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Chapter 10 Chem review. 1. Balance the following equations A. _4_C7H9 +_37_ O2 ---> energy +_28_ CO2 + _18_H2O B. _2__Na2O2 + _2_H2O ---> _4_NaOH + ___ O2 C.__P4O10 + _6_H2O + energy---> _4_H3PO4 D. __FeCl3 + 3_NH4OH -->__Fe(OH)3 +_3_NH4Cl 2.List the reactants in 1C. P4O10, H2O 3.List the products in 1D. Fe(OH)3, NH4Cl 4.Which equation in #1 is Endothermic? __C_ or Exothermic? _A_ 5. How does a balanced chemical equation demonstrate the Law of Conservation of Mass? Mass is neither created nor destroyed in a chemical reaction. Because all atoms have a characteristic mass, equal numbers of each atom must be represented on each side of the equation so that the mass consumed equals the mass produced. 6. Write, balance and determine the type of each of the following chemical equations. Note the physical state of each reactant and product. a. Aqueous barium chloride combines with aqueous lithium sulfate to form solid barium sulfate and aqueous lithium chloride. Type __Double Replacement___ BaCl 2 (aq) Li2 SO4 (aq) BaSO4 (s) 2LiCl (aq) b. Solid silver oxide breaks down to form silver metal and oxygen gas. Type __Decomposition__ 2 Ag 2O(s) 4 Ag(s) O2 ( g ) 7. Determine the physical states of the following ionic compounds. Lithium phosphate _aq___ 8. MgCO3 __s__ Barium iodide __aq__ (NH4)2S__aq___ Predict the products of the following chemical reactions, balance the reaction and determine its type. a. _2_C2H2 +_5_ O2 ---> 4CO2 + 2H20 Type ____Combustion__ b. ___PbCl2 +__Mg --> MgCl2 + Pb Type ___Single Replacement____ c. _2_Na + ___ Cl2 --> Type ____Synthesis_______ d. 2NaCl ___ Ca(OH ) 2 2 KCN Ca(CN)2 + 2 KOH e. _2_FeI3 2Fe + 3I2 Type __Double Replacement______ Type ___Decomposition________ 9. Which of the following single replacement reactions will take place? If they take place, predict the products and their physical states (if possible). ___MgCl2 + ___Al --> NR ___ZnSO4 + __2_K --> K2SO4 + Zn In each of the following pairs, which element will replace the other in a reaction? a. b. c. d. tin and sodium fluorine and iodine lead and silver copper and nickel Predict the products of the following single replacement reactions if they occur 3F2 2 FeI 3 2FeF3 + 3I2 ___ Cu ___ H 2 SO4 NR ___ Br2 ___ AlCl3 NR An aqueous solution of nickel (II) sulfate is mixed with aqueous sodium hydroxide. Will a visible reaction occur? (formation of a precipitate) A. B. C. D. No, solid nickel (II) hydroxide is soluble in water No, solid sodium sulfate is soluble in water Yes, solid sodium sulfate will precipitate out of solution Yes, solid nickel (II) hydroxide will precipitate out of solution 1. When sodium metal (silver in color) and chlorine gas (yellow) are mixed in a flask, a violent explosion takes place that results in the formation of sodium chloride (white salt). The reaction flask must be left to cool for a considerable amount of time following the reaction before the salt can be observed. What are the two indications that a chemical change has taken place between sodium and chlorine? ______Change in color________ ______Change in Temperature_______ 2. List one piece of evidence you would expect to see that indicates that a chemical change has taken place in each of the following situations. A. A piece of raw steak that is left unrefrigerated for 4 days. (Production of a gas or odor) B. Vinegar is accidentally spilled in a box of baking soda. (Production of a gas)