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omi.qxp 3/20/2009 8:26 AM Page 2 Of Material Interest Metallurgical sleuthing sheds light on Viking trade routes, swordsmithing, & counterfeiters I Although beautiful, this sword from the Germanic National Museum, Nurnberg, Germany, is a made of a low-carbon steel and is a contemporary counterfeit. The inscription is +VLFBEHT+. Credit: Alan Williams n the Middle Ages, there were two techniques for making steel for swords. Europeans used the bloomery process of heating iron ore with charcoal and chemically reducing it into a solid mass of metal and slag known as a bloom, which consists of iron, slag, and steel. The steel portions had to be separated from the bulk of the bloom. In Asia steel was made by the crucible process which involved heating pieces of bloomery iron for days in sealed crucibles with a carbon-containing material until enough carbon had been absorbed for steel to be formed as a liquid and easily separated from the slag. A collaboration between scientists at the National Physical Laboratory (NPL) in Teddington, U.K. and curators at the Wallace Collection, London, U.K. provided evidence revealing that the West has imported steel from the East at least since the Middle Ages when the Vikings brought high-carbon crucible steel back from Central Asia. About 100 Viking-era swords bearing the maker’s inscription, +VLFBEHR+T (for Ulfbehrt), have been found scattered around northern This authentic Europe (see map). Using a highly calibrated scanning electron Ulfbehrt sword was microscope, NPL microscopists analyzed the structures and made of a very carbon contents, and determined that the swords were made of high-carbon steel imperfectly melted steel consisting of a mixture of iron and (~1.4% C) and would have been very carbonaceous materials heated together to give high-carbon hard. It is from the steel. NPL’s results match descriptions of ancient sword Wurttemberg making in Herat (now in Afghanistan) described by ninth Landesmuseum, century Arab philosopher and writer Al-Kindi. This information Stuttgart, Germany. links to a known Viking trade route down the Volga and across The maker’s the Caspian Sea to Iran; however, until now it was not known inscription is that Vikings had brought +VLFBERH+T. crucible steel back to Credit: Alan Scandinavia and integrated Williams ancient Arab steelmaking methods with their own swordsmithing. Because the swords forged from crucible steel were the best available by far, enterprising counterfeiters would have been very tempted to replicate the swords, perhaps by welding small pieces of bloomery steel onto a billet of iron and forging it into a blade before quenching. The sharp edge that could be formed might deceive less discerning customers, but with a depth of only a few millimeters, the sword would not have survived many sharpenings. The inferior versions were sometimes inscribed to help convince the gullible; however, similar to modern-day counterfeits, the markings were often misspelled. Acknowledgments: Dr. Alan Williams, Wallace Collection, London, U.K. and Mr. Tony Fry, National Physical Laboratory, Teddington, U.K. Viking trade routes and locations of Ulfbehrt sword discoveries. Credit: Alan Williams 4 For a scholarly article on the history and metallurgy of medieval Viking swords, see Williams, Alan, “Crucible steel in medieval swords” in Metals and Mines, edited by S. LaNiece, D. Hook, and P. Craddock (Archetype Press with the British Museum, London, 2007), 233-241. ISBN 978-1-904982-19-7. For more information visit www.npl.co.uk or www.wallacecollection.org. ADVANCED MATERIALS & PROCESSES/APRIL 2009