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Chapter 3: Atomic Structure Objectives Describe the Historical evolution of the atom List the isotopes of Hydrogen and their properties. Describe and find critical problems of the Dalton atom, Calculate average atomic mass the plum-pudding atom, and Rutherford’s atom Calculate and perform molar conversions Describe Thompson’s and Rutherford’s experiments Write and interpret two isotope notations A. Aristotle vs. Democritus Aristotle Democritus Winner:____________________ B. Dalton’s Atomic Theory Theory The invention of the _______________ led to better experiments. Dalton’s Atomic Theory: 1) All Matter is composed of ___________________ 2) Atoms of a given element are _______________________ in size mass and properties 3) Atoms cannot be subdivided, _____________________________________ 4) Atoms combine in __________________________________to form compounds 5) In chemical reactions atoms are _____________________________________ Problems Problems with Dalton’s Theory: Dalton Atom The Democritus/Dalton Atom: 1 Dalton’s ideas still around Dalton’s Ideas that are still believed: _________________________________ Matter cannot be created or destroyed in any process __________________________________ When elements combine, they do so in simple whole number ratios. Examples: __________________________________ When two elements combine two or more ways to form different compounds, they still form in simple whole number ratios Examples: C. JJ Thompson & The electron Label the parts and cathode rays Show effect of negative charge What was discovered: __________________________ Thompson’s Atomic Model: __________________________ Sketch: D. Rutherford and the nucleus Sketch of experiment: 2 Observations: Rutherford had discovered the _________________. Conclusions Conclusion: More than _______ of the mass of an atom is located in the _______________. The atom is more than _______ empty space. Rutherford model and flaw The Rutherford Model of the atom: MAJOR FLAW: E. Protons, Electrons, Neutrons Particle Symbol Charge Mass Location Atom’s mass comes from ___________________________ or __________________. Atom’s volume comes from ___________________________. 3 F. Isotopes Isotopes are different forms of the same __________________ But have a different _____________ or number of ___________________. Designating Isotopes Hyphen Notation Nuclear Symbol Generic Examples G. Isotopes of Hydrogen Hyphen Notation Nuclear Symbol Other name # Protons # Neutrons Mass amu Mass = H. Average Atomic Mass Mass of 12C atom = _______________________ 1/12 the mass of Mass of 1 proton = ____________________ 12 C defined as ______________________. Mass of 1 neutron = ___________________ Mass of 1 electron = ___________________ 4 _____________________________ is the weighted average of an elements isotopes found in nature. Ignores man-made isotopes. Avg Atomic = mass Equation Sample problem I. The Mole Calculate the avg. atomic mass of oxygen if its abundance in nature is 99.76% 17 O, and 0.20% 18O. 16 O, 0.04% What is a mole? A pair = A score = A quartet = A gross = A dozen J. Molar Mass Elements = A MOLE = _____________________________________ Called ______________________________________________ _____________________ Mass of one mole of an element or compound AKA: For Elements: Carbon = _________________ Pd = ______________________ 5 Compounds For Compounds: _________________________________________________ Examples NaCl C12H22O11 NaHCO3 (NH4)2SO3 K. Molar Conversions The Big 3 Conversions How many moles of carbon are in 26.36 g of carbon? How many molecules are in 2.50 moles of C12H22O11? Find the mass of 2.1E24 molecules of Mn(NO3)2. 6