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CHEM 1212 - terms to know per chapter Fall 2008, Dr. Pennington Ch. 13: Properties of Solutions Solubility Solvent Solute Enthalpy of solvation (Hsoln) Exothermic Endothermic Entropy Unsaturated solution Saturated solution Supersaturated solution Miscible Immiscible Intermolecular forces Ch. 14: Chemical Kinetics Reaction rate Instantaneous rate Rate Law Rate constant (k) Reaction order (first and second) Overall reaction order Half life (t1/2) Activation Energy (Ea) Transition State Arrhenius Equation Reaction Mechanism Elementary Reaction (or elementary step) Molecularity: Uni-, bi- or termolecular Intermediate Rate-determining step Catalyst (homogeneous and heterogeneous) Enzymes Substrate Chapter 15: Chemical Equilibrium CHEM 1212 Glossary of terms, Fall 2008 Pennington, 8/11/08 1 Chemical Equilibrium Haber process Law of Mass Action Equilibrium expression Equilibrium constant (K) Homogeneous equlibrium Heterogeneous equilibrium Spontaneity Reaction quotient (Q) Le Chatelier’s Principle Chapter 16: Acid / Base Equilibria Hydronium ion (H3O+) Lowry Bronsted Acid Lowry-Bronsted Base Amphiprotic Conjugate Acid Conjugate Base Ion-product constant for water pH Strong Acid Weak Acid Acid-dissociation constant (Ka) Polyprotic acid Lewis Acid Lewis Base Chapter 17: Additional Aqueous Equilibria Common-Ion Effect Buffers Buffer Capacity Henderson-Hasselbalch equation pH titration curve Solubility Product (Ksp) CHEM 1212 Glossary of terms, Fall 2008 Pennington, 8/11/08 2 Chapter 19: Chemical Thermodynamics Spontaneous Reversible process Irreversible process Entropy (S) 2nd Law of Thermodynamics 3rd Law of Thermodynamics Standard Molar Entropy (S) Gibbs Free Energy (G) Standard Free Energy of Formation (Gf) Chapter 20: Electrochemistry Electrochemistry Oxidation Reduction Reducing agent Oxidizing agent Half reactions Galvanic (or voltaic) cell Anode Cathode Standard reduction potential (E) Battery Fuel cell CHEM 1212 Glossary of terms, Fall 2008 Pennington, 8/11/08 3