The studied stratigraphic succession (700- 800 m in thickness) is the main part of the Miocene Molasse component of the East Carpathian system (southern sector), being a clastic sequence comprising "Brebu Conglomerates" and "Doftana Formation" units. By using sequence analysis on four stratigraphic sections different facies types, sequences types/ orders– and related 3D architectures - have been described. Several sequence types, of different orders, have been identified – here called micro-, mesoand macrosequences - the data set for each separated sequence specifically including: component facies-/ lower- order sequence types; bounding surfaces (at the base, top and internally); paleocurrent data; 3D architecture; lateral/ vertical transitions (Popa, 2000). The microsequences - up to 1 m in thickness - are the result of different small-scale processes that led to the deposition of distinctive small- scale facies associations. Lower- order mesosequences (up to 5- 8 m in thickness) correspond to laminated sand sheets (LS), channels (CH), gravity flow deposits (SG), gravelly bars (GB), sandy bars (SB), levees (LV), hummocky cross-stratified sandstone bodies (HCS). The bounding- surfaces genetically correspond to erosional/ nonerosional (at base) and bioturbated (at top) surfaces. These sequences were deposited in (fan)- delta (in subaerial or subaequeous) areas and shallow- water (shoreface, offshore) settings, wave- and/or tide- influenced. Higher- order mesosequences (up to 60 m) are subaerial gravity flow lobes (GFL); alluvial braidplain sheets (ABS); fan- delta plain sheets (FDP); (fan)- delta front lobes/ bars (FDFL); (fan)delta front nearshore bars (FDFB); (fan)- delta front subaequeous gravity- flow lobes (FDFS); interdistributary bay- fills/ (fan)- delta fringe (IBF/FDF); shoreface- offshore wedges (SOW). Their stacking pattern is mainly progradational or progradational- aggradational. These have been interpreted as constructive or destructive phases in the evolution of (fan)- delta systems development, strongly controlled by sediment supply and tectonic regime (proximally) and by 38 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai wave- and/or tide- activity of the adjacent shoreface systems (distally). The quality and stacking – pattern of proximal (continental) mesosequences allowed us to recognize the equivalents of dispersion- entrenchment – trench backfilling stages (s. DeCelles et al., 1991) in the evolution of the alluvial systems involved. The subaequeous architectures are very often bioturbated at the top and display a basinward shift in facies. These features indicate them as being parasequences, but their sedimentation have been influenced also by an active tectonic regime, as suggested by welldeveloped diagnostic physical structures. The proximal – “alluvial” equivalents have been separated – when possible - by changes in alluvial architecture. The association of the above- mentioned mesosequences allowed the separation of 3 IIIrd (IV th ?) order macrosequences (parasequences sets). Their stacking pattern was the effect of variations in accomodation space/ sediment supply ratio, with climatic and tectonic control. INTEGRATED INTERPRETATION AND REPRESENTATION OF WELL LOGS Cristian POPA University of Bucharest, Faculty of Geology and Geophysics, email: [email protected] Key words: well logs, integrated interpretation, formation evaluation. In the complex process of formation evaluation the need of high-level integration derives from the multitude of data that are available. The integration is not required only in formation analysis process, but also in the ways the available and calculated data are represented. This paper presents a formation evaluation study, a study that was made using well logs data from three boreholes from Eremieni field. The studied interval is approximately 1000 meters, between 1500 – 2500 meters depth and for this were used all geophysical data available. The evaluation was made using the Petrophysics module from GeoFrame 4.02 software and the final scope was to obtain the distribution of physical properties in the studied interval. CRETACEOUS CONIFERS OF ROMANIA Mihai E. POPA1 and David L. DILCHER2 1 University of Bucharest, Faculty of Geology and Geophysics, Laboratory of Palaeontology, 1, N. Balcescu Ave., 70111, Bucharest, ROMANIA. Email: [email protected] 2 University of Florida, Florida Museum of Natural History, Palaeobotany Laboratory, Dickinson Hall, PO Box 117800, Gainesville FL 32611-7800, USA. E-mail: [email protected] Cretaceous conifer material from Romania is known since the XIXth century, collected mainly from the South Carpathians, as well as from other occurrences. This paper deals with an overview of Romanian Cretaceous conifers, discussing them as a whole, from all known occurrences, with their systematic affinities and nomenclatorial aspects. The oldest Cretaceous sure conifer fossils were reported from Dobrogea, where they are Aptian in age, from Cernavoda, preserved as permineralizations, with Cupressacean affinities. Cenomanian remains were recorded from Rucar, as well preserved compressions, belonging to Cupressaceae (Taxodiaceae). Turonian conifers were described from Babadag Basin, Dobrogea, also in compressive state, and they belong to Cupressaceae (Taxodiaceae) and Incertae sedis (the case of Brachyphyllum). HYDROTHERMAL ALTERATION AT FANCEL LAPUSNA VOLCANIC EDIFICE (EASTERN CARPATHIAN MOUNTAINS, ROMANIA) AND ITS SIGNIFICANCE IN EXPLORATION FOCUS 39 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Tiberius POPA, Silvia POPA, Erika MATSCH, Iulian SEBA S. C. Prospectiuni S. A., 1 Caransebes Street, Sector 1, Bucuresti-32, Romania; e-mail: [email protected]; [email protected] Key words: andesites, propylitisation, potassic alteration, intermediate argillisation, advanced argillisation, factor analysis The volcanic edifice Fancel-Lapusna (FL) is included in the volcanic neogene CalimaniGurghiu- Harghita chain of the Romanian Eastern Carpathian Mountains. FL is a caldera type structure that dominates the northern part of the Gurghiu Mountains. The edifice is an around semicircular depression with an E-W diameter of almost 10-km The caldera has shaped as a result of a bulky explosive eruption, which interrupted the growth of a large complex cone. During the cone edifice stage, there were evolved two units: a volcanoclastic one and a stratovolcanic one. The second unit consists in intrusive bodies, lava flows, domes, breccia bodies and pyroclastic products. Field mapping corroborated with microscope study led us to confine zoned hydrothermal alterations (propylitic, potassic, intermediate argillisation and advanced argillisation). For geochemical study we used factor analysis method. The earlier intrusive stage (andesitc-dioritic) was propylitisation. In the latest postcaldera stage of the intrusions, the hydrothermal solutions developed complex alteration zonality: potassic alteration in the depth, enveloped in the upper part by argilisation. In the apical part of this system, it has developed a convective system, where ascended magmatic volatiles have been absorbed by meteoric water. It is present at the surface with a high grade advanced argillic alterations with vuggy silica. Propylitic alteration transforms partial or totals the phenocrysts of maphic minerals (pyroxenes and green and brown hornblendes) and they are replaced by neominerals, like as chlorite ± epidote ± carbonate ± leucoxene ± actinot. Factor analysis shows an arrangement of chemical elements related with the rock petrogenesis and a weak mineralisation in the main and second factors. Intermediate argillic alteration conserves the structure of the andesites. The rock is distinguished by neoformation assemblages: illite + sericite + montmorillonite/ chlorite ± pyrite and Fe oxides ± calcite. The factor analysis of an intermediate argilic rocks unit shows the pathfinder elements for gold mineralisation (As, Sb, Hg). Potassic alteration was observed in andesite bodies, mainly. This alteration is produced in the end of the magmatic activity and it modifies partially the rocks. Factor analysis of potassic rock samples unit indicates in the main factor the association Cu-K-Na-Ag-Zn-Mn. It is characteristic for porphyry copper mineralization, and in the second factor Au has a good correlation with As and Ag, which is characteristic for epithermal gold mineralisation. Advanced argillic alteration is associated with the process of forming vuggy silica. The neominerals assemblages are quartz, alunite, pyrite, diaspor, rutile and amorphous clays. In the inner of the advanced argillic alteration zone there is vuggy silica, which results by destruction of all primary rock-forming minerals except quartz. Vuggy silica is composed of quartz, pyrite, and minor rutile and has coarse voids structure. A second variety of nearly pure quartz rocks are mineralogical similar to the vuggy silica but lacks large void spaces. Vuggy silica alteration occurs like big boulders inside the advanced argilic alterated rocks.The main factor of the factor analysis displays a connection between alteration and an epithermal gold mineralization, notify the good correlation between Sb-Au-As-Hg-Ag. GIS APPLICATION IN COMPLEX GEOLOGICAL, GEOCHEMICAL AND GEOPHYSICAL DATA PROCESSING AND INTEGRATED INTERPRETATION Dragoş Găbudeanu RĂDULESCU S.C. Prospectiuni S.A., 1 Caransebes st., 78344-Bucharest, Romania, E-mail [email protected] 40 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Geological, geochemical and geophysical data management and interpretation may become very easy when they are performed in an integrated environment like GIS. Using GIS can be particularly efficient when large amounts of data resulted from long term, complex surveys, performed on large areas, are processed. In these cases, serious problems of synchronization in the data management may occur and integrated interpretation can be rather difficult to perform. The poster illustrates the procedures to follow, in GIS environment, in order to manage and correlate the data provided by the different surveying methods and to obtain an geological image of the area as close as possible to the field reality. The case study presents a complex survey on an area of about 400 sq.km, 1:5000 scale, using the following investigation methods: Geological survey - 20000 observation points; Geochemical survey - 12000 samples; Gravity survey - 7000 stations; Magnetic survey - 95000 stations; Electric survey - 3600 stations. All the field observations were introduced in Access'97 database. Geophysical interpretation was performed using Oasis Montage. The graphical database was accomplished using MapInfo 6.5 software. MapInfo 6.5 and MapBasic 6.5 software are very practical solutions in geological data processing and interpretation, taking in account their low price and the fact that MapBasic allows to customize GIS environment as a geological work environment by writing personal adequate applications. CLAY MINERALOGY AND GEOCHEMISTRY OF THE COAL BEARING DEPOSITS: DACIC BASIN Silviu RÃDAN National Institute of Marine Geology and Geo-ecology (GeoEcoMar) 23-25, Dimitrie Onciul St., sect. 2, RO-70318 Bucharest, e-mail: [email protected] Key words: clay minerals, coal, geochemistry, paleo-environment, Pliocene, Dacic Basin (Romania). Pelitic rocks associated with Dacic Basin coals are characterized by a large diversity of clay mineral assemblages and a variable chemical composition. Any clear correlation was observed between the stratigraphic succession of the coal bearing deposits and the vertical evolvement of their clay mineralogy and chemistry. However, the paleo-environmental and the lithologic control are very certain. So, the clays included within the detrital sequences encompassed between the main coal beds and from the coal roof are dominated by illite (Lupoaia quarry) and/or smectite (Husnicioara quarry), followed by kaolinite, and containing low percentage of chlorite. Clayey interbeds intimately associated with coals contain a kaolinite-rich fraction with little illite and smectite, and the underclays are characterized by abundant smectite with subordinate illite and chlorite. Fine 41 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai fractions separated from the thick sandy sequence of Husnicioara quarry show a ternary clay mineral assemblage with comparable percentages of kaolinite, illite and smectite. Geochemical studies revealed a clear transition from clays richer in alkalies and alkaline earths, characterized by low maturity index, to more aluminous rocks, with higher maturity index. The sequence is started by the clays included within the detrital units separating the coal beds, continues with coal roof clays, followed by underclays, and is closed by the clayey interstratifications contained by the coal seams. This succession corresponds, as was pointed out by Englund and Jorgensen (1973), to a transition from immature rocks, rich in feldspars, illite and chlorite, to more and more weathered clays, enriched in smectite and kaolinite. The wide mineralogical spectrum is the result of participation of three well-known mechanisms: inheritance (reworking), transformation and neoformation. These genetic processes interfered with variable intensity and extent in the course of time, controlled or influenced by local and regional changes of sedimentary conditions. Clay mineral assemblages included within the main detrital sequences resulted principally from reworking of clayey materials provided by a northern and north-western source area – the South Carpathians; for smectite-rich underclays, a substantial contribution of transformation and neoformation processes could be admitted, and for the kaolinitic clays included inside of coals, the neoformation (authigenesis) represents the main mechanism. Illite and chlorite are practically exclusively reworked, but for kaolinite and smectite, other additional mechanisms could be superposed. Thus, kaolinite was generated by neoformation processes, especially within the clays included in coals and sometimes in underclays (diagenetic) and within the sands (epigenetic). Smectite minerals can be reworked from older formations and/or neoformed at expense of volcanic ash provided by erosion of some Miocene tuff levels. As regards the high smectite concentration in underclays, diagenetic transformation of illite (and perhaps chlorite), typical for vertisols and underclays, should be taken into consideration. Differential transport and sedimentation processes could be also invoked. Smectite “invasion” evidenced in the whole sedimentary sequence cropping out in Husnicioara quarry suggests the interference of a second source area, richer in volcanogenic material, such as Badenian deposits, well represented westward and even southward (Timoc Valley zone). A peculiar case of mineralogical changes supported by clays is represented by the baked rocks (porcelanites and clinkers), generated in consequence of natural burning of the coal beds: primary clay and non-clay minerals are progressively replaced with hematite, cristobalite, mullite, spinel, tridimite, -cuartz, cordierite and magnetite. TRACE FOSSIL ASSEMBLAGES FROM SIRIU VALLEY TURBIDITES THE EASTERN CARPATHIAN FLYSCH Relu D. Roban 1, Bogdan L. Varban2, Nicolae Anastasiu1 1) University of Bucharest, 2) University of Western Ontario, Canada, Keywords: Ichnofacies, Turbidites, Carpathians The Tarcau Sandstone outcropping in the southern East Carpathians (Buzau Valley) consists of turbidite sequences of Eoceneage. Based on texture and physical sedimentary structures eight (F1F8) facies have been identified: non-organized rudites,amalgamated clast-supported rudites, matrixsupported arenite-rudites, grading stratified arenites, massive (non-organized)arenites, paralel stratified fine arenites, sand-mud couples, mudstones/limestones couples. In the 400 m of measured 42 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai section we separated two first order sequences (called here turbidite systems) consisting of different facies associations. The tracefossils described from each facies associations represent 18 ichnogenera and 23 ichnospecies (s. Ksiazkiewicz, 1970), belonging to different ethological classes (domichnia, fodinichnia, pascichnia, repichnia, agrichnia) (Pemberton , MacEachen1992). Ichnogenus Circulichnis and a fodinichnia graphogliptid are new occurrences in the Tarcau Sandstone and are described herein. The most common association is represented by predepositional suites (such as Paleodictyon, Spiroplycus, Spiroraphe, Megagrapton), and postdepositional suites (Ophiomorpha, Granularia, Scolicia, Planolites, Sabularia, Palaeophycos ) (Kern1980). Based on the distribution of species and species associations two recurrent ichnofacies were identified: Nereites and Zoophycos. The Zoophycos traces are mostly preserved in what we interpreted as turbidite channel environments, whereas the Nereites is very common in lobe and basin plain environments. These ichnofacies are conspicuous similar in both first order turbidite sequences (systems). There is no any clear indication of major water depth change, and we interpret the trace fossils distribution being primary related to local energy conditions (nutrient supply and oxygenation). PRODUCTION AND LOSS OF HIGH-DENSITY BATHOLITHIC ROOT - SOUTHERN SIERRA NEVADA, CALIFORNIA SALEEBY, J.* DUCEA, M. CLEMENS-KNOTT, D. Division of Geological and Planetary Sciences, California Institute of Technology, Mail Stop 100-23, Pasadena, CA 91125 Department of Geosciences, University of Arizona, 1040 E. Fourth St., Tucson, AZ 85721 Department of Geological Sciences, California State University, Fullerton, CA 92634 *Email: [email protected] Experimental studies show that when hydrous mafic to intermediate composition assemblages are melted in excess of 10 kb liquids typical of Cretaceous Sierra Nevada batholith granitoids are generated and garnet+clinopyroxene dominate the residue assemblage. Upper mantle-lower crustal xenolith suites that were entrained in mid-Miocene volcanic centers erupted through the central Sierra Nevada batholith are dominated by garnet clinopyroxenites which are shown by geochemical data to be petrogenetically related to the overlying batholith as its residue assemblage. The xenolith data in conjunction with an exposed oblique crustal section in the southernmost Sierra, as well as seismic data, form the basis for the synthesis of a primary 43 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai lithospheric column for the Sierra Nevada batholith. Critical aspects of this column are the dominance of felsic batholithic rocks to between 35 and 45 km depths, a thick (~ 35 km) underlying garnet clinopyroxenite residue sequence, and underlying garnet peridotite lithospheric mantle to ~ 125 km depths. The peridotite section appears to be the remnants of the mantle wedge from beneath the Sierran arc. The principal source for the batholith was a polygenetic hydrous mafic to intermediate lower crust dominated by mantle wedge derived mafic intrusions. Genesis of the composite batholith over an ~ 50 m.y. time interval entailed the complete reconstitution of the Sierran lithosphere. Sierra Nevada batholith magmatism ended by ~ 80 Ma in conjunction with the onset of conductive geotherm from beneath by flat slab subduction. Disruption of the cornerflow circulation of asthenosphere into the wedge environment by the Laramide slab is suggested to have been the prime factor in the termination of magma genesis. In the southernmost Sierranorthern Mojave Desert region the sub-batholithic mantle lithosphere, including the garnet clinopyroxenite residue sequence, was mechanically delaminated by a shallow segment of the Laramide slab, and was replaced by underthrust oceanic assemblages. These relations record a segmentation of the Laramide slab beneath the southernmost Sierra, similar to that observed beneath the modern Andes. Despite these Laramide events the greater Sierra Nevada mantle lithosphere for the most part remained intact throughout much of Cenozoic time. A pronounced change in xenolith suites sampled by Pliocene-Quaternary lavas to garnet absent, spinel and plagioclase peridotites, whose thermobarometry define an asthenosphere adiabat, as well as seismic data indicate that much of the remaining sub-Sierran lithosphere was removed in Mio-Pliocene time. Such removal is suggested to have arisen from a convective instability related to high-magnitude extension in the adjacent Basin and Range province, and to have worked in conjunction with the recent phase of Sierran uplift and a change in regional volcanism to more primitive compositions. In both the Mio-Pliocene and Late Cretaceous lithosphere removal events the base of the felsic batholith was the preferred locus of separation. This is suggested to have resulted from the sharp rheological contrast between weak quartzofeldspathic deep batholithic rocks, and the stronger and much denser residue sequence. Such phenomena may be of global importance in continent edge arcs, and responsible for the common Moho depths of 30 to 40 km observed in the derivative batholithic belts. This is also suggested to help fractionate and isolate the Earth's felsic crust in the long term. THE OCEAN FLOOR METAMORPHISM AND THE GENESIS OF SPILITES IN THE MURES ZONE, ROMANIA Haralambie SAVU Geological Institute of Romania, 78344 Bucharest 32, 1 Caransebeş St.; E-mail : geol@igr. ro Key words: Ocean floor metamorphism; Spilitization; Spilites; Mineral assemblages; Chemical composition. The ocean floor metamorphism of the Mures Zone ophiolites resulted from the incandescent lava/salt-water reaction1. It manifested itself at temperatures of up to 4oo0 C, and its characteristic mineral assemblage is: albite-chlorite-epidote-quartz-hematite. It is associated with the spilitization process, a reason for witch it was marked as the spilitic facies of metamorphism. Due to the high temperature, the ocean floor salt-water passed into very hot steam, that penetrated into basaltic lavas, which cooled as pillow lava and got steam-vesicles. At the same time, superheated steam and salt-water infiltrated the previously cooled lavas, altering their magmatic minerals, as follows: plagioclase was albitized; augite passed into pseudomorphoses of chlorite epidote iron oxides. 1 Savu, H. Metamorphic and metasomatic processes in the Alpine ophiolites from the Mureş Zone, Romania. Proc. Rom. Acad. Series B, vol 4 (in press) 44 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai These minerals, together with calcite, zeolite, and quartz, infilled the vesicles, too, it resulting in the amygdaloidal structure of spilites. The substances in excess have been antrained by the ocean floor salt-waters and released as limestone and red argillite beds and eventually iron deposits occurring now as intercalations among the spilite flows. WHAT IS CCZN-ARMALCOLITE? – A CRYSTAL-CHEMICAL DISCUSSION AND A PREDICTION Gavril SĂBĂU Geological Institute of Romania 1, Caransebeş St., sect. 1, RO-78344 Bucharest 32, e-mail: [email protected] Key Words: CCZN-armalcolite, crichtonite, close-packed oxides, CCP The term CCZN-armalcolite was created to encompass titanate phases very close in composition to minerals of the armalcolite-pseudobrookite series (Mg, Fe2+,Fe3+)(Ti,Fe3+)2O5, but containing essential Cr, Ca, Zr or Nb. Such compounds were initially identified in lunar samples (Levy et. al., 1972; Brown et al.,1972), but have subsequently been found also in a number of terrestrial occurrences, typically mantle rocks or mantle-derived igneous products. Though contents in small cations like Cr and Nb are considered important in distinguishing “CCZN-armalcolite” from normal armalcolites (Haggerty, 1973), it appears that the most significant difference is given by large cations as Ca (also K in the Argyle “K,Cr-armalcolites” Jaques et al., 1990), contained in proportions which rise the question of compatibility with the armalcolite lattice. Because small grain size prevented so far structural studies on “CCZN-armalcolites”, they are traditionally distinguished from chemically similar compounds on account of their relatively high TiO 2 contents, matching those of armalcolites. On the other hand, there are reports of titanates with CCZNarmalcolite composition, but which represent XRD-documented high-Ti loveringite, a mineral of the crichtonite group (Lorand et al., 1987;Wang et al., 1999). Normalising published analyses of “CCZN-armalcolites” and Ti-rich loveringites to A=1, according to the general formula AMxOy, where A represent large cations and M small ones, one obtains a consistent array placed at higher M/O ratios than armalcolite in the M vs. O plot. The plot is not essentially influenced by the Fe valence considered. This would result in even higher (A+M)/O ratios and proves inconsistency of “CCZN-armalcolite” compositions with an armalcolite formula. As compared to armalcolites, “CCZNarmalcolites” either display a denser overall metal coordination, or a certain degree of AO_ substitution, or both. Along the mentioned array, the plotted analyses tend to concentrate in well-defined clusters, extending over a wide range of A/M (or A/O) ratios, thus indicating that “CCZN-armalcolite” rather represents an artificial heading under which several different mineral phases have been inadvertently packed. High-Ti loveringites proven by diffraction plot well along the array, either in the cluster around the theoretical AM21O38 crichtonite point, or in a cluster immediately adjacent to it. The cluster containing the largest number of analyses plots, however, around the AM16O30 point. Considering that mantle titanates basically display three structural types, namely a pyrochlore-type lattice, channelled close-packed structures related to hollandite, and close packed ones with large cations substituting in some anion positions, the A/M ratio would indicate the last mentioned type for a compound with formula AM16O30. By analogy with similar groups like magnetoplumbites and crichtonites, the basic modules of the lattice would consist of: (a) layers with a large cation site similar to that in perovskite (CCP) or to that in BaTiO3 (HCP), surrounded by ternary bracelets (Moore, 1973) of octahedral clusters with trigonal symmetry, close packed with (b) structurally matching octahedral-tetrahedral layers which do not contain large cations. The best fit for the formula is given by a structure consisting of double layers which contain perovskite-type A sites surrounded by clusters consisting of three octahedra, joined by an additional octahedron (AM8O14), that alternate with double layers containing the same octahedral pattern, joined by tetrahedra (M8O16). The corresponding unit cell has a trigonal symmetry R(-3), is based entirely on a CCP stacking and contains 16 close-packed octahedral layers. Considering a layer thickness of ca. 2.3 Å, the resulting cell parameters are approximately ahex=5.98 Å, chex=36.8 Å. 45 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai EVIDENCE FOR A NEOPROTEROZOIC FORELAND BASIN AT THE SOUTH-WESTERN MARGIN OF BALTICA Antoneta SEGHEDI1, Gheorghe OAIE2, Magdalena IORDAN1 & Marioara VAIDA1 1 2 Geological Institute of Romania, 1 Caransebes st., RO-78344, Bucharest 32 Romania (e-mail: [email protected]) National Institute of Marine Geology and Geoecology, 23-25 Dimitrie Onciul St, RO-70318, Bucharest, Romaina Key Words: Foreland basin, Turbidites, Moesian Platform, Pre-Dobrogea Depression, Moldavian Platform, Vendian. Midfan and distal turbidites of Histria Formation (HF) exposed in an uplifted block of the Moesian Platform accumulated in the inner part of a foreland basin (Oaie 1999), as suggested by following evidence: deposition as deep water turbiditic fans in a basin floored by continental crust; location north of the northward vergent Neoproterozoic thrust wedge, preserved in the subsurface of South Dobrogea; a southerly located source area, indicated by paleoflow directions; great thickness of the succession (5000 m, as estimated from geological and geophysical data); overall upward coarsening facies association suggesting northward progradation of the source area; coarse member composition indicating both older continental crust, as well as volcanic arc input (such source area composition characterise continental margins dominated by active volcanic arcs); mixed sandstone petrofacies, suggesting sediment recycling (due to secondary, intrabasinal sources, represented by submarine highs related to thrust fronts); longitudinal sediment transport, frequent in foreland basins; deformation of the basin fill at 570 Ma (K-Ar WR) in very-low grade metamorphic conditions by northward verging, E-W trending open folds. Geological and geophysical data suggest that the depositional basin was floored by heterogeneous continental crust, made up of Middle Proterozoic metamorphic rocks (Altin Tepe Group) and by the Palazu Mare BIF. The southerly located active continental margin was probably the northern coast of Vendia with its Cadomian volcanic arc. The former was composed of gneisses and BIF, similar to those involved in thrusting. This is in good agreement with zircon provenance data that indicate an older, Svecofennian Baltican and Grenvillian age of the source area (1.5 Ga and 1.0-1.2 Ga, Zelazniewicz et al. 2001). The Late Proterozoic-Early Cambrian age of sediments is documented by palynological assemblages, as well as by a medusoid imprints (Nemiana simplex Palij) identified in the fine grained members of HF. Considering the HF the oldest, proximal member of a foreland basin succession, its shallow water counterparts should be found in areas located to the north. Along the southern margin of the EEP and overlying a Proterozoic basement (granitoids and diorites), a 2000 m thick Vendian succession is known from boreholes in the subsurface of the PreDobrogea Depression (PDD). Its Vendian age is indicated by the presence of Vendotaenia antiqua Grujilov. The Avdarma Series represents an upward coarsening and shallowing sequence of finegrained marine sediments, which grade upwards into continental red clastics (Neaga & Moroz 1987). Black shales rich in phosphate nodules are common. West of the Ukrainian Shield, in the Moldavian Platform, the Vendian succession dated on Nemiana simplex Palij directly overlies the Upper Riphean Cosauti Sandstone. In boreholes, the Vendian succession (about 350 m thick) contains Vendotaenia antiqua Grujilov. The Vendian is an upward coarsening sequence of red and purple mudstones and fine-grained sandstones-siltstones, topped by sandstones. Similar to the PDD, black shales with phosphate nodules are interbedded, indicative of shallow water depth and cold currents. Various evidence suggest that the Vendian successions from the margins of Moesia and East European Platform might represent distinct parts of the same large foreland basin, located in cold climate at aproximately 60o south latitude and floored by Baltican crust. The northward decrease in basin depth is acompanied by development of upward coarsening and shallowing sequences in the external parts of the basin and by decrease in intensity of deformation. Various parts of the basin were subsequently displaced along large-scale crustal faults during translations related to the formation of the Alpine belts. 46 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai NEW INVESTIGATION METHOD OF NATURAL SLIDING RISK IN MATASARI AREA - JILT COAL BASIN Florica STROIA1, Ion STOICAN2, Dumitru ION1, Marius MOCUTA1 1 University of Bucharest, Faculty of Geology & Geophysics,1,N.Balcescu Ave.,sect.1,RO-70111,Bucharest, e-mail:[email protected] 2 Diplomat Engineer in Geology, National company for Lignite "OLTENIA" Key words: fine loose sediments; coal's mechanical stiffness; sliding risk map. The hills "Dragotesti" and "La Rupturi" are contiguous to Matasari town, located to the half distance between Motru and Tg.Jiu and there are belonging to Getic Plateau relief. Geologic ages of the sediments are Dacian, Romanian and Quaternar. There are fine loose sediments: clays with sand and coal intercalation. The geological structure consist on a succession of anticlines and sinklines with small flanks bending angles: 2-3 0 to maximum 50. The first step to evaluation of natural sliding risk was a total estimation considering the slope equilibrium in context of simultaneous action of divers features: lithologic, geomorphologic, structural, hydrographic and climatic, hydrogeologic, seismic, anthropic. Starting from the potential and probability of sliding risk it was computed a global coefficient (Marghidanu,1998) whose value is 0,40. That means a medium towards high sliding probability. Map with equal slope surface zoning, made by computer from the whole area was another possibility to evaluate the sliding risk. Surfaces are representing in different colors, each of them corresponding to a certain slop angel associate to the suitable risk. In the sedimentary unconsolidation rocks succession, with sliding vulnerability, the lignite levels are in contrast because they're high stiffness. A main set and a cosset of fissures affected coals, bought with quasyvertically joint surfaces. As a result the thin coal layers are ease to carry away in slope sliding even on rainless seasons. We define as "minimum resistance surface" the surface make through joining the points in there drills are encountered the first lignite layer. There did make, by computer, tridimensional images with the topographic surface; isobathic map on minimum resistance surface; isopahite map with the sediments resting above those surface; map with slope tendencies. Finally by superposing all those it was made the sliding risk map. All of them are concerning with field elevation and drilling data made before coal exploitation is developed. The prognosis result is confirmed by recent field investigation. RECENT MICROFAUNA OF THE DANUBE DELTA SEDIMENTS - PALEOENVIRONMENTAL SIGNIFICANCE Marius STOICA University of Bucharest, Faculty of Geology & Geophysics, 1, N.Balcescu Ave., sect.1, RO-70111, Bucharest, e-mail: [email protected] Key words: Recent, fresh and brackish water, Ostracoda, Paleoecology. These paper present for the first time a micropaleontological association from recent sediments of Danube Delta. The material came from short cores extracted from main lakes of Danube Delta and samples from surface sediments of deltaic and littoral systems. The microfaunistical assemblage is dominated by ostracods that are the best microfossil for reconstruction of fresh and brackish paleoenvironments. In the studied samples ostracods are associated sometimes with foraminifers, gastropods, bivalves, bryozoa, fish tees and bones, otoliths and characea oogons. 47 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The micropaleontological analysis allows us to separate two types of faunas that are dependent of palaeoenvironment, the salinity being the most important factor: a fresh water fauna in the upper part of sediments and a brackish fauna in lower part. The fresh water fauna is dominated by Cypridacean ostracods that belong to Candona, Cypridopsis, Hetrocypris, Eucypris, Cypria, Cyclocypris, Ilyocypris and Darwinula genus. In the brackish fauna the Cytheracean ostracods with species of Cyprideis, Leptocythere, Heterocythereis, Loxoconcha, Xestoleberis, Pontocythere and Paracytherois genus are dominant. Based of facies fossils we can restore with great precision the salinity of the sedimentary paleonvironment that permitted us to reconstruct the evolution of deltaic system. ELECTROGRAPHY: A NON-DESTRUCTIVE METHOD TO INVESTIGATE THE RELATIONSHIPS BETWEEN MINERALS, ROCKS AND FLUIDS Dan SVORONOS1, Aneta BALABAN2, Adrian NICOLESCU1 1. Geological Institute of Romania, 78344 Bucharest, 1 Caransebeş st, E-mail: [email protected] 2. Prospectiuni S.A., 78344 Bucharest, 1 Caransebes nr. 1 Key Words: Electrographic images, Electoluminescence, Electrical structures, Water, Pores morphology Introduction Electrography is one of the most adequate non- destructive technique for the investigation of the internal structure/ texture of a large category of samples (biological , mineral, rock). The aim of this paper is to present basic data regarding the problems of interpreting the bright manifestations of the minerals and rocks in relation with water or other liquids, investigated by this method. Short presentation of the method The device (Petroelectrograph II) is the monoimpulses electric generator, with values of the tension between 8 and 55 kV, 2500 Hz ( the reference frequency) and 0.2 ms duration of the obtained impulse. The impulse (mono) is applied on a capacitor, created between the rock sample and the electrode. The electrode can have a positive or negative charge. As a result, in our system a positive or negative impulses can be used to produce corresponding positive or negative outputs and images. The working device of this technique consists in putting a special film, AZOIX-RXR-2, blue sensitive, on a dielectric surface (glass) in direct contact with the under bottom of the analyzed sample and placing this “sandwich” in electrical circuit of the device. Electrography principle Our research with many types of minerals (micas, granular and fibrous large gypsum, quartz), rocks in geometrically cut forms or modeled clays, in relations with different fluids (pure or mineralized water, oil) has partially emphasized a very spectacular aspect, similar to the images with “the Kirlian aura ”( the images by special technique, of the radio- frequency electric fields). The recorded effects are the result of some complex phenomena .The image analysis carried was out using the computer. The luminescent impressions (the samples aura) express the characteristics of the pore morphology and the mineral/rock-fluid relationship in connection with very fine chemical peculiarity and volume of fluids. The images (anode / cathode electric discharge – graphic images) can be ranked in the following way; from the viewpoint of “luminescent aura amplitude” and streamers’ morphology for each group of minerals or rocks, characterized by an ionic conductivity. Summary of the results and conclusions The outlined streamer patterns mainly reflect the energetic equilibrium ratio between the samples and the surrounding environment. 48 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The investigations point out the following aspects: mineral/rock-water-air relation in the process of infiltration/ex-filtration; laminar flow in porous media; quality of a collector for fluids; quality of water solution in minerals and rocks. We may add the following conclusions: The electrography for rocks (petroelectrography) does not imply the destruction of the rock samples; The petroelectrographic images are related to the free water (or various fluids) content and to the physically weak linked water in the rock pores. GYPSUM IN RELATIONSHIPS WITH FLUIDS: ELECTROGRAPHIC IMAGES Dan SVORONOS 1, Aneta BALABAN2, Adrian NICOLESCU1 Geological Institute of Romania, 78344 Bucharest, 1 Caransebeş st., E-mail: [email protected] 2 Prospectiuni S.A.,78344 Bucharest,1Caransebes st. 1 Key Words: Electrographic images, Electoluminescence, Electrical structures, Water, Pores morphology Introduction The variable porosity of the gypsum samples are considered the best to spotlight the relationship between rocks and fluids. Our contribution to prove this process is based on the electrographic technique – a nonconventional analysis method. Technical aspects of the experimental investigation Laboratory standard conditions: temperature 25020 C; temperature of solution l8020 C; atmospheric pressure: 76o mm Hg. The samples typology: granular gypsum: mono-mineral rock ; fibrous gypsum : mono-mineral rock; gypsum-powder: mineral association – gypsum-anhydrite-quartz-argillaceous minerals-chlorite; chemical specific of sample CaSO42H2O– 95,15 %; SiO2 – 1,02 %; Al2O3 – 0,45%. The solution used was de-ionized water, and sometimes another fluids (NaOH, HCl, in various concentrations). The device used (Petroelectrograph) is mono-impulses generator characterized by variable tension varying 8-55 kV, the reference frequency 2500 Hz and 0,2 ms duration of impulse. Results Electrographic images recorded on the film (AZOIX-RXR-2) suggest a clear relationship between the rock structure/texture and contained fluids. The dried samples showed not streamers “aura”. A presence in images of a very large streamers “aura” is equivalent to a strong saturation in fluids and a significant porosity. The morphology of the streamers is dependent on the pores morphology and the geochemical feature of the used rocks and fluids. The perturbation in the obtained images, dried samples or fluids saturated, represent the migration velocity of the fluids, a process dependent on many parameters. There have been obtained by each experiment two images: positive and negative (values of the electric field). Usually, the positive images are analyzed by color-trace-mode (with linear or arbitrary color variation). With help of a computer, such as in our own methodology, many unseen details have been revealed. The difficulty in interpreting the electrographic images taken into account is represented by the control of the quantity of received/given water by the rock during the experiment. 49 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Conclusions In this study we presented the migration of the fluids in rocks using the method operating in the image domain. The following aspects have been investigated: the process of infiltration of fluids in gypsum; the relationship between samples and acid/basic fluids. Our method is based on the special non-conventional technique. A PROPOSAL FOR A GEOCHIMICAL MAP OF ROMANIA Constantin SUCIU, Ion IONEL, Dorina IONEL, Adrian BIŢA S.C. PROSPECŢIUNI S.A., 1 Caransebeş St., 78344 Bucharest, Romania E-mail: prospec1 sunu.rnc.ro These days pollution problems national priorities in the world, as well as the necessity of base metal contens knowledge in environment, determined many countries or international organizations to promote regional geochemical mapping programs. These maps illustrate the distribution in surface, in different sampling targets, of different metals with economic concentration or environmental value very useful in the following domains: petrogenetical districts limitation, with low elementary variability, from metallogenetical districts with high natural variability; rich content heavy metals values zones limitation caused by pollution; useful base data for epidemic statistic studies conceming some degenerative human, animals or crops diseases. In the last decade the envinmental protection and rational utilization concept, as a fundamental component of development projects, was determined on a national and international level. Thus, to adopt the scientfic fundamental measures for lithosphere and hydrosphere protection, UNESCO and UNEP promoted two interdisciplinary projects: The protection of lithosphere as an envinment component (1979-1984) Geology and environment (1984). The major conclusion of the projects is that the environment utilization has to control the geological atlases and maps on various scales (Austria, Finland, Norway, Germany, United Kingdom, Sweden etc.). Unitary projected, those reserches followed many elements or components in differet targets (rocks, soils, superficial and underground waters, stream sediments from riovers and lakes, or vegetation), at sampling scales to cover largest part or entire teritory of a country. Generally, the regional geochemical maps elaboration was coordinated in the last decade by the European Geological Reserch Forum (FOREGS), by a special domain works froup (RGM). This group elaborated a three-year (1988-1990) project for drawning up regional geochemical maps by using a low density of collecting samples. This program objectives were to prepare elaboration of a regional geochemical maps set for the whole Westwrn Europe and to establish the limits of using only the samples from sediments to working out these maps. Although our program for drawning up regional geochemical maps, is not yet integrated in the European institutions, the achievements are, at least, noteworthy. During six years, there were collected from an about 5,800 sq. km area a number of 23,500 soil samples, 8.750 roks samples, 3,852 samples from the fine fraction of the present sediments, 3,250 plant samples and 1,340 samples from springs and active water flows. All the samples were analyzed for 20 elements by spectral methods (in emission, absorbtion or plasm I.C.P.), and the data were interpretated according to apllied geochemistry criteria. Using heavy metals values, the maps of their distribution in the sample media were drawn up. 50 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The field working methods were based on the recomandations of Lowering et al. (1950), Rope, Howks and Weeb (1981), garrett and Nichol (1967), Grigorion and Bens (1967), Morozov and Sokilov (1981), concering sampling representativity and reproductibility aspects. The data obtained as a result of heavy metals distribution processing and comparison on sampled areas are extremely suggestive and important for the further regional geochemical maps drawning up programs. Thus, the following were established: - the main mineralized and potentially mineralized areas were delimited, using lithogeochemical, pedogeochemical and stream-sediments samples; - the contaminated areas were outlined, mainly by mising work, using stream-sediment and water samples; - the plants biogeochemical changes, due to theexcessive presence of some heavy metals, were performed; - the plants biogeochemical migration aspects, in different media, of some noxious metals (Pb, Cd, As) could be compared; - an optimal, strict and efficient methodology for elaboration of a geochemical maps atlas for the whole Romanian territory was estabilished. MINERAL REACTIONS ON KYANITE IN ECLOGITES FROM THE PORTILE DE FIER UNIT Marin ŞECLĂMAN, Gelu COSTIN, Anca LUCA, Péter LUFFI University of Bucharest, Faculty of Geology & Geophysics 1. Bălcescu Blvd., sect.1, RO-70111, Bucharest, e-mail: [email protected] Keywords: eclogite, kyanite, symplectite, coronitic texture, metasomatic reaction, melt, incongruent crystallization, Portile de Fier Unit Kyanite crystals from the eclogites of Porţile de Fier Unit are frequently replaced by various mineral phases forming coronitic textures. Substitutions have been realized by capturing of ionic groups by the kyanite according to the following reaction: Kyanite + Mn+ + n(OH)- B H2O, where Mn+ = Ca2+, Mg2+, Fe2+, Na+, K+, Si4+ and B symbolize the phases formed on the kyanite. Water formed by this reaction may be preserved as inclusions in the B phases or expelled. The most important reactions are: 2Kyanite + Ca2+ + 2(OH)- Anorthite + Corundum + H2O (1) Kyanite + Ca2+ + Si4+ + 6(OH)- Anorthite + 3H2O (2) 2+ 2+ 2+ 2Kyanite + Ca + (Mg , Fe ) + 4(OH) Anorthite + Spinel + 2H2O (3) + 4+ Kyanite + 2Na + 5Si + 12(OH) 2Albite + 6H2O (4) Kyanite + 2K+ + 5Si4+ + 12(OH)- 2Kspar + (5) + 4+ 3Kyanite + 2K + 3Si + 14(OH) 2Muscovite + 5H2O (6) + 6Kyanite + 2K + 2(OH) 2Muscovite + Corundum (7) 3Kyanite + 2K+ + 6(Mg2+, Fe2+) + 14(OH)- 2Biotite + 2Corundum + 5H2O (8) + 2+ 2+ 3Kyanite + 2K + (6+n)(Mg , Fe ) + (8+n)(OH) 2Biotite + Spinel + (n)Corundum +(4+n)H2O (9) Kyanite + K+ + 3(Mg2+, Fe2+) + 2Si4+ + 14(OH)- Biotite + 6H2O (10) The assemblage anorthite+corundum±spinel+H2O is certainly formed at high temperatures. In some cases reaction (1) may be coupled with the zoisite breakdown reaction: 2Zoisite + 2Kyanite Anorthite + Corundum + H2O The equilibrium of this reaction has a positive slope in the P-T field, above an invariant point at 700°C and ~9Kbars. By cooling, the assemblage anorthite+corundum+H2O should break down to margarite. However, in absence of the necessary water this reaction occurs rarely. 51 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai At crystal-scale, all the above-described reactions are metasomatic, implying a ~30% volume increase for their solid terms. The source of the ions involved in the reactions (2) to (10) is very likely a hydrous silicate melt. These reactions are believed to describe an incongruent crystallization from a hydrous liquid: Liquid(1) + Solid(1) Liquid(2) + Solid(2), with Vr=0. The final crystallization leaded to the forming of an amphibole-plagioclase symplectite, reducing significantly the activity of water. Therefore the metastable preservation of the assemblage kyanitefeldspars-corundum-spinel became possible. GRANITOIDE INTRUSE ÎN COMPLEXUL BAZIC DIN VALEA CUMPĂNA MINERALOGIE ŞI POSIBILE SEMNIFICAŢII GENETICE Mircea TOPÂRCEANU (anul III) Îndrumător: Lect. Dr. Gelu COSTIN Corpul granitoidic (granite, granodoirite), cu aspect pofiroid, apar intruse în rocile metamorfice bazice (amfibolite cu granat, meta-gabbrouri) din bazinul Văii Cumpăna (M-ţii Făgăraş). Lucrarea prezintă date preliminare privind mineralogia acestor granitoide, succesiunea posibilă de cristalizare magmatică precum şi tipurile de transformări subsolidus. Deformarea penetrativă a acestor corpuri (dezvoltarea unui fabric liniar – planar) precum şi tipurile de transformări subsolidus, arată o punere în loc a granitoidelor în condiţii PT de stabilitate a granatului, apoi o evoluţie post răcire şi depresurizare (biotit crescut pe granat, pertite de exsoluţie controlate de deformare, pertite de substituţie, myrmekite). Evoluţia asociată depresurizării estimăm că este comună cu cea a complexului bazic. Geneza magmelor granitoidice este presupusă a fi legată de procesele sincolizionale hercinice. THE ESSENTIAL ROLE OF THE VALACH CLIMATIC CYCLE (4,1 M.Y.) IN THE OCCURRENCE AND DEVELOPMENT OF THE SENONIAN AND CAINOZOIC COAL FACIES IN ROMANIA Mircea TICLEANU1, Nicolae TICLEANU2, Paul CONSTANTIN1, Simon PAULIUC1, Florian MARINESCU2 1 - Geological Institute of Romania, 1 Caransebes street, 78344 Bucharest; E-mail: [email protected] 2 - Faculty of Geology and Geophysics, Bucharest University1 Blvd. N. Balcescu, 70111 Bucharest; E-mail: [email protected] Key words: Valach climatic cycle, coal facies, generating coal stages, Quaternary glaciation, Senonian, Cainozoic, Romania. The detailed study of Pliocene coal facies from the western side of the Dacic Basin leaded to the idea of a climatic cycle ("The Valach Cycle" - nom. nov., Praga, 1998, M. Ticleanu et al.), with a period of about 4,1 m.y., responsible for the Neogene coal complexes occurrence. The warm periods of this climatic cycle, due to the same possible pulsations of the Solar system (named "Valach pulsations") leaded to the appearance of the coal facies. The cool periods were not favourable for these, the last cool period of the Valach cycle practical corresponding to the Quaternary glaciation. The analyses of coal bearing Palaeogene formations from Romania allowed to distinguish other three distinct generating coal stages. Thus, from Uppermost Eocene to Pliocene one can notice 52 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai the following generating coal stages: 1) Priabonian-Lowermost Rupelian; 2) Middle Rupelian; 3) Lower Chattian; 4) Uppermost Chattian; 5) Middle Burdigalian; 6) Badenian; 7) Middle Sarmatian; 8) Middle Pontian; 9) Pliocene (Upper Dacian- Lower and Middle Romanian). All these can be illustrated by the coal deposits from Romania. Considering the Thanetian generating coal stage (Uppermost Palaeocene from Paris and Pannonic basins), we could approximate the stratigrafical levels of the other four Eocene generating coal stages (illustrated by the coals from Western Europe and Russian platform): Ypresian, Lower Lutetian, Upper Lutetian and Bartonian. The characteristic features of the first two generating coal stages (Ypresian and Lower Lutetian) are the great thickness of the coal layers but their smaller extension and, for the last two stages (Upper Lutetian and Bartonian) are the coal layers with smaller thickness but a large extension. The period of the Valach cycle is confirmed by the stratigraphical position of the Senonian generating coal stages from Rusca Montana, Rosia and Vad-Borod basins. We could notice only one generating coal stage (Santonian developed in Vad-Borod Basin) versus two generating coal stages (Lower and Middle Maastrichtian developed in Rusca Monta and Rosia basins). Other Campanian generating coal stages are known from the Rhone Basin. Three stratigrafical levels between Middle Maastrichtian and Thanetian might be illustrated by generating coal stages (Upper Maastrichtian, Lower Danian and Selandian) but these seem to be hidden by the superposition of a strong cool period of another cycle, superior in order one (the Galactic Cycle). This data permitted us to appreciate that the Valach cycle can be justifed, through the alternance of coal facies with cool periods, on a span of time of about at least 86 m. y. ASOCIATIA DE SPONGIERI JURASICI DIN VALEA CHECHIRGEA (DOBROGEA CENTRALA) Daniel UNGUREANU (anul III), Eugen BARBU (anul IV) Îndrumător: Prof. Dr. Aurelia Barbulescu Lucrarea de fata este o continuarea a studiului nostru realizat in Valea Chechirgea si prezentat cu ocazia celui de-al III – lea Simpozion National al Studentilor, Iasi 18 – 20 aprilie 2002. Vom urmari aceleasi criterii de analizare a distributiei spongierilor: a) criteriul dimensional, morfometric – studiu static pe exemplare complete (observatii in situ si pe material colectat) si fragmente recuperate – rezultatele studiului bazate acest criteriu vor fi exemplificate prin material ilustrat; b) criteriu taxonomic – statistic; Vor fi prezentate rezultate obtinute cu ocazia ultimei deplasari de pe teren; continuarea studiului din punctul ramas pina la Valea Scrofeni, Valea Cumpana; Vom evidentia trecerea de la faciesul de spongieri la faciesul de corali, cu urmarirea genurilor si modului in care se face aceasta trecere. De asemenea, vom incerca elaborarea unui model matematic de incadrare sistematica luind in calcul diversi parametri cum ar fi: densitatea porilor, dimensiunile exemplarelor complete (inaltime, dimeniunea osculului, grosimea peretelui) etc. Localizarea pe afloriment prin realizarea unei schite cit se poate de complete in punctele in care abundenta spongierilor sau diverse relatii paleoecologice sint mai evidente. Completarea graficului de distributie a genurilor de porifere si a tabloului sistematic. CLAY FRACTION OF ARGILLIC BROWN SOILS FROM THE PIŞCHIA AREA, TIMIŞ COUNTY 53 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Stela URUIOC Banatului University, Timişoara This paper presents a study concerning the mineralogical composition of argillic brown soils clay fraction from the Pişchia area. The soil horizons samples were analysed in the polarising transmission microscopy, electron transmission microscopy, infrared absorption spectroscopy, and X-ray diffractommetry. The clay minerals identified in the clay fraction of these soils were smectite (montmorillonite), illite and kaolinite. The quantitative variations of the clay minerals (illite, illite/smectite, smectite, illite/chlorite, chlorite/smectite, kaolinite) along the entire profile may have been caused by the initial non-uniformity of the parental material and by pedogenetic processes, as well. STRUCTURA DEPOZITELOR PALEOGENE SI MIOCEN INFERIOARE DIN NORDUL BAZINULUI TRANSILVANIEI DEDUSA DIN DATE SEISMICE Iuliana VASILIEV (masterand) Acest studiu isi propune interpretarea geometriei depozitelor paleogene si miocen inferioare din cadrul Bazinului Transilvaniei. Au fost folosite 24 de sectiuni seismice de reflexie si date din 23 de sonde sapate in zona studiata. Datorita calitatii exceptionale a sectiunilor seismice a fost posbila separarea diferitelor formatiuni din cadrul intervalelor de timp studiate. Pentru Eocen au putut fi separate Formatiunea de Jibou, Formatiunea de Racoti, Formatiunea de Turbuta. In cadrul Oligocenului au fost urmarite Formatiunea de Ileanda si de Valea Carelor. Miocenul se distinge prin Formatiunea de Hida si Formatiunea Tufului de Dej. Din interpretarea sectiunilor seismice reiese faptul ca, in Bazinul Transilvaniei, exista structuri si discordante importante la toate nivelele stratigrafice. Aceste structuri si discordante sunt concomitente cu structurile si discordantele din intreaga arie carpatica. Acestea au influentat morfologia bazinului, natura depozitelor sedimentare si extinderea lor. Acestea sunt concluziile preliminare ale unui studiu mai amplu care se va materializa in realizarea lucrarii de dizertatie. TRANSFORMARILE MINERALOGICE OBSERVATE IN SONDA K 8, IN PROCESUL COMBUSTIEI SUBTERANE A HIDROCARBURILOR, SUPLACU DE BARCAU Viorel - Eugen VASILIU Oil and gas University of Ploiesti, 28 Bucuresti Ave., ro-2000. The paper reviews the main mineralogical transformations that could be detected by optical microscope analyses, X-ray analyses, electronic microscopy and spectral analyses. It could be thus noticed, by a parallelism with the data obtained from the cores taken of well 474, a pronunced diminishing of the calcite content, argillization processes of the feldspars, the creation of a real fracturing system, aragonite disappearance, montmorillonite transformation in illite and micas as well the occurence of new minerals as wollastonite, wairakite and scapolite in K 8 well. It must be also mention the organo-minerals presence, the thread-shaped "semi-coke" forms. STRIKE-SLIP FAULT SISTEMS IN THE CRYSTALLINE-MESOZOIC ZONE EAST CARPATHIANS (ROMANIA) 54 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai Alexandru VODA PROSPECTIUNI S.A., 78.344-Bucharest, 1 Caransebes st., E-mail: [email protected] The Crystalline-Mesozoic Zone (East Carpathians) is limited at south by a very important strike-slip fault – the South Transylvanian Fault, which opposes the Garbovei crystalline rocks from Persani Mountains and the crystalline rocks from North-East Fagaras Mountains. The Garbovei crystalline rocks form the basement of a frontal ramification of the Bucovinic Nappe and the eastern edge of the Fagaras Mountains contains Austrian and Mediterranean structural units from South Carpathians. The Crystalline-Mesozoic Zone of Eastern Carpathians is crossed from Vladeni gorge up to the northern border of Romania, by lots of strike-slip faults as follows (named from north to south): Vaser Fault, Dragos Voda Fault, Crucea-Zugreni Fault, Darmoxa-Grinties Fault, North Persani Fault, Garbova Fault. A geotectonic analysis including evidence from the western side, under the post-tectonic sedimentary deposits of the Transylvanian Basin, offers an interpretative model in which the mentioned faults form two systems of strike-slip faults: a) the senestral strike-slip fault system connected to Dragos Voda Fault b) the dextral strike-slip fault system formed by the Persani Mts. faults connected to the South Transylvanian Fault. The Vaser Fault limits the Vaser crystalline at SSE, the Miocene retro-overlapping from the Maramures Mts. north and Southwards of Black Flysch from the Crystalline-Mesozoic Zone border. South-westwards it is connected with Dragos Voda Fault and is senestral. The Dragos Voda Fault is an EW one and continues the transcrustal Bogdan Voda Fault, limiting southwards the Rodnei Mountains elevation. Eastwards of Carlibaba is difficult to be marked. The moderate effects of strike slip between Carlibaba, Tatarca and Breaza suggest its continuity south eastwards of Ciocanesti, then on direction of Crucea-Zugreni Fault up to Brosteni. The Crucea-Zugreni senestral Fault, followed northwards of Lesul Ursului Mining Field, divides tectonic entities with different compositions and structures. Its correlation with BogdanDragos Voda Fault gives sense to the Rodnei Mountains and Bistritei Mountains structure. The Darmoxa-Grinties Fault and its possible prolongation southwards of Rodnei Montains to Preluca Mountains, limited, northwards up to Dragos Voda - Bogdan Voda – Borsteni Fault, the tectonic compartment of Rodnei Mountains and the southern side of Bistritei Mountains, striked eastwards. The North Persani Fault is deduced as the northern limit of an area covered by a upper Aptian post-tectonic cover. By geophysical data it continues westwards under the sedimentary deposits of thr Transylvanian Basin, marking the magnetic anaomaly decreasing southwards of Tarnava Mare River. The North Garbova Fault, in southern part of Persani Mountains, put in contact Garbova ramification of Bucovinic Nappe with Transylvanian Nappes from Persani Mts., by eastwards movement of the northern compartment. STRUCTURAL FEATURES USED IN THE MAPPING OF METALLOGENIC FIELDS FROM CRYSTALINE-MESOZOIC ZONE OF EAST CARPATHIANS (ROMANIA) Alexandru VODA PROSPECTIUNI S.A., 1 Caransebes st.,78.344-Bucharest, E-mail: [email protected] 55 Societatea Geologică a României - www.geo.edu.ro/sgr GEO-2002 – Sesiunea ştiinţifică anuală, 24-25 mai The metallogenic studies on large scale impose as obligatory the analysis of geotectonic context from major structural unit, where the mineral ores exist. Taking into account the main elements which define the metallogenic frame –mineralization type, mineralogical definition, geochemistry, deposition type, place and timing – is difficult to correlate global metallogenic provinces. The synthesis of Crystalline-Mesozoic zone from East Carpathians evidenced that the structural elements which bound singenetic pre-alpine ores on major scale are: (a) in deep – nappe surface , (b) in length – strike sleeping faults. The major strike sleeping faults explain the interruption of Balan, Lesu Ursului and Fundu Moldovei metallogenic fields. The connection between the mineralized zoned areas and their ultimate geotectonic evolution is evident for alpine epigenetic ores (barite, base metal, uranium etc.). The barite ore (Ostra type) and the uranium ore (Crucea type), in opposite geotectonic context, but in the same external side (eastern) of protoBucovinic Realm – the generator of the Bucovinic Nappe frontal ramifications, offer the best example. The correlations between some ores from the Crystalline-Mesozoic zone of the Eastern Carpathians and similar ones from the South Carpathians are suggestive. For example, the base metal ores from Muncelu Mic of crystalline Pades Group could be correlated with the ones from Lesu Ursului if the pre-alpine Putna unit would be accepted as a correspondent of Gladna unit from Poiana Rusca Mountains and the Rodna unit would correspond with Hunedoara Nappe (in limestones from Fagaras Group from Fagaras mountains lead-zinc mineralizations Blaznei type exist). The base metal ores from the East Carpathian Crystalline-Mesozoic zone Tulghes Group could be correlated with the Gemerides East Carpathians Smolnic ones, each ones in opposite structural position on the Major Tethysian suture. This correlation suggests that the Transylvanian Tethys spreading crosscut some pre-alpine metallogenic unitary zones. 56