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IJCA 41A(8) 1629-1633
IJCA 41A(8) 1629-1633

... New copper(II) and cobalt(II) complexes of macrocyclic Schiff base ligand containing thiosemicarbazone moiety have been prepared with a general composition [M(H 2L 2)X 2] [where M = Cu(II) or Co(ll); H2L2 = 3,4,9,10-tetraphenyl-1,2,5,6,8,11hexaazacycldodeca-7, 12-dithione-2,4,8, 10-tetraene; X = Cr, ...
chemistry advanced may 2010 marking scheme
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... The oxidation of NO is slow and air is blown into the nitrous gas which is passed up through baffles against a flow of dilute nitric acid in a large tower in which oxidation and absorption is completed. (0.5 marks) NB The Ostwald Process (above) has displaced the obsolete Birkeland-Eyde Process invo ...
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Leaching of Sphalerite with Hydrogen Peroxide and Nitric Acid
Leaching of Sphalerite with Hydrogen Peroxide and Nitric Acid

... The effect of temperature was used to determine the rate-controlling step. The experimental data were analysed using rate equations (9) and (10) to determine the rate controlling step according to the method of Levespiel [12]. From the analysis equation (10) gave straight lines, which could be concl ...
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JF CH 1101 General and Physical Chemistry 2013
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... decreases slightly as the molar concentration is increased. In contrast, the molar conductivity of a potential electrolyte such as CH3COOH decreases in a very marked manner with increasing electrolyte concentration. Strong electrolytes are virtually completely ionized in solution, and so the concent ...
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Full Text - Verlag der Zeitschrift für Naturforschung
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... structure (and in the energy), when compared with 2b, causes an increase in 13 C(carbene) shielding of almost 200 ppm. The structures of 1b and 2b are similar, and the difference in the δ 13 C data for the carbene centers is similar as calculated for 7 amd 8. Nuclear shielding of 11 B is affected by ...
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1984 Advanced Placement Exam
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... H3AsO4 + 3 I– + 2 H3O+  H3AsO3 + I3– + H2O The oxidation of iodide ions by arsenic acid in acidic aqueous solution occurs according to the stoichiometry shown above. The experimental rate law of the reaction is: Rate = k [H3AsO4] [I–] [H3O+] 25. What is the order of the reaction with respect to I–? ...
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CHEMISTRY NOTES – CHAPTERS 20 AND 21

... Note : I will treat the hydrogen ion (H+) and the hydronium ion (H3O+) as the same thing throughout these notes. Neutral solutions have a pH of 7 and have equal concentrations of hydronium and hydroxyl ions (10-7 M). The pH of a solution is the negative logarithm of the hydrogen ion concentration (p ...
Eperimental studies of V.Ostwald and J.van Hoff
Eperimental studies of V.Ostwald and J.van Hoff

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1.8 M - Thierry Karsenti
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... copyright free, relevant, compulsory resources other than a written text or a web site. These could be a video file, an audio file, a set of images, etc. For each resource, Module Developers need to write the complete reference (APA style), as well as a 50 word abstract written in a way to motivate ...
chemical reaction
chemical reaction

... • How to Balance an Equation To balance an equation, you must use coefficients. A coefficient is a number that is placed in front of a chemical symbol or formula. • For an equation to be balanced, all atoms must be counted. So, you multiply the subscript of each element in a formula by the formula’s ...
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Extractible Synthesis and Characterization of Cu (II) Complex with
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... degree of extraction of copper (II) increases with increase in pH and capric acid concentration. In the case of other non-polar solvents such as chloroform, extraction of copper (II) is low. This can be explained ...
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... The forces holding an ionic compound together are the strong electrical attraction that exists between cations and anions. It is therefore somewhat surprising that ionic compounds will dissolve in water. The reason some ionic compounds will dissolve in water is because the water molecules have a par ...
On the Importance of Prereactive Complexes in
On the Importance of Prereactive Complexes in

... several explanations have been proposed, which are summarized in ref 2. Three of them maintain the idea of an elementary reaction but suggest a modification of the preexponential factor in the Arrhenius equation to allow for a term T-1.5. Singleton and Cvetanovic11 propose a complex mechanism and ex ...
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Determination of equilibrium constants

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