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Chemistry Significant Figures Rules For Significant Figures: 1. Non zero integers: 2. 3. Zeros: Non zero integers always count as significant figures. a. Leading zeros are zeros that precede all of the non-zero digits. They do not count as significant figures. 0.0025 = two significant figures. b. Captive zeros are zeros between non-zero digits. They always count as significant. 1.008 = four significant figures. c. Trailing zeros are zeros at the right end of the number. They are significant only if there is a decimal point. 100 = 1 significant figure. 100. = 3 significant figures. Exact Numbers These are defined or counting numbers such as 1 dozen = 12 (defined number) or 7 people (counting number). They have an infinite number of significant figures. Calculations Using Significant Figures. 1. Multiplication and Division: When multiplying and/or dividing, use the least number of significant digits in your final answer. 2. a. If the figure following the last number to be retained is less than 5, all the unwanted figures are discarded and the last number is left unchanged. 3.6247 is 3.62 to three significant figures. b. If the figure following the last number to be retained is 5 or greater, the last figure is increased by 1 and the unwanted figures are discarded. 7.565 is 7.57 to three significant figures. Addition and Subtraction: The result of an addition or subtraction should be reported to the same number of decimal places as that of the term with the least number of decimal places. 161.032 5.6 32.4524 199.0844 = 199.1 since the number 5.6 only has one digit following the decimal point. 3. Combination: When all four operations are involved, obtain the significant figures from addition and subtraction first then from multiplication and division. (5.63 - 2.5) (3.667) = 1.710538 (2.11 + 4.6) (5.63 - 2.5) = two significant figures 3.667 = four significant figures (2.11 + 4.6) = two significant figures Thus, the least number of significant figures is two and the answer should be 1.7. Exercise: 1. State the number of significant figures in each of the following measured quantities. a. 23.2 cm __________ e. 2.440 g __________ b. 40.1 kg __________ f. 0.00035 g __________ c. 0.00025 nm _________ g. 20000 m __________ 2. Round off each of the following numbers to give the number of significant figures indicated. a. 35.7823 (3) d. 0.578 (3) b. 0.002624 (2) e. 0.12256 (3) c. 381.268 (1) f. 87.025 (3) 3. figures. Perform the following operations and give the answers with the correct number of significant a. (56.8)(0.37) f. (5.653-3.2) b. 71.4 11 g. (3.36 + 2.1)(5.00) c. 25.0 5.00 h. (600. - 32) 15.45 d. (2.075)(0.585) (8.42)(0.0045) i. (3.58) 2.005 e. (4.0)(8.00) 16 j. (24.6 - 24.3)(5.00) 2.25