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NkT PV = nRT PV = Pa pressure P = m volume V = moles n particles
NkT PV = nRT PV = Pa pressure P = m volume V = moles n particles

... > 0  decreasing U If work is done on the system, W < 0  increasing U In throttling a gas confined in a container under pressure undergoes a free expansion into an evacuated container by route of a small orifice. In aerosol throttling, liquid expands passing through a small orifice and vaporizes in ...
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... • Indefinite volume and shape • Molecules mostly not in contact • Allowed motions – Vibration and rotation (molecules with more than one atom) – Translation on random, mostly free paths ...
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... CQ In Fig. 12.20, the plunger of a syringe is pushed in quickly, and the small pieces of paper in the syringe catch fire. Explain this phenomenon, using the first law of thermodynamics. (Similarly, in a diesel engine, there are no spark plugs. How can the air–fuel mixture ignite?) see Solutions  W ...
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Thermodynamics of ideal gases

... take place in an isolated system which is not allowed to exchange heat with or perform work on the environment. The First Law states that the energy is unchanged under any process in an isolated system. This implies that the energy of an open system can only change by exchange of heat or work with t ...
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... Sommerfeld coefficient γ = 200 mJ/(K2 mole) of Yb4As3 does not originate from impurities. The change of γ is observed when the specific heat is measured in a magnetic field of 1 T. The Korringa law (T1T=constant) holds only in the narrow temperature range between 20 K and 10 K. Their physical proper ...
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Temperature

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