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Chemistry 1151, Fall 2005 NAME:________________________ Test 1A. 100 pts. I.D.#_____________ Disc. Sec. ____ Part 1:____________ Part 1. Part 2: ______________ Total:________________ Work must be shown for all numerical problems, or credit will not be given. 1. Write formulas for the following: (3 points each) a. Magnesium nitrate _________________ b. Ammonium sulfide _________________ c. Potassium sulfate ___________________ d. Nickel iodide_____________________ e. Hydrobromic Acid____________________ f. Aluminum hydroxide _____________________ 2. Name: (3 points each) a. SF6 :__________________________________________ b. H2SO3(aq): an acid_____________________________________ Use the following equation for problems 3, 4, and 5. 3 Ca(OH)2(aq) + 2 Na3PO4(aq) Ca3(PO4)2(s) + 6 NaOH(aq) Mol. Mass (g/mol): Ca(OH)2; 74.1, Na3PO4; 164, Ca3(PO4)2; 310.0, NaOH; 40.0 3. (7) If 85.00 g Ca(OH)2 are combined with 150.00 g Na3PO4, which is the limiting reactant? Answer must be supported by calculations or explanation. 4. (7) If 48.2 g Ca(OH)2 is combined with enough Na3PO4 , how many grams of Ca3(PO4)2(s) are produced if the yield is 73.5 % 5. (7) How many mL of 0.750 M Na3PO4 solution will react completely with 46.3 mL of 1.25 M Ca(OH)2 solution? 6. The combustion of 3.42 g of a compound known to contain only nitrogen and hydrogen gave 9.82 g of NO2 and 3.85 g of water. Mol. mass(g/mol): N: 14.00; H: 1.01; O: 16.00 a. (6) Determine the empirical formula of this compound. b. (3) If the molecular mass is 32.0 g/mol, what is the molecular formula? Support answer with calculations. 7. (7) A metal, M, was converted to the chloride, MCl2: M + Cl2 MCl2 A solution of MCl2 was treated with AgNO3(aq) according to the equation: MCl2(aq) + 2 AgNO3(aq) 2 AgCl(s) + M(NO3)2(aq) If 2.434 g of the metal, M, gave 7.964 g of AgCl, what is the atomic weight and the identity of the metal? At. Mass (amu): Ag; 107.8, Cl; 35.5, N; 14.0, O; 16.0 Part 2. Multiple Choice: 3 points each question _____1. Which scientist is incorrectly paired: a. Thompson – electron, c. Proust – neutron b. Rutherford – nucleus of atom, d. Dalton—Atomic Theory _____2. What is the coefficient for oxygen when the following equation is balanced? C4H10(g) + O2(g) CO2(g) + H2O(g) a. 7, b. 5, c. 10, d. 13, _____3. Elements A and Q form two compounds. Given the following data; Cpd. 1: mass Q = 0.271, Cpd. 2: mass Q = .407 Mass A mass A If Cpd 1 has the formula AQ, what is the formula for Cpd. 2? a. A2Q3, b. AQ2, c. A3Q4, d. AQ3, _____4. Which of the following elements has chemical properties similar to calcium? a. sodium, b. nitrogen c. hydrogen d. strontium _____5. How many significant figures are there in the number 0.0006042? a. 7 b. 4 c. 8 d. 3 _____6. Convert 4.301 quarts (qts) to mL. (1L = 1.06 qts) a. 4.559 mL b. 4559 mL c. 4.058 mL _____7. d. 4058 mL A transition metal, a halogen and a semi-metal in that order are: a. Ni, N, Sn, b. Cr, Cl, As, c. As, Cl, Se, d. Ca, Cl, Se _____8. Rhenium (Re) has 2 stable isotopes and an average atomic mass of 186.2 amu. Given that 37.1% of natural rhenium is Re–185, what is the other stable isotope? a. Re-183 b. Re-187 c. Re-189 d. Re-181 _____ 9. How many carbon atoms are there in 52.06 g of carbon dioxide? a. 5.206x1024 b. 3.134x1025 c. 7.122x1023 d. 1.424x1024 _____10. How many protons (p) and neutrons (n) are in an atom of 3890 Sr? a. 38 p, 52 n b. 38 p, 90 n c. 90 p, 38 n, d. 52 p, 38 n _____ 11. Which of the following compounds contains ionic bonds: a. SiO2, b . NI3 c. CH4 d. CaO _____ 12. What is the mass in grams of a single chlorine molecule (Cl2) ? a. 1.177x10-22 g b. 2.37x1024 g c. 70.90 g ________ 13. The charge on the manganese in the salt MnF3 is a. +3 b. +2 c. -3 d. -2 d. 5.887x10-23 g