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How Atoms Differ Learning Objective • Explain the role of atomic number in determining the identity of an atom. • Define an isotope. • Define an ion. • Calculate the number of electrons, protons, and neutrons in an atom, isotope, or ion given its mass number and atomic number. The Electron and Proton • J.J. Thomson discovered the electron while conducting an experiment with the cathode ray tube (vacuum tube) • Ernest Rutherford discovered the positively charged nucleus during his gold foil experiment. The Neutron • James Chadwick showed that the nucleus contained a subatomic neutral particle, called the neutron. • A neutron is a subatomic particle that has a mass nearly equal to that of a proton, but carries no electric charge. Summary of Atomic Structure proton electron neutron Charge: Charge: Charge: Location: Location: Location: Mass: 1 Mass: 1 Mass: 𝟏 𝟏,𝟎𝟎𝟎 of proton and neutron The Atom • The smallest particle of an element that retains the properties of the element is called an atom. • A molecule forms when two or more atoms form a chemical bond. • A compound is a molecule that contains at least two different elements. Dalton’s Atomic Theory Write this table on page 103 of notebook Correct 1. All matter is made up of atoms. 2. Atoms are indivisible and indestructible. 3. All atoms of an element are identical. 4. Atoms of different elements are different 5. Compounds form when atoms of different elements combine 6. Chemical reactions involve rearranging atoms, not change in the atom. Incorrect Isotopes • Dalton was incorrect about atoms being indivisible and in stating that all atoms of an element are identical. • All atoms of an element have the same number of protons and electrons, but the number of neutrons might differ. Isotopes • Atoms with the same number of protons but different numbers of neutrons are called isotopes. Dalton’s Atomic Theory Correct 1. All matter is made up of atoms. 2. Atoms are indivisible and indestructible. 3. All atoms of an element are identical. 4. Atoms of different elements are different 5. Compounds form when atoms of different elements combine 6. Chemical reactions involve rearranging atoms, not change in the atom. Incorrect Atomic Number • The number of protons in an atom identifies it as an atom of a particular element. • The number of protons in an atom is referred to as the atomic number. Atomic Number • Because all atoms are neutral, the number of protons and electrons in an atom must be equal. • Atomic number = number of protons = number of electrons Isotopes and Mass Number • Each isotope of an element is identified with a number called the mass number. • The mass number is the sum of the atomic number (or number of protons) and neutrons. • Mas number = atomic number + number of neutrons Isotope Notation Identifies a specific isotope mass number protons + neutrons atomic number # of protons (= electrons) Learning Check • Determine how many protons, neutrons, and electrons each of the following isotopes of chlorine has: – 35 17 Cl 37 – 17 Cl Learning Check • An atom has an atomic number of 9 and a mass number of 19. Determine the number of each of the following: – Protons – Neutrons – Electrons Atomic Mass • The existence of isotopes means that atoms of an element can have several different masses. • Atomic masses are decimal numbers on the periodic table because the atomic mass is the calculated average mass for the isotopes of an element. Element Notation atomic # # of protons (= # of electrons) element symbol element name atomic mass protons + neutrons Calculated average mass for the isotopes of an element Add this to your diagram Calculating Subatomic Particles Ape tomic number A____________________ = rotons P____________________ = E_____________________ electrons Man M____________________ ass number - (minus) tomic number A____________________ = eutrons N_____________________ Ions • Atoms can gain or lose one or more electrons to form ions. • An ion is an atom (or group of atoms) that is electrically charged as a result of loss or gain of electrons. Ions • If an atom gains one or more electrons, it becomes a negatively charged ion called an anion. • If an atom loses one or more electrons, it becomes a positively charged ion called a cation. Cat-ions are pawsitive! Learning Check • Determine the number of protons, neutrons, and electrons in the following ions: – Li+ – N-3 Homework: Atomic Structure worksheet Attach to page 107 in notebook Element Atomic Atomic Mass Protons Neutrons /Ion Number Mass Number H H+ 12 C 6 Electrons