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AC. Atomic Structure packet Name: _________________________________KEY__________________ Date: __________ Period: ______ Atomic Structure You can become more familiar with the atomic structure of some common substances by completing the chart below. For each substance, you have been given enough information to fill in all the blanks. Note: Atoms are neutral Symbol Atomic Mass Number of Number of Number of Substance Number Number Protons Neutrons Electrons Helium He 2 4 2 2 2 Magnesium Mg 12 24 12 12 12 Zinc Zn 30 65 30 35 30 Bromine Br 35 80 35 45 35 Aluminum Al 13 27 13 14 13 Uranium U 92 238 92 146 92 Sodium Na 11 23 11 12 11 Krypton Kr 36 84 36 48 36 Calcium Ca 20 40 20 20 20 Silver Ag 47 108 47 61 47 More practice Atomic number 1 2 6 20 4 29 8 16 5 11 26 7 13 10 30 50 82 15 35 51 27 Page 1 Name of element Hydrogen Helium Carbon Calcium Beryllium Copper Oxygen Sulfur Boron Sodium Iron Nitrogen Aluminum Neon Zinc Tin Lead Phosphorus Bromine Antimony Cobalt # of protons 1 2 6 20 4 29 8 16 5 11 26 7 13 10 30 50 82 15 35 51 27 # of electrons 1 2 6 20 4 29 8 16 5 11 26 7 13 10 30 50 82 15 35 51 27 # of neutrons 0 2 6 20 5 35 8 16 6 12 30 7 14 10 35 69 125 16 45 71 32 Atomic mass (2 decimals) 1.01 4.00 12.01 40.07 9.01 63.55 16.00 32.06 10.81 22.98 55.85 14.00 26.98 20.17 65.39 118.71 207.2 30.97 79.90 121.76 58.93 Mass number 1 4 12 40 9 64 16 32 11 23 56 14 27 20 65 119 207 31 80 122 59 Symbol H He C Ca Be Cu O S B Na Fe N Al Ne Zn Sn Pb P Br Sb Co AC. Atomic Structure packet Atomic Structure An atom is made up of protons and neutrons (Both found in the nucleus) and electrons (in the surrounding electron cloud). The atomic number is equal to the number of protons. The mass number is equal to the number of protons plus neutrons. In a neutral atom, the number of protons equals the number of electrons. The charge on an ion indicates an imbalance between protons and electrons. Too many electrons produces a negative charge, too few, a positive charge. This structure can be written as part of a chemical symbol Example: Ma ss nu mb er 15 7 7 protons 8 neutrons (15-7) 4 electrons Cha rge N Element / Ion Atomic number Ato mic nu mb Atomic Mass er (2 decimals) H 1 H 12 6 3 Mass number Protons Neutrons Electrons 1.01 1 1 0 1 1 1.01 1 1 0 0 C 6 12.01 12 6 6 6 Li 3 6.94 7 3 4 2 Cl 17 35.45 35 17 18 18 39 19 K 19 39.10 39 19 20 19 24 12 Mg 2 12 24.31 24 12 12 10 As 3 33 74.92 75 33 42 36 Ag 47 107.87 108 47 61 47 Ag 1 47 107.87 108 47 61 46 S 2 16 32.07 32 16 16 18 U 92 238.03 238 92 146 92 7 3 35 17 Page 2 AC. Atomic Structure packet Parts of an atom An atom is made up of protons and neutrons, which are in the nucleus, and electrons, which are in the electron cloud surrounding the atom. The atomic number equals the number of protons. The electrons in a neutral atom equal the number of protons. The mass number equals the sum of the protons and neutrons. The charge indicates the number of electrons that have been lost or gained. A positive charge indicates the number of electrons (which are negatively charged) lost. A negative charge indicates the number of electrons gained. This structure can be written as part of a chemical symbol. Example: Ma ss nu mb er 12 6 This carbon ion would have 6 protons, 6 neutrons and 2 electrons. C Cha rge 4 Ato mic nu mb Complete the following chart.er Element / Ion 24 1. 12 Mg Atomic number 12 Mass number 24 Charge Protons Neutrons Electrons 0 12 12 12 2. 39 19 K 19 39 0 19 20 19 3. Na 1 11 23 +1 11 12 10 4. 23 11 19 9 F 1 9 19 -1 9 10 10 5. 27 13 Al 3 13 27 +3 13 14 10 1 1 0 1 0 1 12 24 +2 12 12 10 47 16 1 108 32 2 0 -2 0 47 16 1 61 16 1 47 18 1 17 35 -1 17 18 18 4 9 +2 4 5 2 6. 11 H 7. 24 Mg 2 8. Ag 2 9. S 10. 12 H 11. Cl 35 12. Be 2 Page 3 AC. Atomic Structure packet Drawing Atoms You can draw the structures of some common atoms by knowing their atomic number and number of neutrons. Using the information below, draw an atom of each substance. Remember to put the correct number of electrons in each energy level. Substance Helium Lithium Nitrogen Fluorine Neon Atomic number 2 3 7 9 10 Number of neutrons 2 4 7 10 10 Lithiu m Heliu m Nitrog en e 2 p - + 3 p + 2 n e 4 n o - o 7 p + 7 n o Fluori ne e Neon e - - 9p+ 10 no Page 4 10 p+ 10 no e - AC. Atomic Structure packet Isotopes 1. a. What are isotopes? Atoms of same element with different mass (different number of neutrons) b. How are the isotopes of a particular element alike? Same number of protons c. How are they different? Different number of neutrons 2. Complete the following table relative to the three isotopes of hydrogen. Isotope Name # protons # electrons H-1 Protium 1 1 H-2 Deuterium 1 1 H-3 Tritium 1 1 # neutrons 0 1 2 3. a. What is the meaning of the term the atomic number of an element? Number of protons b. What is the mass number of an isotope? Protons + neutrons c. In the nuclear symbol for deuterium ( 12 H ) identify the atomic number and the mass number. Atomic number = 1 Mass number = 2 d. Write its hyphen notation. Hydrogen - 2 4. What is a nuclide? Any isotope of any element 5. Use the periodic table and the information given below to write the hyphen notation for each isotope described: a. atomic number = 2, mass number = 4 Helium - 4 b. atomic number = 8, mass number = 16 Oxygen - 16 c. atomic number = 10, mass number = 39 Neon - 39 Label the following as Isotopes or different elements ___Different____ 1. Element D has 6 protons and 7 neutrons. Element F has 7 protons and 7 neutrons. ___Isotope_____ 2. Element J has 27 protons and 32 neutrons. Element L has 27 protons and 33 neutrons. ___Different____ 3. Element X has 17 protons and 18 neutrons. Element Y has 18 protons and 17 neutrons. ___Isotope______ 4. Element Q has 56 protons and 81 neutrons. Element R has 56 protons and 82 neutrons. ___Isotope______ 5. Element T has an atomic number of 20 and an atomic mass of 40. Element Z has an atomic number of 20 and an atomic mass of 41. ___Different____ 6. Element W has 8 protons and 8 neutrons. Element V has 7 protons and 8 neutrons. ___Isotope_____ 7. Element P has an atomic number of 92 and an atomic mass of 238. Element S has 92 protons and 143 neutrons. Page 5 AC. Atomic Structure packet Calculating atomic mass To calculate the atomic mass of an element, _Multiply___________ the mass of each _element_____ by its natural abundance, expressed as a decimal, and then _add_________ the products Example: Isotope 10X Isotope 11X Mass = 10.012 amu Mass = 11.009 amu Relative abundance = 19.91% = 0.1991 Relative abundance = 80.09% = 0.8009 Atomic mass for X is [(0.1991) x (10.012 amu)] + [(0.8009)x(11.009 amu)] = ____10.810 amu___________________ Sample isotope atomic mass problems 1. The element Copper has naturally occurring isotopes with mass numbers of 63 and 65. The relative abundance and atomic masses are 69.2% for mass 62.93 amu and 30.8% for mass 64.93 amu. Calculate the average atomic mass of copper. (0.692)(62.93amu) + (0.308)(64.93amu) = 63.546 amu 2. Calculate the atomic mass of Bromine. The two isotopes of bromine have atomic masses and relative abundance of 78.92 amu (50.69%) and 80.92 amu (49.31%). (0.5069)(78.92amu) + (0.4931)(80.92amu) = 79.9 amu 3. Magnesium has three naturally occurring isotopes in the following proportions: Mg – 24 (78.70% , 23.98504 amu) Mg – 25 (10.13%, 24.98584 amu) Mg – 26 (11.17%, 25.9825916 amu) What is the atomic mass of Magnesium? (0.7870)(23.98504amu) + (0.1013)(24.98583amu) + (0.1117)(25.9825916amu) = 24.31 amu Page 6 AC. Atomic Structure packet 4. Lithium has 2 isotopes 7.42% of its atoms have a mass of 6.02 amu and 92.58% of its atoms have a mass of 7.02 amu. What is the atomic mass of lithium? (0.0742)(6.02 amu) + (0.9258)(7.02) = 6.95 amu 5. What is the atomic mass of hafnium if 5% have a mass of 176, 19% have a mass of 177, 27% have a mass of 178, 14% have a mass of 179, and 35% have a mass of 180? (0.05)(176 amu) + (0.19)(177 amu) + (0.27)(178 amu) + (0.14)(179 amu) + (0.35)(180 amu) = 179 amu 6. 90% of neon’s atoms have a mass of 20 amu and 10% have a mass of 22 amu. What is neon’s atomic mass? (0.9)(20 amu) + (0.10)(22 amu) = 20.2 amu 7. Copper exists in nature at copper – 63 atomic mass 62.9298 amu and copper –65 atomic mass 64.9278 amu. Its atomic weight is 63.546 amu. What must be the approximate abundance in nature of these two isotopes? (x)(62.9298 amu) + (1-x)(64.9278 = 63.546 amu 62.9298x + 64.9278 – 64.9278x = 63.546 -1.998x = -1.3818 x= 0.691592 So 69.1592% of Cu-63 30.8408% of Cu-65 8. a. What is the relationship between an atom containing 12 protons, 12 neutrons, and 12 electrons and one containing 12 protons, 13 neutrons, and 12 electrons? Isotopes b. What is the relationship between an atom containing 12 protons, 12 neutrons, and 12 electrons and one containing 13 protons, 12 neutrons, and 13 electrons? Different elements Page 7 AC. Atomic Structure packet Isotope and average atomic mass Elements come in a variety of isotopes, meaning they are made up of atoms with the same atomic number but different atomic masses. These atoms differ in the number of neutrons. The average atomic mass is the weighted average of all of the isotopes of an element. Example: A sample of cesium is 75% 133Cs, 20.% 132Cs, and 5% 134Cs. What is the average atomic mass? Answer: (0.75 x 133 amu) + (0.20 x 132 amu) + (0.05 x 134 amu) = 132.85 amu Determine the average atomic mass of the following mixtures of isotopes. 1. 80% 127I, 17% 126I, 3% 128I (0.80)(127) + (0.17)(126) + (0.03)(128) = 126.86 amu 2. 50% 197Au, 50% 198Au (0.5)(197) + (0.5)(198) = 197.5 amu 3. 15% 55Fe, 85% 56Fe (0.15)(55) + (0.85)(56) = 55.85 amu 4. 99% 1H, 0.8% 2H, and 0.2% 3H (0.99)(1) + (0.008)(2) + (0.002)(3) = 1.012 amu 5. 95% 14N, 3% 15N, and 2% 16N (0.95)(14) + (0.03)(15) + (0.02)(16) = 14.07 amu 6. 98% 12C, 2% 14C (0.98)(12) + (0.02)(14) = 12.04 amu Page 8