Lecture 1: Key Concepts in Stereoselective Synthesis
... Olefins with no coordinating functionalities, especially tri- and tetrasubstituted, have been identified as the most difficult substrates for asymmetric hydrogenation. These olefins are particularly difficult to hydrogenate due to the absence of the polar group which is required for Rh or Ru catalys ...
... Olefins with no coordinating functionalities, especially tri- and tetrasubstituted, have been identified as the most difficult substrates for asymmetric hydrogenation. These olefins are particularly difficult to hydrogenate due to the absence of the polar group which is required for Rh or Ru catalys ...
Organometallic Chemistry
... • Reactions of crotylmetal (2-butenylmetal) reagents with carbonyl substrates provide access to acyclic stereo- and enantioselective syntheses of β-methyl homoallylic alcohols. ...
... • Reactions of crotylmetal (2-butenylmetal) reagents with carbonyl substrates provide access to acyclic stereo- and enantioselective syntheses of β-methyl homoallylic alcohols. ...
aciee-2004-43-5442-palomo
... of reactant activation and reaction diastereo- and enantiocontrol, which may guide new developments. Yet, since some of these principles are too general and sometimes little supported, much effort will be needed to fully understand the basis of reactivity and selectivity. Much improvement is still n ...
... of reactant activation and reaction diastereo- and enantiocontrol, which may guide new developments. Yet, since some of these principles are too general and sometimes little supported, much effort will be needed to fully understand the basis of reactivity and selectivity. Much improvement is still n ...
TRANSITION METALS
... [Ag(NH3)2]+ This complex ion, which is formed when either AgCl or Ag 2O dissolves in excess aqueous ammonia, is colourless because of the d 10 configuration of silver(I). It is the ion present in Tollen’s reagent. Tollen’s reagent is used to distinguish aldehydes from ketones: when aldehydes are hea ...
... [Ag(NH3)2]+ This complex ion, which is formed when either AgCl or Ag 2O dissolves in excess aqueous ammonia, is colourless because of the d 10 configuration of silver(I). It is the ion present in Tollen’s reagent. Tollen’s reagent is used to distinguish aldehydes from ketones: when aldehydes are hea ...
