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GENERAL CHEMISTRY (303102) SECOND SEMESTER 2015/2016 (3 Cr. hrs.) TEXTBOOK: General Chemistry, The Essential Concepts by Chang, Sixth Edition, McGraw-Hill International 2011 GRADING SYSTEM: Grading will be based on the following breakdown: First Midterm 25% Second Midterm 25% Final Exam: 50% Total : 100% Exams’ dates and locations will be announced later Course Content The course material has been divided into the units outlined below. 1. Intermolecular Forces and Liquids and Solids (Chapter 12, 6 Lectures) The Kinetic Molecular Theory of Liquids and Solids, Intermolecular Forcs, Properties of Liquids, Phase Changes, Phase Diagrams. (Exclude 12.4 and 12.5). 2. Physical Properties of Solutions:, (Chapter 13, 6 Lectures) Types of Solutions, A Molecular View of the Solution Process, Concentration Units, Effect of Temperature on Solubility, Effect of Pressure on Solubility, Colligative Properties. 3. Chemical Kinetics:, (Chapter 14, 5 Lectures) The rate of a reaction, the rate laws, relation between reactant concentrations and time, activation energy and temperature dependence of rate constants. Reaction Mechanisms, catalysis. 4. Chemical Equilibrium: (Chapter 15, 5 Lectures) The concept of equilibrium, ways of expressing equilibrium constants, what does the equilibrium constant tell us? Factors that affect chemical equilibrium. -2- 5. Acids and Bases, (Chapter 16, 5 Lectures) Bronsted acids and bases, the acid-base properties of water, pHA measure for acidity, strength of acids and bases, weak acids and acid ionization constants, weak bases and base ionization constants, the relationship between conjugate acid-base ionization constants, molecular structure and the strength of acids, acid-base properties of salts, acidic, basic, and amphoteric oxides, Lewis acids and bases. 6. Acid-Base Equilibria and Solubility Equilibria, (Chapter 17, 3 Lectures) Homogeneous versus heterogeneous solution equilibria, buffer solutions. (Exclude, 17.3, 17.4, 17.5, 17.6, 17.7, 17.8). 7. Thermodynamics: (Chapter 18, 6 Lectures) The three laws of thermodynamics, spontaneous processes, entropy, the second law of thermodynamics, Gibbs free energy, free energy and chemical equilibrium. (Exclude 18.7). 8. Redox Reactions and Electrochemistry: (Chapter 19, 6 Lectures) Redox reactions Galvanic cells, standard reduction potentials, thermodynamics of redox reactions, the effect of concentration on Cell Emf, electrolysis. (Exclude 19.6, 19.7, 19.9). ******************************