Download TEST I (Alcohols

TEST I (Alcohols - Ethers)
1.
4.
Compound Name
I.
I. CH3 – OH
II. CH3
|
CH – OH
|
CH3
III.
CH3
|
CH3 – C – OH
|
CH3
methyl alcohol
II.
secondary propyl alcohol
What is the chemical formula of this compound?
A)
tertiary butyl alcohol
O
||
H–C–H
C) H – C  C – CH3
2.
B) I – III
C) I – II
D) II – III
E) I, II, III
5.
I.
II.
III.
For the compound 2 – methyl – 2 – oxypropane,
CH3
|
I. it is formulated by H3C – C – CH3
|
OH
II. when oxidized, acetone is formed
III. it forms alkolate with Na
B) II
3.
I.
C) III
A) I
I.
D) I – II E) I - III
II.
O
||
CH3 – C – H + H2  X
C2H5 – OH
CH3 – O – CH3
CH3 – C – OH
||
O
B) II
D) II – III
C) I – II
E) I – III
A ketone is formed when it is oxidized
in the presence of suitable catalyst
0,5 mole of hydrogen is liberated when
1 mole of the alcohol is reacted with
sodium
Which one of the following is expected to be
the alcohol?
A)
B)
C)
D)
E)
What are the compounds X and Y ?
X
ethanol
ethanol
ethanol
ethanoic acid
alcohol
D) C3H5CHO
6.
[O]
 Y
II. CH3 – CH – OH 
|
CH3
A)
B)
C)
D)
E)
O
||
CH3 – C - H
Which compound or compounds consist of
hydrogen bonds between their molecules?
Which one(s) is/are correct?
A) I
B)
E) CH3 – C – CH3
||
O
Which naming or namings are expected to be
correct?
A) I
it reacts with AgNO3 solution (Tollen’s
reagent)
it doesn’t react with Fehling solution
(Cu2Cl2 solution)
Y
ketone
acetic acid
acetone
acetone
acetone
7.
Which one of the following is the isomer with
diethyl ether?
A)
B)
C)
D)
E)
1
1,2 – butanediol
1 – butanol
2 – butanol
1,3 – butanediol
2,3 – butanediol
ethanol
etanediol
diethyl ketone
butanol
butanediol
TEST I (Alcohols - Ethers)
8.
9.
Which one of the following forms 2 –
oxybutane when reduced?
CH3CH2ONa + CH3Br 
A) CH3CH2CH2CH2OH
A)
B)
C)
D)
E)
B) CH3CH2CHOH
|
CH3
ethyl acetate
ethyl methyl ether
diethyl ether
acetone (dimethyl ketone)
propane
C)
Which one of the following forms aketone when
oxidized?
A)
B)
C)
D)
E)
10.
14.
What is the name of the compound formed from
the reaction
D) CH3 – C – CH3
||
O
n – butanol
butanal
2 – methyl – 2 – butanol
2 – methyl – 1 – butanol
3 – methyl – 2 – butanol
E) CH3 – O – C3H7
15.
11.
Which compounds are expected to be formed?
B) CH3CHO
D) CH3COCH3
A)
B)
C)
D)
E)
What is the name of the compound:
CH2 – CH – CH – CH2 – CH3
|
|
|
OH
CH3 OH
A)
B)
C)
D)
E)
12.
I. 2CH3Cl + 2 Na 
II. C2H4 + H2O 
III. C3H6 + H2 
Which one of the following compounds
liberates hydrogen gas with sodium but not zinc?
A) CH3 – O – CH3
C) CH3CH2CH2OH
E) CH3COOH
I
ethane
ethanol
ethylalcohol
ethane
acetaldehyde
II
III
ethylalcohol
propanon
aceticacid
propanon
acetaldehyde propylalcohol
ethylalcohol
propanon
aceticacid
propanon
16.
1,3 – pentanediol
1,3 – hexanediol
seconder hexanol
2 – methyl – 1,3 – hexanediol
2 – methyl – 1,3 – pentanediol
CH3
|
CH3 – CH – CH2OH
For this compound:
I.
it is primary alcohol
II. it is named as “isobutylalcohol”
III. when oxidized, 2 – meethyl propanol is
formed
To prepare methyl ethyl ketone which one
should oxidize?
A)
B)
C)
D)
E)
O
||
CH3 – C – CH2CH3
Which statement(s) is/are correct?
2 – propanol
1 – butanol
2 – butanol
t – butyl alcohol
2 – methyl – 1 – propanol
A) I
B) II
D) II – III
C) I –III
E) I, II, III
17.
I.
13.
when 1 mole of H2 adds 1 mole of
acetylene; 1 mole X forms
II. when 1 mole of H2O adds to 1 mole
X, 1 mole of Y forms
III. when Y oxidized, Z forms
The compound 2 – chloro – 3 – methyl – 1 –
butanol has the formula of
A)
B)
C)
D)
E)
CH2ClC(CH3)2CH2OH
CH3CHOHCH(CH3)CH2Cl
CH3CH(CH3)CHClCH2OH
CH3CHClCH(CH3)CH2OH
CH3C(CH3)CHClCH2OH
What is the compound Z?
A) etylene
D) etanoic acid
2
B) ethanol
C) ethanal
E) dimethyl ketone
TEST I (Alcohols - Ethers)
18.
21.
CH3 – OH
I.
CH3
|
CH – CH – CH2 – OH
|
|
H 3C
OH
R – Cl – NaOH  NaCl + X
X + Na  Y + 1 2 H2
II.
What is the name of Y formed by the reaction?
III.
A)
B)
C)
D)
E)
OH
|
CH3 – C – CH3
|
OH
Which compound or compounds belong to
alcohol class?
A) I
B) II
D) I – II
alcohol
ether
alkolate
alkene
alkyne
22.
I.
C) III
E) I , II, III
H–C=O
|
OH
II.
CH2OH
O
19.
CH3
|
C2H5 – C – OH
|
CH3
III. CH3 – C = O
|
H
for the given compound
Which one(s) can be oxidized?
A) I
I.
II.
it is tertiary alcohol
when it reacts with Na, 1 mole of H2 gas
is liberated
III. when oxidized, ketone forms
which one(s) is/are not correct?
A) I
B) II
D) I – III
C) III
E) II - III
20.
OH
O
COOH
Some information is given for organic compound
I.
II.
III.
it is an oxyacid
it shows both acidic and basic character
it reacts with alcohols
which one(s) is/are correct?
A) I
B) II
D) I – II
C) I –III
E) I, II, III
3
B) I –II
C) I – III
D) II – III
E) I, II, III