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Unit 2 Lesson #5 Avogadro’s Number & The Mole (p.14-16) How Big is A Mole? A. What is the Mole? 1. A counting number (like a dozen) 2. Avogadro’s number (NA) 1 mole = 6.022 1023 representative particles 3. Using Dimensional Analysis to Make Conversions a. Convert 48 eggs to dozens of eggs Conversion factor : 48 eggs 1 X 1 dozen 12 eggs X 12 eggs 1 dozen b. Convert 6 dozen to number of eggs Conversion factor : 6 dozen 1 4. Molar Conversion Factors a. # of Particles (atoms, molecules, ions, etc.) 1 mole = 6.022 1023 particles b. Molar mass = mass of 1 mole of a substance 1 mole = molar mass c. Molar Volume = 22.4 Liters for any gas at STP (Standard Temperature Pressure) *STP = T = 0o C or 273 K P = 1.0 atmosphere (atm) 1 mole = molar volume Mole Relationships http://itschemistrytime.blogspot.com/2011_11_01_archive.html Representative Particles & Moles Substance Chemical Formula Carbon C Nitrogen gas N2 Calcium ion Ca2+ Magnesium fluoride MgF2 Representative Particle Rep Particles in 1.00 mole 6.02 x 1023 6.02 x 1023 Representative Particles & Moles Substance Chemical Formula Representative Particle Rep Particles in 1.00 mole Carbon C Atom 6.02 x 1023 Nitrogen gas N2 Molecule 6.02 x 1023 Calcium ion Ca2+ Ion 6.02 x 1023 Magnesium fluoride MgF2 Formula unit 6.02 x 1023 B. Mole to Particle Conversions 6.022 1023 NA NUMBER MOLES OF PARTICLES (particles/mol) NA atoms/mol NA molecules/mol Particles = atoms, molecules, formula units, ions, etc 1. How many molecules are in 2.50 moles of C12H22O11? 2.50 mol C12H22O11 6.02 1023 molecules C12H22O11 1 mol C12H22O11 = 1.51 1024 molecules C12H22O11 2. If you have 2.23 x 1018 atoms of sodium, how many moles is that? 2.23 1018 1 mole Na atoms Na 6.02 1023 atoms Na 3.70 x 10-6 = moles Na 3. How many formula units is 3.75 moles of calcium hydroxide? 6.02 1023 3.75 formula units mol Ca(OH)2 Ca(OH)2 = 2.26 1024 1 mol Ca(OH)2 formula units Ca(OH)2 C. Molar Mass Conversions 1. Molar Mass = The mass of one mole of an element or compound Atomic mass (on the PT) tells the... mass of each atom (amu) grams per mole (g/mol) 2. Round to 2 decimal places 3. Molar Mass Examples a. carbon 12.01 g/mol b. aluminum 26.98 g/mol c. zinc 65.39 g/mol 4. Molar Mass Examples a. water H2O 2(1.01) + 16.00 = 18.02 g/mol b. sodium chloride NaCl 22.99 + 35.45 = 58.44 g/mol 5. Molar Mass Examples a. sodium bicarbonate NaHCO3 22.99 + 1.01 + 12.01 + 3(16.00) b. sucrose = 84.01 g/mol C12H22O11 12(12.01) + 22(1.01) + 11(16.00) = 342.34 g/mol 6. Molar Mass Examples a. magnesium hydroxide Mg(OH)2 24.31 + 2(16.00) + 2(1.01) = 58.33 g/mol b. ammonium sulfate (NH4)2SO4 2(14.01) + 8(1.01) + 32.06 + 4(16.00) = 132.16 g/mol D. Molar Mass Conversions 6.02 1023 NA molar mass MASS NUMBER MOLES IN GRAMS (g/mol) OF (particles/mol) PARTICLES Particles = atoms, molecules, formula units, ions, etc NA atoms/mol NA molecules/mol 1. How many moles of carbon atoms are in 26 g of carbon? 26 g C 1 mol C 12.01 g C = 2.2 mol C 2. Find the mass of 2.1 1024 molecules of NaHCO3. 2.1 1024 Molecules NaHCO3 1 mol 84.01 g NaHCO3 NaHCO3 6.02 1023 1 mol Molecules NaHCO3 NaHCO3 = 290 g NaHCO3 3. How many atoms are in 22.5 grams of potassium? 22.5 g K 1 mol K 6.02 1023 atoms K 39.10 g K 1 mol K = 3.46 x 1023 atoms K E. Molar Volume Conversions NA Molar Mass Molar Vol * Molar Volume = 22.4 Liters for any gas at STP 1. What is the volume at STP of 4.00 g of CH4? 4.0g X 1 1 mole 16 g X 22.4 L = 5.6 L 1 mole 2. How many grams of He are present in 8.00 L of He at STP? 8.0 L X 1 1 mole X 4.0 grams 22.4 L 1 mole = 1.4 g